Transesterification of rapeseed oil over acid resins promoted by supercritical carbon dioxide

Journal of Supercritical Fluids

Volumn 56, Issue 2, 2011, Pages 186-193

  Galia, Alessandro ^a   Scialdone, Onofrio ^a   Tortorici, Emanuele ^a  

^a UNIVERSITY OF PALERMO   (Italy)

Author keywords

Biodiesel; Heterogeneous catalysis; Ion exchange resin; Supercritical carbon dioxide; Transesterification

Indexed keywords

ENHANCEMENT EFFECTS; FATTY ACID METHYL ESTER; FLUID PHASIS; HETEROGENEOUS CATALYSIS; MACROPOROUS; METHANOLYSIS; OPERATING PRESSURE; PHASE BEHAVIOUR; POLYMERIC ACID; RAPESEED OIL; REACTION SYSTEM; REACTION TEMPERATURE; REACTION TIME; STYRENE-DIVINYLBENZENE; SUPERCRITICAL CARBON DIOXIDES; TWO-FLUID;

BATCH REACTORS; BIODIESEL; CARBON DIOXIDE; CATALYSIS; ESTERIFICATION; ESTERS; FATTY ACIDS; ION EXCHANGE; ION EXCHANGE RESINS; REACTION KINETICS; STYRENE; TRANSESTERIFICATION; VEGETABLE OILS;

SUPERCRITICAL FLUID EXTRACTION;

EID: 79951957571     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2010.12.005     Document Type: Article

References (47)

