A purely organic paramagnetic metal, κ-β″-(BEDT-TTF) 2(PO-CONHC2H4SO3), where PO = 2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical

Chemistry of Materials

Volumn 23, Issue 3, 2011, Pages 762-764

  Akutsu, Hiroki ^a   Yamashita, Shinji ^a   Yamada, Jun Ichi ^a   Nakatsuji, Shin'ichi ^a   Hosokoshi, Yuko ^b   Turner, Scott S ^c  

^a UNIVERSITY OF HYOGO   (Japan)

^b Osaka Prefecture University   (Japan)

^c UNIVERSITY OF SURREY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AMINOXYL RADICAL; AREA DETECTORS; BEDT-TTF; BEDT-TTF SALTS; BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE (BEDT-TTF); CONSTANT-CURRENT; ELECTROCRYSTALLIZATION; MIXED SOLVENT; NEEDLE-LIKE CRYSTALS; SINGLE CRYSTAL X-RAY DIFFRACTION; STABLE METALS; SULFONIC ACID; TEMPO RADICAL; TETRAMETHYL;

CRYSTAL GROWTH; DIFFRACTION; PARAMAGNETIC MATERIALS; PARAMAGNETISM; X RAY DIFFRACTION;

FREE RADICALS;

EID: 79952175479     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm100984z     Document Type: Article

References (42)

