Elementary reaction kinetics of the CO/CO2 /Ni/YSZ electrode

Journal of the Electrochemical Society

Volumn 158, Issue 1, 2011, Pages

  Yurkiv, V ^a   Starukhin, D ^a   Volpp, H R ^a   Bessler, W G ^b,c  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b GERMAN AEROSPACE CENTER DLR   (Germany)

^c UNIVERSITY OF STUTTGART   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION/DESORPTION KINETICS; ANODE SYSTEM; CO OXIDATION; COMPARISON WITH EXPERIMENTS; ELECTROCHEMICAL IMPEDANCE SPECTRA; ELEMENTARY CHEMICAL REACTION; ELEMENTARY REACTION; EXPERIMENTAL DATA; HETEROGENEOUS REACTION SYSTEMS; KINETIC REACTIONS; NUMERICAL SIMULATION; OXYGEN SPILLOVER; SPILLOVER MECHANISMS; STABILIZED ZIRCONIA; STEADY-STATE POLARIZATION CURVES; THEORETICAL INVESTIGATIONS; THERMODYNAMIC PARAMETER; THREE PHASE BOUNDARY;

CHARGE TRANSFER; ELECTROCHEMISTRY; OXYGEN; SOLID OXIDE FUEL CELLS (SOFC); TEMPERATURE PROGRAMMED DESORPTION; YTTRIA STABILIZED ZIRCONIA; ZIRCONIA;

REACTION KINETICS;

EID: 79951970007     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.3505296     Document Type: Article

References (32)