1. F. Ma, and M.A. Hanna Biodiesel production: a review Bioresource Technology 70 1999 1 15 (Pubitemid 29225069)
2. H. Fukuda, A. Kondo, and H. Noda Biodiesel fuel production by transesterification of oils Journal of Bioscience and Bioengineering 92 2001 405 416 (Pubitemid 34016984)
3. M.J. Haas, and T.A. Foglia Alternate feedstocks and technologies for biodiesel production G. Knothe, J. Van Gerpen, J. Krahl, The Biodiesel Handbook 2005 AOCS Press Champaign IL 42 61
4. E. Lotero, Y. Liu, D.E. Lopez, K. Suwannakarn, D.A. Bruce, and J.G. Goodwin Synthesis of biodiesel via acid catalysis Industrial & Engineering Chemistry Research 44 2005 5353 5363
5. E. Lotero, J.G. Goodwin Jr., D.A. Bruce, K. Suwannakarn, Y. Liu, and D.E. Lopez The catalysis of biodiesel synthesis, catalysis The Royal Society of Chemistry 19 2006
6. M. Di Serio, R. Tesser, L. Pengmei, and E. Santacesaria Heterogeneous catalysts for biodiesel production Energy and Fuels 22 2008 207 217 (Pubitemid 351233455)
7. J.A. Melero, J. Iglesias, and G. Morales Heterogeneous acid catalysts for biodiesel production: current status and future challenges Green Chemistry 11 2009 1285 1308
8. Z. Helwani, M.R. Othman, N. Aziz, J. Kim, and W.J.N. Fernando Solid heterogeneous catalysts for transesterification of tryglycerides with methanol: a review Applied Catalysis A: General 363 2009 1 10
9. D.E. López, J.G. Goodwin Jr., D.A. Bruce, and E. Lotero Transesterification of triacetin with methanol on solid acid and base catalysts Applied Catalysis A: General 295 2005 97 105
10. F. Chai, F. Cao, F. Zhai, Y. Chen, X. Wang, and Z. Su Transesterification of vegetable oil to biodiesel using a heteropolyacid solid catalyst Advanced Synthesis & Catalysis 349 2007 1057 1065
11. C.S. Caetano, I.M. Fonseca, A.M. Ramos, J. Vital, and J.E. Castanheiro Esterification of free fatty acids with methanol using heteropolyacids immobilized on silica Catalysis Communications 9 2008 1996 1999
12. 40 Journal of Molecular Catalysis A: Chemical 316 2010 30 44
13. P. Morin, B. Hamad, G. Sapaly, M.G. Carneiro Rocha, P.G. Pries de Oliveira, W.A. Gonzalez, E. Andrade Sales, and N. Essayem Transesterification of rapeseed oil with ethanol I. Catalysis with homogeneous Keggin heteropolyacids Applied Catalysis A: General 330 2007 69 76 (Pubitemid 47321935)
14. A. Chakrabartia, and M.M. Sharma Cationic ion exchange resins as catalyst Reactive Polymers 20 1993 1 45 (Pubitemid 23674316)
15. S.D. Alexandratos Ion-exchange resins: a retrospective from industrial and engineering chemistry research Industrial & Engineering Chemistry Research 48 2009 388 398
16. R. Tesser, L. Casale, D. Verde, M. Di Serio, and E. Santacesaria Kinetics and modelling of fatty acids esterification on acid exchange resins Chemical Engineering Journal 157 2010 539 550
17. S. Pasias, N. Barakos, C. Alexopulos, and N. Papayannakos Heterogeneously catalyzed esterification of FFAs in vegetable oils Chemical Engineering & Technology 29 2006 1365 1371 (Pubitemid 46131480)
18. Y. Feng, B. He, Y. Cao, J. Li, M. Liu, F. Yan, and X. Liang Biodiesel production using cation-exchange resin as heterogeneous catalyst Bioresource Technology 101 2010 1518 1521
19. C.V. Grossi, E. de Oliveira Jardim, M.H. de Araújo, R. Montero Lago, and M.J. da Silva Sulfonated polystyrene: a catalyst with acid and superabsorbent properties for the esterification of fatty acids Fuel 89 2010 257 259
20. N. Özbay, N. Oktar, and N.A. Tapan Esterification of free fatty acids in waste cooking oils (WCO): role of ion-exchange resins Fuel 87 2008 1789 1798
21. C.S. Caetano, L. Guerreiro, I.M. Fonseca, A.M. Ramos, J. Vital, and J.E. Castanheiro Esterification of fatty acids to biodiesel over polymers with sulfonic acid groups Applied Catalysis A: General 359 2009 41 46
22. S.M. de Rezende, M. de Castro Reis, M. Garcia Reid, P.L. Silva Jr., F.M.B. Coutinho, R. Aguiar da Silva San Gil, and E.R. Lachter Transesterification of vegetable oils promoted by poly(styrene-divinylbenzene) and poly(divinylbenzene) Applied Catalysis A: General 349 2008 198 203
23. L. Guerreiro, J.E. Castanheiro, I.M. Fonseca, R.M. Martin-Aranda, A.M. Ramos, and J. Vital Transesterification of soybean oil over sulfonic acid functionalised polymeric membranes Catalysis Today 118 2006 166 171 (Pubitemid 44468335)