1. Williams, J. M.; Ferraro, J. R.; Thorn, R. J.; Carlson, K. D.; Geiser U.; Wang H. H.; Kini A. M.; Whangbo M.-H. Organic Superconductor (Including Fullerenes) Synthesis, Structure, Properties and Theory; Prentice-Hall: New York, 1992.
2. Mori, T.; Mori, H.; Tanaka, S. Bull. Chem. Soc. Jpn. 1999, 72, 179.
3. Kurmoo M.; Graham A. W.; Day P.; Coles S. J.; Hursthouse M. B.; Caulfield, J. L.; Singleton, J.; Pratt, F. L.; Hayes, W.; Ducasse, L.; Guionneau, P. J. Am. Chem. Soc. 1995, 117, 12209.
4. Coronado, E.; Day, P. Chem. Rev. 2004, 104, 5419.
5. Enoki, T.; Miyazaki A. Chem. Rev. 2004, 104, 5449.
6. Kobayashi H.; Cui H.; Kobayashi A. Chem. Rev. 2004 104 5265.
7. Sugano, T.; Fukasaka, T.; Kinoshita, M. Synth. Met. 1991, 41-43, 3281.
8. Fujiwara, E.; Aonuma, S.; Fujiwara, H.; Sugimoto, T.; Misaki, Y. Chem. Lett. 2008, 37, 84.
9. Otsubo, S.; Cui, H.; Lee, H.-J.; Fujiwara, H.; Takahashi, K.; Okano, Y.; Kobayashi, H. Chem. Lett. 2006, 35, 130.
10. Matsushita, M. M.; Kawakami, H.; Sugawara, T.; Ogata, M. Phys. Rev. B 2008, 77, 195208.
11. Sugimoto, T.; Yamaga, S.; Nakai, M.; Ohmori, K.; Tsujii, M.; Nakatsuji, H.; Hosoito, H. Chem. Lett. 1993, 1361.
12. Hutchison, K. A.; Srdanov, G.; Menon, R.; Gabriel, J.-C. P.; Knight, B.; Wudl, F. J. Am. Chem. Soc. 1996, 118, 13081.
13. Nakatsuji, S.; Anzai, H. J. Mater. Chem. 1997, 7, 2161.
14. Nakamura, Y.; Koga, N.; Iwamura, H. Chem. Lett. 1991, 69.
15. Mukai, K.; Senba, N.; Hatanaka, T.; Minakuchi, H.; Ohara, K.; Taniguchi, M.; Misaki, Y.; Hosokoshi, Y.; Inoue, K.; Azuma, N. Inorg. Chem. 2004, 43, 566.
16. Aonuma, S.; Casellas, H.; Faulmann, C.; Garreau de Bonneval, B.; Malfant, I.; Cassoux, P.; Lacroix, P. G.; Hosokoshi, Y.; Inoue, K. J. Mater. Chem. 2001, 11, 337.
17. (a) Akutsu H.; Yamada J.; Nakatsuji S. Chem. Lett. 2003 32 1118.
18. (b) Akutsu, H.; Yamada, J.; Nakatsuji, S. Synth. Met. 2005, 152, 377.
19. (c) Akutsu H.; Masaki K.; Mori K.; Yamada J.; Nakatsuji S. Polyhedron 2005, 24, 2126.
20. (d) Yamashita, A.; Akutsu, H.; Yamada, J.; Nakatsuji, S. Polyhedron 2005, 24, 2796.
21. (e) Akutsu, H.; Yamada, J.; Nakatsuji S.; Turner S. S. Solid State Commun. 2006 140 256.
22. (f) Akutsu, H.; Sato, K.; Yamashita, S.; Yamada, J.; Nakatsuji, S.; Turner S. S. J. Mater. Chem. 2008 18 3313.
23. (g) Akutsu H.; Yamashita S.; Yamada J.; Nakatsuji S.; Turner S. S. Chem. Lett. 2008 37 882.
24. w= 0.057 on |F|, and S = 1.094 (see the Supporting Information for further details).
25. w = 0.075 on |F|, and S = 1.151 (see the Supporting Information for further details).
26. Several BEDT-TTF salts have been reported that have two different donor layers with entirely different structures (see ref 11).
27. Schlueter, J. A.; Geiser, U.; Wang, H. H.; Kini, A. M.; Ward, B. H.; Parakka, J. P.; Daugherty, R. G.; Kelly, M. E.; Nixon, P. G.; Winter, R. W.; Gard, G. L.; Montgomery, L. K.; Koo, H.-J.; Whangbo, M.-H. J. Solid State Chem. 2002, 168, 524.
28. Akutsu, H.; Akutsu, A.; Turner, S. S.; Day, P.; Canadell, E.; Firth, S.; Clark, R. J. H.; Yamada, J.; Nakatsuji, S. Chem. Commun. 2004, 18.
29. Akutsu, H.; Yamada, J.; Nakatsuji, S.; Turner, S. S. Solid State Commun. 2007, 144, 144.
30. Martin, L.; Day, P.; Akutsu, H.; Yamada, J.; Nakatsuji, S.; Clegg, W.; Harrington, R. W.; Horton, P. N.; Hursthouse, M. B.; McMillan, P.; Firth, S. CrystEngComm 2007, 9, 865.
31. Guionneau, P.; Kepert, C. J.; Bravic, G.; Chasseau, D.; Truter, M. R.; Kurmoo, M.; Day, P. Synth. Met. 1997, 86, 1973.
32. Only a small number of charge-transfer salts have been reported with two crystallographically independent conducting layers, each of which have different band fillings (see refs 14a-c).
33. (a) Ishikawa, Y.; Saito, K.; Kikuchi, K.; Kobayashi, K.; Ikemoto, I. Bull. Chem. Soc. Jpn. 1991, 64, 212.
34. (b) Kato, R.; Fujiwara, M.; Kashimura, Y.; Yamaura, J. Synth. Met. 2001, 120, 675.
35. (c) Kawamoto, T.; Mori, T.; Kakiuchi, T.; Sawa, H.; Shirahata, T.; Kibune, M.; Yoshino, H.; Imakubo, T. Phys. Rev. B 2007, 76, 134517.
36. The shortest S ··· O contact between the other independent anion 2 and a BEDT-TTF molecule (S15-O10, Figure 1e) is 3.989 (11) Å.
37. Shibaeva, R. N. Zh. Strukt Khim. 1975, 16, 330.
38. 4)] (see ref 18).
39. Nakatsuji, S.; Takai, A.; Nishikawa, K.; Morimoto, Y.; Yasuoka, N.; Suzuki, K.; Enoki, T.; Anzai, H. Chem. Commun. 1997, 275.
40. Mori, T.; Kobayashi, A.; Sasaki, Y.; Kobayashi, H.; Saito, G.; Inokuchi, H. Bull. Chem. Soc. Jpn. 1984, 57, 627.
41. Hall, J. W.; Marsh, W. E.; Weller, R. R.; Hatfield, W. E. Inorg. Chem. 1981, 20, 1033.
42. ET at low temperature may indicate that the data does not exactly follow the 1D alternating chain model.