The role of green rust in the migration of radionuclides: An overview of processes that can control mobility of radioactive elements in the environment using as examples Np, Se and Cr

Radiochimica Acta

Volumn 98, Issue 9-11, 2010, Pages 607-612

  Skovbjerg, L L ^a   Christiansen, B C ^a   Nedel, S ^a   Dideriksen, K ^a   Stipp, S L S ^a  

^a Universitetsparken 5 ^*  (Denmark)

Author keywords

Chromium; Green rust; Neptunium; Radioactive waste; Redox; Selenium

Indexed keywords

EID: 79951791438     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2010.1760     Document Type: Article

References (36)

1. Chichagov, A. V.: WWW - MINCRYST. 1985-2009, Institute of Experimental Mineralogy, Russian Academy of Sciences.
2. Magill, J., Pfennig, G., Galy, J.: The Karlsruhe Chart of the Nuclides, 7th Edn. (2006).
3. Barceloux, D. G.: Selenium. J. Toxic.-Clin. Toxic. 37, 145 (1999).
4. Cornell, R. M., Schwertmann, U.: The Iron Oxides. Structure, Properties, Reactions, Occurences and Uses. 2nd Edn., Wiley- VCN, Weinheim (2003).
5. Christiansen, B. C., Balic-Zunic, T., Petit, P. O., Frandsen, C., Morup, S., Geckeis, H., Katerinopoulou, A., Stipp, S. L. S.: Composition and structure of an iron-bearing, layered double hydroxide (LDH) - Green rust sodium sulphate. Geochim. Cosmochim. Acta 73, 3579 (2009).
6. Hansen, H. C. B., Guldberg, S., Erbs,M., Koch, C. B.,: Kinetics of nitrate reduction by green rusts - effects of interlayer anion and Fe(II) : Fe(III) ratio. Appl. Clay Sci. 18, 81 (2001).
7. Hansen, H. C. B., Koch, C. B., Nancke-Krogh, H., Borggaard, O. K., Sørensen, J.: Abiotic nitrate reduction to ammonium: Key role of green rust. Environ. Sci. Technol. 30, 2053 (1996).
8. Hansen, H. C. B., Poulsen, I. F.: Interaction of synthetic sulphate "green rust" with phosphate and the crystallization of vivianite. Clays Clay Miner. 47, 312 (1999).
9. Skovbjerg, L. L., Stipp, S. L. S., Utsunomiya, S., Ewing, R. C.: The mechanisms of reduction of hexavalent chromium by green rust sodium sulphate: Formation of Cr-goethite. Geochim. Cosmochim. Acta 70, 3582 (2006).
10. Loyaux-Lawniczak, S., Refait, P., Ehrhardt, J. J., Lecomte, P., Génin, J.-M. R.: Trapping of Cr by formation of ferrihydrite during the reduction of chromate ions by Fe(II)-Fe(III) hydroxysalt green rusts. Environ. Sci. Technol. 34, 438 (2000).
11. Bond, D. L., Fendorf, S.: Kinetics and structural constraints of chromate reduction by green rusts. Environ. Sci. Technol. 37, 2750 (2003).
12. Williams, A. G. B., Scherer,M. M.: Kinetics of Cr(VI) reduction by carbonate green rust. Environ. Sci. Technol. 35, 3488.
13. 4 anions and anoxic formation of iron(II)-iron(III) hydroxy-selenate green rust. Environ. Sci. Technol. 34, 819 (2000).
14. Scheidegger,A.M., Grolimund, D., Cui, D., Devoy, J., Spahiu,K., Wersin, P., Bonhoure, I., Janousch,M.: Reduction of selenite on iron surfaces: A micro-spectroscopic study. J. Phys. IV 104, 417 (2003).
15. Scheinost,A. C.,Kirsch, R., Banerjee,D., Fernandez-Martinez,A., Zaenker, H., Funke, H., Charlet, L.: X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by Fe-IIbearing minerals. J. Contam. Hydrol. 102, 228 (2008).
16. 2 nanoparticles. Environ. Sci. Technol. 37, 721 (2003).
17. Dodge, C. J., Francis, A. J., Gillow, J. B., Halada, G. P., Eng, C., Clayton, C. R.: Association of uranium with iron oxides typically formed on corroding steel surfaces. Environ. Sci. Technol. 36, 3504 (2003).
18. Pepper, S. E., Bunker, D. J., Bryan, N. D., Livens, F. R., Charnock, J. M., Pattrick, R. A. D., Collison, D.: Treatment of radioactive wastes: an X-ray absorption spectroscopy study of the reaction of technetium with green rust. J. Colloid Interface Sci. 268, 408 (2003).
