Catalysis science of methanol oxidation over iron vanadate catalysts: Nature of the catalytic active sites

ACS Catalysis

Volumn 1, Issue 1, 2011, Pages 54-66

  Routray, Kamalakanta ^a   Zhou, Wu ^a   Kiely, Christopher J ^a   Wachs, Israel E ^a  

^a Lehigh University   (United States)

Author keywords

Fe 2O3; bulk; carbon dioxide (CO 2); carbon monoxide (CO); catalysts; dimethyl ether (CH3OCH3); EELS; electron; FeVO4; formaldehyde (HCHO); HR TEM; in situ; IR; methanol (CH3OH); microscopy; Oxidation; Raman; spectroscopy; supported; TPSR; V2O 5 Fe2O3; V2O5

Indexed keywords

BULK; DIMETHYL ETHERS; EELS; FEVO4; HR-TEM; IN-SITU; IR; MICROSCOPY; RAMAN; SUPPORTED; TPSR; V2O5;

CARBON DIOXIDE; CARBON MONOXIDE; CATALYSIS; CATALYTIC OXIDATION; CHEMICAL ANALYSIS; ETHERS; FORMALDEHYDE; FUELS; METALLIC COMPOUNDS; METALS; METHANOL; MOLECULAR OXYGEN; MONOLAYERS; ORGANIC COMPOUNDS; RAMAN SPECTROSCOPY; SURFACE CHEMISTRY; SURFACES;

CATALYSTS;

EID: 79952035408     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs1000569     Document Type: Article

References (47)

