Synthesis, structure and properties of a microporous Cd(II) 3,3′,4,4′-Benzophenone-tetracarboxylate framework material

Inorganic Chemistry Communications

Volumn 14, Issue 3, 2011, Pages 447-449

  Chen, Shu Mei ^a   Lian, Ting Ting ^a  

^a FUZHOU UNIVERSITY   (China)

Author keywords

3,3 4,4 benzophenone tetracarboxylate; Metal organic framework; Porous material; Solvothermal synthesis

Indexed keywords

EID: 79952186394     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.12.004     Document Type: Article

References (26)

1. N.L. Rosi, J. Kim, M. Eddaoudi, B. Chen, M. O'Keeffe, and O.M. Yaghi J. Am. Chem. Soc. 127 2005 1504
2. O.R. Evans, and W. Lin Acc. Chem. Res. 35 2002 511
3. Y.B. Chen, Y. Kang, and J. Zhang Chem. Commun. 46 2010 3182
4. Y. Kang, F. Wang, and J. Zhang Inorg. Chem. Commun. 13 2010 938
5. O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, and J. Kim Nature 423 2003 705
6. S.L. James Chem. Soc. Rev. 32 2003 276
7. Q.G. Zhai, S.N. Li, X. Gao, W.J. Ji, Y.C. Jiang, and M.C. Hu Inorg. Chem. Commun. 13 2010 211
8. H. Li, M. Eddaoudi, M. O'keeffe, and O.M. Yaghi Nature 402 1999 276-
9. G. Férey Nat. Mater. 2 2003 136
10. J.J. Wang, L. Gou, H.M. Hu, Z.X. Han, D.S. Li, G.L. Xue, M.L. Yang, and Q.Z. Shi Cryst. Growth Des. 7 2007 1514
11. R.Q. Zou, R.Q. Zhong, M. Du, T. Kiyobayashi, and Q. Xu Chem. Commun. 2007 2467
12. G.D. Kong, and C.D. Wu Inorg. Chem. Commun. 12 2009 731
13. X. Feng, Y.H. Wen, Y.Z. Lan, Y.L. Feng, C.Y. Pan, and Y.G. Yao Inorg. Chem. Commun. 12 2009 89
14. S. Chen, and T. Lian Inorg. Chem. Commun. 13 2010 1380
15. J. Zhang, Z.-J. Li, Y. Kang, J.K. Cheng, and Y.-G. Yao Inorg. Chem. 43 2004 8085
16. J. Zhang, Z.-J. Li, J.-K. Cheng, Y. Kang, Y.-Y. Qin, and Y.-G. Yao New J. Chem. 29 2005 421
17. D.R. Xiao, E.B. Wang, H.Y. An, Z.M. Su, Y.G. Li, L. Gao, C.Y. Sun, and L. Xu Chem. Eur. J. 11 2005 6673
18. D.R. Xiao, E.B. Wang, H.Y. An, Y.G. Li, Z.M. Su, and C.Y. Sun Chem. Eur. J. 12 2006 6528
19. S.L. Li, Y.Q. Lan, J.F. Ma, J. Yang, G.H. Wei, L.P. Zhang, and Z.M. Su Cryst. Growth Des. 8 2008 675
20. 2O (0.53 g) solution was placed in a 20 ml vial. The sample was heated at 120 °C for 3 days, and then cooled to room-temperature. The solid was washed with ethanol and the colorless crystals were obtained (Yield: 78% based on Cd). Anal. Calc. for 1, C41H35Cd3N3O19: C, 40.50%; H, 2.90%; N, 3.46%. Found: C, 41.02%; H, 2.48%; N, 3.32%.
21. X-ray intensity of 1 was collected on a Siemens Smart CCD diffractometer equipped with graphite monochromated MoKa radiation (λ = 0.71073 Å) at 293(2)K. Empirical absorption corrections were applied to the data using the SADABS program. The structure was solved by the direct method and refined by the full-matrix least-squares on F2 using the SHELXTL-97 program. Crystal data for 1: C41H35Cd3N3O19, Mr = 1214.89, Orthorhombic, space group Ccca, a = 8.1040(3) Å, b = 27.0656(10) Å, c = 20.4233(8) Å, V = 4479.6(3) Å3, Z = 4, Dc = 1.683 g/cm3, R1(wR2) = 0.0457 (0.1455) and S = 1.068 for 1497 reflections with I > 2σ(I). CCDC-758788 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
22. A.L. Spek Acta Crystallogr. Sect. A 46 1990 C34
23. R. Vaidhyanathan, D. Bradshaw, J.-N. Rebilly, J.P. Barrio, J.A. Gould, N.G. Berry, and M.J. Rosseinsky Angew. Chem. Int. Ed. 45 2006 6495
24. C.R. De Silva, S. Smith, and Z. Zheng J. Am. Chem. Soc. 131 2009 6336
25. K.A. White, D.A. Chengelis, N.L. Rosi, and S. Petoud J. Am. Chem. Soc. 131 2009 18069
26. F. Luo, and S.R. Batten Dalton Trans. 39 2010 4485