Nature of the reaction intermediates in the flavin adenine dinucleotide-dependent epoxidation mechanism of styrene monooxygenase

Biochemistry

Volumn 50, Issue 4, 2011, Pages 523-532

  Kantz, Auric ^a   Gassner, George T ^a  

^a SAN FRANCISCO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORBANCES; ACTIVATION FREE ENERGY; CATALYZED EPOXIDATION; ENANTIOSELECTIVE SYNTHESIS; EPOXIDATION MECHANISM; FLAVIN ADENINE DINUCLEOTIDE; FLAVIN REDUCTASE; FLAVOENZYMES; MONOOXYGENASES; OXYGEN ATOM; PEROXIDE INTERMEDIATE; PH-DEPENDENT; SECOND-ORDER RATE CONSTANTS; SIDE CHAINS; STEREOSPECIFIC ADDITION; STYRENE EPOXIDATIONS; STYRENE OXIDE; TIME POINTS; TWO-COMPONENT;

ACTIVATION ENERGY; CATALYSIS; FLUORESCENCE; MOLECULAR OXYGEN; OXIDATION; OXYGENATION; RATE CONSTANTS; REACTION INTERMEDIATES; SYNTHESIS (CHEMICAL);

STYRENE;

FLAVINE ADENINE NUCLEOTIDE; FLAVOPROTEIN; HYDROXIDE; OXYGEN; PEROXIDE; STYRENE; STYRENE OXIDE; STYRENE OXYGENASE; UNCLASSIFIED DRUG; UNSPECIFIC MONOOXYGENASE; VINYL DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; ENANTIOSELECTIVITY; ENZYME BINDING; EPOXIDATION; FLUORESCENCE; NONHUMAN; PH; PRIORITY JOURNAL; STEREOSPECIFICITY;

CATALYSIS; ENZYME ACTIVATION; EPOXY COMPOUNDS; FLAVIN-ADENINE DINUCLEOTIDE; HYDROGEN PEROXIDE; HYDROGEN-ION CONCENTRATION; KINETICS; OXIDOREDUCTASES; OXYGENASES; PSEUDOMONAS PUTIDA; RECOMBINANT PROTEINS; SPECTROMETRY, FLUORESCENCE; STEREOISOMERISM;

EID: 79952092735     PISSN: 00062960     EISSN: 15204995     Source Type: Journal    
DOI: 10.1021/bi101328r     Document Type: Article

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