Interaction of synthetic sulphate green rust with phosphate and the crystallization of vivianite

Clays and Clay Minerals

Volumn 47, Issue 3, 1999, Pages 312-318

  Christian, Hans ^a   Hansen, Bruun ^a   Poulsen, Inge Fiil ^a  

^a UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

Anion exchange; Fe(ii)feiii hydroxides; Green rust; Layered hydroxides; Phosphate; Vivianite

Indexed keywords

CRYSTALLIZATION; DISSOLUTION; ION EXCHANGE; IRON COMPOUNDS; NEGATIVE IONS; OXIDATION; PHOSPHATES; SEDIMENTS; SOILS; SORPTION; SUSPENSIONS (FLUIDS); SYNTHESIS (CHEMICAL);

AMORPHOUS GREENISH PHOSPHATE; ANION EXCHANGE; ANOXIC SOILS; GREEN RUST; LAYERED HYDROXIDES; REDUCTIVE DISSOLUTION; VIVIANITE;

OXIDE MINERALS;

ANION; CRYSTALLIZATION; ION EXCHANGE; PHOSPHATE; SULFATE; VIVIANITE;

EID: 0032855172     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/ccmn.1999.0470307     Document Type: Article

References (45)

1. Al-Borno, A. and Tomson, M.B. (1994) The temperature dependence of the solubility product constant of vivianite. Geocliimica et Cosmochimica Ada, 58, 5373-5378.
2. Allison, J.C., Brown, D.S., and Novo-Gradac, K.J. (1990) M1NTEQA2IPRODEFA2, a Geochemical Assessment Model for Environmental Systems: Version 3.00 User's Manual. EPA-600/3-91-021, USEPA, Athens, Georgia.
3. x+. Chimia, 24, 99-108.
4. Arden, T.V. (1950) The solubility products of ferrous and ferrosic hydroxides. Journal of the Chemical Society, 882885.
5. Bernai, J.D., Dasgupta, D.T., and Mackay, A.L. (1959) The oxides and hydroxides of iron and their structural interrelationships. Clay Minerals Bulletin, 4, 15-30.
6. Brindley, G.W. and Bish, D.L. (1976) GR: A pyroaurite type structure. Nature, 263, 353.
7. Dutta, P.K. and Puri, M. (1989) Anion exchange in lithium aluminatc hydroxides. Journal of Physical Chemistry, 96, 376-381.
8. Fadrus, H. and Maly, J. (1975) Suppression of iron(III) interference in the determination of iron(II) in water by the 1,10-phenamhroIine method. Analyst, 100, 549-554.
9. Feitknecht, \V. and Keller, G. (1950) Über de dunkelgrünen Hydroxyverbindungen des Eisens. Zeitschrift für anorganische Chemie, 262, 61-68.
10. Fox, L.E. (1988) The solubility of colloidal ferric hydroxide and its relevance to iron concentrations in river water. Geochimica et Cosmochimica Ada, 52, 771-777.
11. Hansen, H.C.B. (1989) Composition, stabilization, and light absorption of Fe(II)Fe(III) hydroxy-carbonate ('Green Rust'). Clay Minerals, 24, 663-669.
12. Hansen, H.C.B. (1994) TITRA-A MS Windows 3.x program for communication between Methrohm pH-meters/-dosiinates and a PC via RS-232. Technical Report, Chemistry Department, The Royal Veterinary and Agricultural University, Copenhagen, 83 pp. (in Danish).
13. Hansen, H.C.B. (1995) Interlayer-bonding of orthophosphate and orthosilicate in layered magnesium-aluminium hydroxide (Hydrotalcite). In Proceedings of the 10th International Clay Conference Adelaide, Australia, 201-206.
14. Hansen, H.C.B., Borggaard, O.K., and S0rensen, J. (1994) Evaluation of the free energy of formation of iron(II)iron(III)-hydroxide-sulphate (Green Rust) and its reduction of nitrite. Geochimica et CosmocMmica Ada, 58, 2599-2608.
15. Hansen, H.C.B., Koch, C.B., Nancke-Krogh, H., Borggaard, O.K., and Sprensen, J. (1996) Abiotic nitrate reduction to ammonium: Key role of green rust. Environmental Science and Technology, 30, 2053-2056.
16. Holford, I.C.R. and Patrick, W.H., Jr. (1979) Effects of reduction and pH changes on phosphate Sorption and mobility in an acid soil. Soil Science Society of America Journal, 43, 292-297.
17. Kandori, K., Uchida, S., Kataoka, S., and Ishihawa, T. (1992) Effects of silicate and phosphate on the formation of ferric oxide hydroxide particles. Journal of Materials Science, 26, 3313-3319.
18. Karim, Z. (1986) Formation of ferrihydrite by inhibition of green rust structures in the presence of silicon. Soil Science Society of America Journal, 50, 247-250.
19. Koch, C.B. and Hansen, H.C.B. (1997) Reduction of nitrate to ammonium by sulphate green rust. Advances in GeoEcology, 30, 373-393.
20. Kosin, J.A., Preston, B.W., and Wallace, D.N. (1989) Modified synthetic hydrotalcite. US Patent 4.883.533.
