A pressure sensitive two-dimensional tetracyanoquinodimethane (TCNQ) salt of a stable free radical

Journal of the American Chemical Society

Volumn 118, Issue 51, 1996, Pages 13081-13082

  Hutchison, Katherine A ^a   Srdanov, Gordana ^a   Menon, Reghu ^a   Gabriel, Jean Christophe P ^a   Knight, Brian ^a   Wudl, Fred ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FREE RADICAL;

ARTICLE; CRYSTALLIZATION; DRUG STRUCTURE; ELECTRON SPIN RESONANCE;

EID: 0030466981     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963174i     Document Type: Article

References (20)

1. Bryan, C. D.; Cordes, A. W.; Fleming, R. M.; George, N. A.; Glarum, S. H.; Haddon, R. C.; Oakley, R. T.; Palstra, T. T. M,; Perel, A. S.; Schneemeyer, L. F.; Waszczak, J. V. Nature 1993, 365, 821-823.
2. Bryan, C. D.; Cordes, A. W.; Haddon, R. C.; Hicks, R. G.; Kennepohl, D. K.; MacKinnon, C. D.; Oakley, R. T.; Palstra, T. T. M.; Perel, A. S.; Scott, S. R.; Schneemeyer, L. F.; Waszczak, J. V. J. Am. Chem. Soc. 1994, 116, 1205-1210.
3. Sugimoto, T.; Tsujii, M.; Suga, T.; Hosoito, N.; Ishikawa, M.; Takeda, N.; Shiro, M. Mol. Cryst. Liq. Cryst. 1995, 272, 183-194.
4. Only one other case is reported to date: Ueyama, K.; Matsubayashi, G.-E.; Shinohara, I.; Tanaka, T.; Nakatsu, K. J. Chem. Res. 1985, 48-49.
5. Neugebauer, F. A.; Umminger, I. Chem. Ber. 1980, 113, 1205-1225.
6. 3 (nonaqueous) as the reference electrode.
7. Bard, A. J.; Faulkner, L. R. Electrochemical Methods Fundamentals and Applications; John Wiley & Sons: New York, 1980.
8. Dubois, D.; Moninot, G.; Kutner, W.; Jones, M. T.; Kadish, K. M. J. Phys. Chem. 1992, 96, 7137.
9. Huizinga, S.; Kommandeur, J.; Sawatzky, G. A.; Thole, B. T.; Kopinga, K.; de Jonge, W. J. M.; Roos, J. Phys. Rev. B: Condens. Matter 1979, 19, 4723.
10. Obertelli, S. D.; Friend, R. H.; Moore, A. J.; Bryce, M. R.; Bates, P. Synth. Metals 1988, 27, B327-B332.
11. Chappel, J. S.; Bloch, A. N.; Bryden, W. A.; Maxfield, M.; Poehler, T. O.; Cowan, D. O. J. Am. Chem. Soc. 1981, 103, 2442-2443.
12. Umland, T. C.; Allie, S.; Kuhlmann, T.; Coppens, P. J. Phys. Chem. 1988, 92, 6456.
13. König, E. In Landolt-Bornstein New Series; Hellwege, K. H., Ed.; Springer: Berlin, 1966; Vol II.
14. 3) where x = |J|/kT, μB = Bohr magneton, and k = the Boltzmann constant.
15. Kahn, O. Molecular Magnetism; VCH: New York, 1993.
16. Wudl, F.; Bryce, M. R. J. Chem. Educ. 1990, 67, 717.
17. Jerome, D.; Schulz, H. J. Adv. Phys. 1982, 31, 299.
18. Roth, S. One Dimensional Metals: Physics and Materials Science; VCH: Weinheim, 1995.
19. Williams, J. M.; Ferraro, J. R.; Thorn, R. J.; Carlson, K. D.; Geiser, U.; Wang. H. H.; Kini, A. M.; Whangbo, M.-H. Organic Superconductors; Prentice Hall: London, 1992.
20. On few occasions crystals could not be cycled past 2 kbar pressure without loss of contacts.