1. Grasselli, R. K.; Burrington, J. D. Adv. Catal. 1981, 30, 133-163
2. Adkins, H.; Peterson, W. R. J. Am. Chem. Soc. 1931, 53, 1512-1520
3. Botella, P.; Lopez Nieto, J. M.; Dejoz, A.; Vazquez, M. I.; Martinez-Arias, A. Catal. Today 2003, 78, 507-512
4. Pyrz, W. D.; Blom, D. A.; Shiju, N. R.; Guliants, V. V.; Vogt, T.; Buttrey, D. J. Catal. Today 2009, 142, 320-328
5. Wachs, I. E. Catal. Today 2005, 100, 79-94
6. Ballarini, N.; Cavani, F.; Cortelli, C.; Ligi, S.; Pierelli, F.; Trifiro, F.; Fumagalli, C.; Mazzoni, G.; Monti, T. Top. Catal. 2006, 38, 147-156
7. Briand, L. E.; Tkachenko, O. P.; Guraya, M.; Gao, X.; Wachs, I. E.; Grunert, W. J. Phys. Chem. B 2004, 108, 4823-4830
8. Merzlikin, S. V.; Tolkachev, N. N.; Briand, L. E.; Strunskus, T.; Wöll, C.; Wachs, I. E.; Grünert, W. Angew. Chem., Int. Ed. 2010, 49, 8037-8041
9. Guliants, V. V.; Bhandari, R.; Brongersma, H. H.; Knoester, A.; Gaffney, A. M.; Han, S. J. Phys. Chem. B 2005, 109, 10234-10242
10. Briand, L. E.; Jehng, J.-M.; Cornaglia, L.; Hirt, A. M.; Wachs, I. E. Catal. Today 2003, 78, 257-268
11. Wachs, I. E.; Briand, L. E. Methanol Oxidation over Bulk Metal Vanadate Catalysts. U.S. Patent 7 193 117 B2 (2007), March 20, 2007.
12. Tian, H.; Wachs, I. E.; Briand, L. E. J. Phys. Chem. B 2005, 109, 23491-23499
13. Burcham, L. J.; Briand, L. E.; Wachs, I. E. Langmuir 2001, 17, 6175-6184
14. Routray, K.; Briand, L. E.; Wachs, I. E. J. Catal. 2008, 256, 145-153
15. Tatibouët, J. M. Appl. Catal., A 1997, 148, 213-252
16. Badlani, M.; Wachs, I. E. Catal. Lett. 2001, 75, 137-149
17. Briand, L. E.; Hirt, A. M.; Wachs, I. E. J. Catal. 2001, 202, 268-278
18. Gao, X.; Bare, S. R.; Weckhuysen, B. M.; Wachs, I. E. J. Phys. Chem. B 1998, 102, 10842-10852
19. Watanabe, M.; Ackland, D. W.; Kiely, C. J.; Williams, D. B.; Kanno, M.; Hynes, R.; Sawada, H. JEOL News 2006, 41, 2-7
20. Briand, L. E.; Farneth, W.; Wachs, I. E. Catal. Today 2000, 62, 219-229
21. Demmin, R. A.; Gorte, R. J. J. Catal. 1984, 90, 32-39
22. Niemantsverdriet, J. W. Spectroscopy in Catalysis; Wiley-VCHVerlag GmbH: Weinheim, Germany, 2000; p 141.
23. Döbler, J.; Pritzsche, M.; Sauer, J. J. Am. Chem. Soc. 2005, 127, 10861-10868
24. Routray, K.; Deo, G. AIChE J. 2005, 51, 1733-1746
25. Jehng, J.-M.; Wachs, I. E.; Clark, F. T.; Springman, M. C. J. Mol. Catal. 1993, 81, 63-75
26. Griffith, W. P.; Lesniak, P. J. B. J. Chem. Soc. A 1969, 7, 1066-1071
27. Routray, K.; Zhou, W.; Kiely, C. J.; Gruenert, W.; Wachs, I. E. J. Catal. 2010, 275, 84-98
28. Luo, J. Crit. Rev. Solid State Mater. Sci. 2007, 32, 67-109
29. Qian, H.; Luo, J. Acta Mater. 2008, 56, 4702-4714
30. Guliants, V. V.; Benziger, J. B.; Sunderesan, S.; Yao, N.; Wachs, I. E. Catal. Lett. 1995, 32, 379-386
31. Hutchings, G. J.; Bartley, J. K.; Webster, J. M.; Lopez-Sanchez, J. A.; Gilbert, D. J.; Kiely, C. J.; Carley, A. F.; Howdle, S. M.; Sajip, S.; Calderelli, S.; Rhodes, C.; Volta, J. C.; Poliakoff, M. J. Catal. 2001, 197, 232-235
32. Bluhm, H.; Havecker, M.; Kleimenov, E.; Knop-Gericke, A.; Liskowski, A.; Schlogl, R.; Su, D. S. Top. Catal. 2003, 23, 99-107
33. Kiely, C. J.; Sajip, S.; Ellison, I. J.; Sananes, M. T.; Hutchings, G. J.; Volta, J. C. Catal. Lett. 1995, 33, 357-368
34. Burcham, L. J.; Briand, L. E.; Wachs, I. E. Langmuir 2001, 17, 6164-6174
35. Wachs, I. E.; Jehng, J.-M.; Ueda, W. J. Phys. Chem. B 2005, 109, 2275-2284
36. Mars, P.; van Krevelen, D. W. Chem. Eng. Sci.(Spec. Suppl) 1954, 3, 41-57
37. Liu, H. C.; Iglesia, E. J. Catal. 2004, 223, 161-169
38. Kurzawa, M.; Tomaszewicz, E. Spectrochim. Acta, Part A 1999, 55, 2889-2892
39. Knozinger, H.; Taglauer, E. Catalysis 1993, 10, 1-40
40. Wang, C.-B.; Cai, Y.; Wachs, I. E. Langmuir 1999, 15, 1223-1235
41. Arora, N.; Deo, G.; Wachs, I. E.; Hirt, A. M. J. Catal. 1996, 159, 1-13
42. Wachs, I. E.; Deo, G.; Weckhuysen, B. M.; Andreini, A.; Vuurman, M. A.; de Boer, M.; Amiridis, M. D. J. Catal. 1996, 161, 211-221
43. Wachs, I. E.; Jehng, J.-M.; Deo, G.; Weckhuysen, B. M.; Guliants, V. V.; Benziger, J. B.; Sundaresan, S. J. Catal. 1997, 170, 75-88
44. Chen, K.; Khodakov, A.; Yang, J.; Bell, A. T.; Iglesia, E. J. Catal. 1999, 186, 325-333
45. Zhao, C.; Wachs, I. E. J. Phys. Chem. C 2008, 112, 11363-11372
46. Routray, K.; Reddy, K. R. S. K.; Deo, G. Appl. Catal., A 2004, 265, 103-113
47. Dunn, J. P.; Koppula, P.; Stenger, H. G.; Wachs, I. E. Appl. Catal., B 1998, 19, 103-117