24. R.A. Soldi, A.R.S. Oliveira, L.P. Ramos, and M.A.F. César-Oliveira Soybean oil and beef tallow alcoholysis by acid heterogeneous catalysis Applied Catalysis A: General 361 2009 42 48
25. D.G.B. Boocock, S.K. Konar, V. Mao, and H. Sidi Fast one-phase oil-rich processes for the preparation of vegetable oil methyl esters Biomass and Bioenergy 11 1996 43 50 (Pubitemid 27124116)
26. A. Baiker Supercritical fluids in heterogeneous catalysis Chemical Review 99 1999 453 473 (Pubitemid 129606082)
27. 2 Journal of Supercritical Fluids 47 2009 351 356
28. R.A. Dombro Jr., M.A. McHugh, G.A. Prentice, and C.R. Westgate Dielectric constant behavior of carbon dioxide - methanol mixtures in the mixture-critical and liquid-phase regions Fluid Phase Equilibria 61 1991 227 241
29. 2 mixtures AIChE Journal 42 1996 2047 2056 (Pubitemid 126452028)
30. R. Span, and W. Wagner A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa Journal of Physical and Chemical Reference Data 25 1996 1509 1596
31. Ch. Tegeler, R. Span, and W. Wagner A new equation of state for argon covering the fluid region for temperature from the melting line to 700 K at pressures up to 1000 MPa Journal of Physical and Chemical Reference Data 28 1999 779 850
32. T. Kleint, and S. Schulz Measurement and model prediction of vapor-liquid equilibria of mixtures of rapeseed oil and supercritical carbon dioxide Industrial & Engineering Chemistry Research 28 1989 1073 1081
33. S.Z. Mohamed Shamshuddin, and N. Nagaraju Liquid phase transesterification of methyl salicylate and phenol over solid acids: kinetic studies Journal of Catalysis A: Chemical 273 2007 55 63 (Pubitemid 46992837)
34. Y. Liu, E. Lotero, and J.G. Goodwin Jr. A comparison of the esterification of acetic acid with methanol using heterogeneous versus homogeneous acid catalysis Journal of Catalysis 242 2006 278 286 (Pubitemid 44175978)
35. ® acid resins Journal of Catalysis 245 2007 381 391 (Pubitemid 46037689)
36. S.R. Kirumakki, N. Nagaraju, and K.V.R. Chary Esterification of alcohols with acetic acid over zeolites Hb, HY and HZSM5 Applied Catalysis A: General 299 2006 185 192 (Pubitemid 41818963)
37. R. Tesser, L. Casale, D. Verde, M. Di Serio, and E. Santacesaria Kinetics of free fatty acids esterification: batch and loop reactor modelling Chemical Engineering Journal 154 2009 25 33
38. D.M. Alonso, M. López Granados, R. Mariscal, and A. Douhal Polarity of the acid chain of esters and transesterification activity of acid catalysts Journal of Catalysis 262 2009 18 26
39. Y. Sato, M. Yurugi, K. Fujiwara, S. Takishima, and H. Masuoka Solubilities of carbon dioxide and nitrogen in polystyrene under high temperature and pressure Fluid Phase Equilibria 125 1996 129 138 (Pubitemid 126379481)
40. S. Hilic, S.A.E. Boyer, A.A.H. Pádua, and J-P.E. Grolier Simultaneous measurement of the solubility of nitrogen and carbon dioxide in polystyrene and of the associated polymer swelling Journal of Polymer Science Part B: Polymer Physics 39 2001 2063 2070 (Pubitemid 32825117)
41. Y. Sato, T. Takikawa, S. Takishima, and H. Masuoka Solubilities and diffusion coefficients of carbon dioxide in poly(vinyl acetate) and polystyrene Journal of Supercritical Fluids 19 2001 187 198 (Pubitemid 32173021)
42. A.R. Berens, G.S. Huvard, R.W. Korsmeyer, and F.W. Kunig Application of compressed carbon dioxide in the incorporation of additives into polymers Journal of Applied Polymer Science 46 1992 231 242
43. J. Rieger The glass transition temperature of polystyrene Journal of Thermal Analysis and Calorimetry 46 1996 965 972
44. J.H. Glans, and D.T. Turner Glass transition elevation of polystyrene by crosslinks Polymer 22 1981 1540 1543 (Pubitemid 12459501)
45. M. Berrios, and R.L. Skelton Comparison of purification methods for biodiesel Chemical Engineering Journal 144 2008 459 465
46. M.A. Harmer, Q. Sun, A.J. Vega, W.E. Farneth, A. Heidekum, and W.F. Hoelderich Nafion resin-silica nanocomposite solid acid catalysts. Microstructure-processing-property correlations Green Chemistry 2000 7 14
47. M.A. Harmer, and Q. Sun Solid acid catalysis using ion-exchange resins Applied Catalysis A: General 221 2001 45 62 (Pubitemid 34524099)