1. S. C. Singhal and K. Kendall, High-Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications, Elsevier Science, Oxford (2003).
2. A. Atkinson, S. Barnett, R. J. Gorte, J. T. S. Irvine, A. J. McEvoy, M. Mogensen, S. C. Singhal, and J. M. Vohs, Nature Mater. NMAACR 1476-1122, 3, 17 (2004). 10.1038/nmat1040
3. S. B. Adler and W. G. Bessler, in Handbook of Fuel Cells-Fundamentals, Technology and Applications, Vol. 5, W. Vielstich, H. Yokokawa, and, H. A. Gasteiger, Editors, pp. 441-462, John Wiley & Sons, Chichester, UK (2009).
4. A. Bieberle and L. J. Gauckler, Solid State Ionics SSIOD3 0167-2738, 146, 23 (2002). 10.1016/S0167-2738(01)01004-9 (Pubitemid 34089163)
5. M. Vogler, A. Bieberle-Hutter, L. Gauckler, J. Warnatz, and W. G. Bessler, J. Electrochem. Soc. JESOAN 0013-4651, 156, B663 (2009). 10.1149/1.3095477
6. D. G. Goodwin, H. Y. Zhu, A. M. Colclasure, and R. J. Kee, J. Electrochem. Soc. JESOAN 0013-4651, 156, B1004 (2009). 10.1149/1.3148331
7. A. Utz, H. Störmer, A. Leonide, A. Weber, and E. Ivers-Tiff́e, J. Electrochem. Soc. JESOAN 0013-4651, 157, B920 (2010). 10.1149/1.3383041
8. W. G. Bessler, M. Vogler, H. Störmer, D. Gerthsen, A. Utz, A. Weber, and E. Ivers-Tiff́e, Phys. Chem. Chem. Phys. PPCPFQ 1463-9076 12, 13888 (2010).
9. V. M. Janardhanan and O. Deutschmann, J. Power Sources JPSODZ 0378-7753, 162, 1192 (2006). 10.1016/j.jpowsour.2006.08.017 (Pubitemid 44738400)
10. Y. Jiang and A. V. Virkar, J. Electrochem. Soc. JESOAN 0013-4651, 150, A942 (2003). 10.1149/1.1579480
11. G. O. Lauvstad, R. Tunold, and S. Sunde, J. Electrochem. Soc. JESOAN 0013-4651, 149, E497 (2002). 10.1149/1.1518484
12. G. O. Lauvstad, R. Tunold, and S. Sunde, J. Electrochem. Soc. JESOAN 0013-4651, 149, E506 (2002). 10.1149/1.1518485
13. A. M. Sukeshini, B. Habibzadeh, B. P. Becker, C. A. Stoltz, B. W. Eichhorn, and G. S. Jackson, J. Electrochem. Soc. JESOAN 0013-4651, 153, A705 (2006). 10.1149/1.2170577 (Pubitemid 43352225)
14. B. Habibzadeha, B. P. Beckera, A. M. Sukeshinib, and G. S. Jacksona, ECS Trans. ECSTF8 1938-5862, 11 (33), 53 (2008). 10.1149/1.3038908
15. A. Utz, A. Leonide, A. Weber, and E. Ivers-Tiff́e, J. Power Sources, In press.
16. T. Pery, M. G. Schweitzer, H.-R. Volpp, J. Wolfurm, L. Ciossu, O. Deutschmann, and J. Warnatz, Proc. Combust. Inst. PCIRC2 1540-7489, 29, 973 (2002). 10.1016/S1540-7489(02)80123-7
17. H.-R. Volpp and J. Wolfrum, Applied Combustion Diagnostics, Taylor and Francis, New York, pp. 336-358 (2002).
18. T. Edmonds and R. C. Pitkethly, Surf. Sci. SUSCAS 0039-6028, 15, 137 (1969). 10.1016/0039-6028(69)90071-5
19. K. Christmann, O. Schober, and G. Ertl, J. Chem. Phys. JCPSA6 0021-9606, 60, 4719 (1974). 10.1063/1.1680972
20. O. Deutschmann, S. Tischer, S. Kleditzsch, V. M. Janardhanan, C. Correa, D. Chatterjee, N. Mladenov, and H. D. Mihn, DETCHEM software package, 2.1 ed., Karlsruhe, 2007, www.detchem.com, last accessed 3/11/2010.
21. W. G. Bessler, S. Gewies, and M. Vogler, Electrochim. Acta ELCAAV 0013-4686, 53, 1782 (2007). 10.1016/j.electacta.2007.08.030 (Pubitemid 350007516)
22. W. G. Bessler, J. Electrochem. Soc. JESOAN 0013-4651, 154, B1186 (2007). 10.1149/1.2772092 (Pubitemid 47501765)
23. J. T. Stuckless, N. Alsarraf, C. Wartnaby, and D. A. King, J. Chem. Phys. JCPSA6 0021-9606, 99, 2202 (1993). 10.1063/1.465282
24. R. Davis, D. P. Woodruff, P. Hofmann, O. Schaff, V. Fernandez, K. M. Schindler, V. Fritzsche, and A. M. Bradshaw, J. Phys. Condens. Matter JCOMEL 0953-8984, 8, 1367 (1996). 10.1088/0953-8984/8/10/009
25. A. Eichler, Surf. Sci. SUSCAS 0039-6028, 526, 332 (2003). 10.1016/S0039-6028(02)02682-1
26. T. H. Etsell, and S. N. Flengas, J. Electrochem. Soc. JESOAN 0013-4651, 118, 1890 (1971). 10.1149/1.2407862
27. X. D. Zhu, T. Rasing, and Y. R. Shen, Phys. Rev. Lett. PRLTAO 0031-9007, 61, 2883 (1988). 10.1103/PhysRevLett.61.2883
28. O. R. Inderwildi, D. Lebiedz, O. Deutschmann, and J. Warnatz, J. Chem. Phys. JCPSA6 0021-9606, 122, 034710 (2005). 10.1063/1.1835891 (Pubitemid 41047672)
29. A. Galdikas, C. Descorme, and D. Duprez, Solid State Ionics SSIOD3 0167-2738, 166, 147 (2004). 10.1016/j.ssi.2003.11.002
30. S. Gewies and W. G. Bessler, J. Electrochem. Soc. JESOAN 0013-4651, 155, B937 (2008). 10.1149/1.2943411
31. M. W. Chase, C. A. Davies, J. R. Downey, D. J. Frurip, R. A. McDonald, and A. N. Syverud, J. Phys. Chem. Ref. Data JPCRBU 0047-2689, 14, 1 (1985). 10.1063/1.555747
32. W. G. Bessler, J. Warnatz, and D. G. Goodwin, Solid State Ionics SSIOD3 0167-2738, 177, 3371 (2007). 10.1016/j.ssi.2006.10.020 (Pubitemid 44960509)