How and why nanoparticle's curvature regulates the apparent pKa of the coating ligands

Journal of the American Chemical Society

Volumn 133, Issue 7, 2011, Pages 2192-2197

  Wang, Dawei ^a,b   Nap, Rikkert J ^b,c   Lagzi, István ^b   Kowalczyk, Bartlomiej ^b   Han, Shuangbing ^b   Grzybowski, Bartosz A ^b,c   Szleifer, Igal ^b,c  

^a NORTHWESTERN POLYTECHNICAL UNIVERSITY   (China)

^b Northwestern University   (United States)

^c NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACID DISSOCIATION CONSTANTS; COUNTERIONS; FLAT SURFACES; FREE LIGANDS; IMMOBILIZED LIGANDS; NANOPATICLES; SELF-ASSEMBLED; THEORETICAL MODELS;

DISSOCIATION;

LIGANDS;

GOLD NANOPARTICLE; NANOPARTICLE;

ARTICLE; CONFORMATION; PARTICLE SIZE; PKA; THEORETICAL MODEL;

GOLD; HYDROGEN-ION CONCENTRATION; IONS; LIGANDS; METAL NANOPARTICLES; MODELS, MOLECULAR; PARTICLE SIZE; SURFACE PROPERTIES;

EID: 79951842389     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja108154a     Document Type: Article

References (42)

1. Klajn, R.; Olson, M. A.; Wesson, P. J.; Fang, L.; Coskun, A.; Trabolsi, A.; Soh, S.; Stoddart, J. F.; Grzybowski, B. A. Nat. Chem. 2009, 1, 733.
2. Klajn, R.; Bishop, K. J. M.; Grzybowski, B. A. Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 10305.
3. DeVries, G. A.; Brunnbauer, M.; Hu, Y.; Jackson, A. M.; Long, B.; Neltner, B. T.; Uzun, O.; Wunsch, B. H.; Stellacci, F. Science 2007, 315, 358.
4. Kalsin, A. M.; Kowalczyk, B.; Wesson, P.; Paszewski, M.; Grzybowski, B. A. J. Am. Chem. Soc. 2007, 129, 6664.
5. Pengo, P.; Baltzer, L.; Pasquato, L.; Scrimin, P. Angew. Chem. 2007, 119, 404.
6. Simard, J.; Briggs, C.; Boal, A. K.; Rotello, V. M. Chem. Commun. 2000, 1943.
7. Kalsin, A. M.; Fialkowski, M.; Paszewski, M.; Smoukov, S. K.; Bishop, K. J. M.; Grzybowski, B. A. Science 2006, 312, 420.
8. Smoukov, S. K.; Bishop, K. J. M.; Kowalczyk, B.; Kalsin, A. M.; Grzybowski, B. A. J. Am. Chem. Soc. 2007, 129, 15623.
9. Witt, D.; Klajn, R.; Barski, P.; Grzybowski, B. A. Curr. Org. Chem. 2004, 8, 1763.
10. Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesides, G. M. Chem. Rev. 2005, 105, 1103.
11. Kakiuchi, T.; Iida, M.; Imabayashi, S.; Niki, K. Langmuir 2000, 16, 5397.
12. Leopold, M. C.; Bowden, E. F. Langmuir 2002, 18, 2239.
13. Albert, A.; Serjeant, E. P. Ionization Constants of Acids and Bases; Methuen & Co Ltd.: London, 1962.
14. Shan, J.; Tenhu, H. Chem. Commun. 2007, 4580.
15. Pellegrino, T.; Kudera, S.; Liedl, T.; Muñoz Javier, A.; Manna, L.; Parak, W. J. Small 2005, 1, 48.
16. Kalsin, A. M.; Grzybowski, B. A. Nano Lett. 2007, 7, 1018.
17. Lattuada, M.; Hatton, T. A. J. Am. Chem. Soc. 2007, 129, 12878.
18. Sugihara, K.; Teranishi, T.; Shimazu, K.; Uosaki, K. Electrochemistry 1999, 67, 1172.
19. a will coincide with the true equilibrium constant.
20. Szleifer, I.; Carignano, M. A. Macromol. Rapid Commun. 2000, 21, 423.
21. Nap, R.; Gong, P.; Szleifer, I. J. Polym. Sci., Part B: Polym. Phys. 2006, 44, 2638.
22. Szleifer, I.; Carignano, M. A. Adv. Chem. Phys. 1996, 94, 165.
23. Satulovsky, J.; Carignano, M. A.; Szleifer, I. Proc. Natl. Acad. Sci. U.S.A. 2000, 97, 9037.
24. Shvartzman-Cohen, R.; Nativ-Roth, E.; Baskaran, E.; Levi-Kalisman, Y.; Szleifer, I.; Yerusalmi-Rozen, R. J. Am. Chem. Soc. 2004, 126, 14850.
25. Gong, P.; Wu, T.; Genzer, J.; Szleifer, I. Macromolecules 2007, 40, 8765.
26. Wu, T.; Genzer, J.; Gong, P.; Szleifer, I.; Vlček, P.; Šubr, V. Polymer Brushes; Wiley-VCH: Weinheim, Germany, 2004; p 287.
27. Tagliazucchi, M.; Calvo, E. J.; Szleifer, I. Langmuir 2008, 24, 2869.
28. Tagliazucchi, M.; Azzaroni, O.; Szleifer, I. J. Am. Chem. Soc. 2010, 132, 12404.
29. Wu, T.; Gong, P.; Szleifer, I.; Vlček, P.; Šubr, V.; Genzer, J. Macromolecules 2007, 40, 8756.
30. Bishop, K. J. M.; Wilmer, C. E.; Soh, S.; Grzybowski, B. A. Small 2009, 5, 1600.
31. Tanford, C. The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2nd ed.; Wiley: New York, 1980.
32. Raphael, E.; Joanny, J. F. Europhys. Lett. 1990, 13, 623.
33. Croze, O. A.; Cates, M. E. Langmuir 2005, 21, 5627.
34. Schwinger, J.; DeRaad, J., L. L.; Milton, K. A.; Tsai, W. Y. Classical Electrodynamics; Persus Books: Reading, MA, 1998.
35. Landau, L. D.; Lifshitz, E. M. Electrodynamics of Continuous Media; Pergamon Press: Oxford, NY, 1960.
36. Carignano, M. A.; Szleifer, I. J. Chem. Phys. 1995, 102, 8662.
37. Hindmarsh, A. C.; Brown, P. N.; Grant, K. E.; Lee, S. L.; Serban, R.; Shumaker, D. E.; Woodward, C. S. ACM Trans. Math. Softw. 2005, 31, 363.
38. Longo, G.; Szleifer, I. Langmuir 2005, 21, 11342.
39. Laaksonen, T.; Ahonen, P.; Johans, C.; Kontturi, K. ChemPhysChem 2006, 7, 2143.
40. Lok, B. M.; Cannan, T. R.; Messina, C. A. Zeolites 1983, 3, 282.
41. Carnie, S. L.; Chan, D. Y. C.; Gunning, J. S. Langmuir 1994, 10, 2993.
42. Bishop, K. J. M.; Grzybowski, B. A. ChemPhysChem 2007, 8, 2171.