21. Lovley, D.R. (1987) Organic matter mineralization with the reduction of ferric iron: A review. Geomicrobiology Journal, 5, 375-399.
22. Lovley, D.R. (1991) Dissimilatory Fe(III) and Mn(IV) reduction. Microbiological Reviews, 55, 259-287.
23. Miyata, S. (1983) Anion-exchange properties of hydrotalcitelike compounds. Clays and Clay Minerals, 31, 305-311.
24. Nriagu, J.O. and Dell, C.I. (1974) Diagenetic formation of iron phosphates in recent lake sediments. American Mineralogist, 59, 934-946.
25. Patrick, W.H., Jr. and Khalid, R.A. (1974) Phosphate release and sorption by soils and sediments: Effect of aerobic and anaerobic conditions. Science, 186, 53-55.
26. Ponnamperuma, F.N. (1972) The chemistry of submerged soils. Advances in Agronomy, 24, 29-96.
27. Reardon, E.J. and Delia Vale, S. (1997) Anion sequestering by the formation of anionic clays: Lime treatment of fly
28. ash slurries. Environmental Science anil Technology, 31, 1218-1223.
29. Shin, H.S., Kirn, M.J., Nam, S.Y., and Moon, H.C. (1996) Phosphorus removal by hydrotalcite-likc compounds (HTLcs). Water Science anil Technology, 34, 161-168.
30. Siemens (1997) DiffracPlus Evaluation Program. User's Guide. Siemens, Karlsruhe, 128 pp.
31. Szilas, C.P., Borggaard, O.K., Hansen, H.C.B., and Rauer, J. (1997) Potential iron and phosphate mobilization during flooding of soil material. Water, Air and Soil Pollution, 106, 97-109.
32. Tamaura, Y., Saturno, M., Yamada, K., and Katsura, T. (1984a) The transformation of -y-FeO(OH) to FeAO4 and green rust II in an aqueous solution. Bulletin of the Chemical Society of Japan, 57, 2417-2421.
33. Tamaura, Y., Yoshida, T., and Katsura, T. (1984b) The synthesis of green rust II (Fe1,-Fe2) and its spontaneous transformation into Fe3O4. Bulletin of the Chemical Society of Japan, 57, 2411-2416.
34. Taylor, R.M. (1980) Formation and properties of Fe(II)Fe(III) hydroxycarbonate and its possible significance in soil formation. Clay Minerals, 15, 369-382.
35. Taylor, R.M. and McKenzie, R.M. (1980) The influence of aluminum on iron oxides. VI. The formation of Fe(II)Al(III) hydroxy-chlorides, -sulfates, and -carbonates as new members of the pyroaurite group and their significance in soils. Clays and Clay Minerals, 28, 179-187.
36. Tecator (1983) Determination of total phosphorus in svater by flow injection analysis. Application Note, ASN 60-02/03, Höganäs, Sweden.
37. Trolard, F., Genin, J.M.R., Abdelmoula, M., Bourne, G., Humbert, B., and Herbillon, A. (1997) Identification of a green rust mineral in a reductomorphic soil by Mössbauer and Raman spectroscopies. Geochimica et Cosmochimica Acta, 61, 1107-1111.
38. Wagman, D.D., Evans, W.H., Parker, V.B., Schumm, H., Halow, I., Bailey, S.M., Churney, K.L., and Nuttall, R.L. (1982) The NBS tables of chemical thermodynamic properties. Selected values for inorganic and C, and C2 organic substances in SI units. Journal of Physical anil Chemical Reference Data, 11, (Supplement 2).
39. Westergaard, B., Hansen, H.C.B., and Borggaard, O.K. (1998) Determination of anions in soil solutions by capillary zone electrophoresis. Analyst, 123, 721-724.
40. Vins, J., Subrt, J., Zapletal, V, and Hanousek, E (1987) Preparation and properties of green rust type substances. Collection of the Czechoslovak Chemical Communications, 52, 93-102.
41. Wille, I.R. (1985) The reductive dissolution of phosphated ferrihydrite and strengite. Australian Journal of Soil Research, 23, 237-244.
42. Willett, I.R. (1986) Phosphorus dynamics in relation to redox processes in flooded soils. In Transactions of the 13 Congress of the International Soil Science Society, Hamburg. Volume VI, 748-755.
43. Willett, I.R. (1989) Causes and prediction of changes in extractable phosphorus during flooding. Australian Journal of Soil Research, 27, 45-54.
44. Willett, I.R. and Higgins, M.L. (1978) Phosphate sorption by reduced and reoxidized rice soils. Australian Journal of Soil Research, 16, 319-326.
45. Williams, J.D.H., Syers, J.K., Shukla, S.S., Harris, R.F., and Armstrong, D.E. (1971) Levels of inorganic and total phosphorus in lake sediments as related to other sediment parameters. Environmental Science ana Technology, 5, 11131120.