19. Trolard, F., Génin, J.-M. R., Abdelmoula,M., Bourrié, G., Humbert, B., Herbillon, A.: Identification of a green rust mineral in a reductomorphic soil by Mössbauer and Raman spectroscopies. Geochim. Cosmochim. Acta 61, 1107 (1997).
20. Koch, C. B., Mørup, S.: Identification of green rust in an ochre sludge. Clay Miner. 26, 577 (1991).
21. Christiansen,B. C., Balic-Zunic, T., Dideriksen,K., Stipp, S. L. S.: Identification of green rust in groundwater. Environ. Sci. Tech. 43, 3436 (2009).
22. Génin, J.-M. R., Bauer, Ph., Olowe, A. A., Rezel, D.: Mössbauer study of the kinetics of simulated corrosion process of iron in chlorinated aqueoues solution around room temperature: The hyperfine structure of ferrous hydroxides and green rust I. Hyperf. Interact. 29, 1355 (1986).
23. Kounde, B., Raharinaivo, A., Olowe, A. A., Rezel, D., Bauer, Ph., Génin, J.-M. R.: Mössbauer characterization of the corrosion products of steel in civil works: suspension bridge and reinforced concrete. Hyperf. Interact. 46, 421 (1989).
24. Génin, J.-M., Refait, Ph., Olowe, A., Abdelmoula,M., Fall, I., Drissi, S.: Identification of green rust compounds in the aqueous corrosion processes of steels, the case of microbially induced corrosion and use of 78K CEMS. Hyperf. Interact. 112, 47 (1998).
25. Génin, J.-M. R., Olowe, A. A., Resiak, B., Confente,M., Rollet- Benbouzid, N., L'Haridon, S., Prieur, D.: Products obtained by microbially-induced corrosion of steel in a marine environment: role of green rust two. Hyperf. Interact. 93, 1807 (1994).
26. Drissi, H., Refait, P., Abdelmoula,M., Génin, J.-M. R.: The preparation and thermodynamic properties of Fe(II)-Fe(III) hydroxidecarbonate (Green Rust 1), Pourbaix diagram of iron in carbonatecontaining aqueousmedia. Corros. Sci. 37, 2025 (1995).
27. (s))). Geochim. Cosmochim. Acta, accepted (2010).
28. Refait, P., Bon, C., Simon, L., Bourrié, G., Trolard, F., Bessière, J., Génin, J.-M. R.: Chemical composition and Gibbs standard free energy of formation of Fe(II)-Fe(III) hydroxysulphate green rust and Fe(II) hydroxide. Clay Miner. 34, 499 (1999).
29. Christiansen, B. C., Balic-Zunic, T., Petit, P. O., Frandsen, C., Morup, S., Geckeis, H., Katerinopoulou,A., Stipp, S. L. S.: Composition and structure of an iron-bearing, layered double hydroxide (LDH) - Green rust sodium sulphate. Geochim. Cosmochim. Acta 73, 3579 (2009).
30. Koch, C. B., Hansen, H. C. B.: Reduction of nitrate to ammonium by sulphated green rust. In: Adv. GeoEcology. (Auerswald, K., Stanjek, H., Bigham, J. M., eds.) Catena Verlag, Reiskirchen (1997), Vol. 30, p. 373.
31. Lewis, D. G.: Factors influencing the stability and properties of green rusts. In: Adv.GeoEcology. (Auerswald, K., Stanjek, H., Bigham, J.M., eds.)CatenaVerlag,Reiskirchen (1997),Vol. 30, p. 345.
32. Schwertmann,U., Gasser, U., Sticher,H.: Chromium-for-iron substitution in synthetic goethites. Geochim. Cosmochim. Acta 53, 1293 (1989).
33. Teterin, Y. A., Kalmykov, S. N., Novikov, A. P., Sapozhnikov, Y. A., Vukcevic, L. D., Teterin, A. Y., Maslakov, K. I., Utkin, I. O., Khasanova, A. B., Shcherbina, N. S.: An XPS study of interaction of neptunyl(V) in aqueous solution with goethite (α-FeOOH). Radiochemistry 46, 545 (2004).
34. Teterin, Y. A., Teterin, A. Y.: The structure of X-ray photoelectron spectra of light actinide compounds. Russ. Chem. Rev. 73, 541 (2004).
35. SO4 and the occurrence of GR in nature. Ph.D. Thesis at the Department of Chemistry, University of Copenhagen, Denmark (2008), p. 71.
36. Clark, D. L., Hobart, D. E., Neu, M. P.: Actinide carbonate complexes and their importance in actinide environmental chemistry. Chem. Rev. 95, 25 (1995).