From molecules to systems: Sol-gel microencapsulation in silica-based materials

Chemical Reviews

Volumn 111, Issue 2, 2011, Pages 765-789

  Ciriminna, Rosaria ^a   Sciortino, Marzia ^a   Alonzo, Giuseppe ^b   De Schrijver, Aster ^c   Pagliaro, Mario ^a  

^a CNR   (Italy)

^b UNIVERSITY OF PALERMO   (Italy)

^c Port of Ghent   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBED LAYERS; DYNAMIC CHARACTER; EMULSION DROPLETS; EMULSION DROPS; EMULSION SYSTEMS; HOLLOW SILICA SPHERES; MICRO REACTOR; MICRO-PARTICLES; O/W EMULSIONS; SHELL THICKNESS; SILICON PRECURSORS; WATER IN OIL EMULSIONS; WATER RATIO;

CHEMICAL REACTORS; DROP FORMATION; EMULSIONS; ENCAPSULATION; ETHANOL; SILICA; SOLS; SPHERES;

EMULSIFICATION;

NANOPARTICLE; ORMOSIL; SILICON DIOXIDE; SILOXANE; SUNSCREEN;

ARTICLE; CHEMISTRY; GEL; MICROCAPSULE;

CAPSULES; GELS; NANOPARTICLES; SILICON DIOXIDE; SILOXANES; SUNSCREENING AGENTS;

EID: 79951599621     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/cr100161x     Document Type: Article

References (84)

1. Levy, D.; Reisfeld, R.; Avnir, D. J. Phys. Chem. 1984, 88, 5956.
2. Avnir, D.; Coradin, T.; Lev, O.; Livage, J. J. Mater. Chem. 2006, 16, 1013.
3. Avnir, D.; Blum, J.; Lev, O. Reactive Ceramic Nanocomposites with Organic and Bio-organic Dopants. In Encyclopedia of Materials: Science and Technology; Jurgen, K. H., Buschow, R. W., Cahn, M. C., Flemings, B., Ilschner, E., Kramer, J., Mahajan, S., Eds.; Elsevier Science: Amsterdam, 2001.
4. Avnir, D. Acc. Chem. Res. 1995, 28, 328.
5. Pagliaro, M. Silica-Based Materials for Advanced Chemical Applications; RSC Publishing: Cambridge, 2009.
6. Pagliaro, M.; Ciriminna, R.; Wong Chi Man, M.; Campestrini, S. J. Phys. Chem. B 2006, 110, 1976.
7. Sanchez, C.; Julián, B.; Belleville, P.; Popall, M. J. Mater. Chem. 2005, 15, 3559.
8. Gouin, S. Trends Food Sci. Technol. 2004, 15, 330.
9. Kreimeyer, A. (Basf), "Basf keeps R&D spending at high level", press release, 28 January 2010.
10. Microencapsulation: Methods and Industrial Applications; Benita, S., Ed.; Informa Healthcare: London, 2005.
11. Ghosh, S. K. Functional Coatings and Microencapsulation: A General Perspective. In Functional Coatings; Ghosh, S. K., Ed.; Wiley-VCH: Weinheim, Germany, 2006.
12. McCoy, M. Chem. Eng. News 2008, 86 (12), 26.
13. van Driessche, I.; Hoste, S. Encapsulations Through the Sol-Gel Technique and their Applications in Functional Coatings. In Functional Coatings; Ghosh, S. K., Ed.; Wiley-VCH: Weinheim, 2006; Chapters 1 and 8.
14. Lai, W.; Garino, J.; Ducheyne, P. Biomaterials 2002, 23, 213.
15. Microemulsions: Properties and Applications; Fanun, M., Ed.; CRC Press: Boca Raton, 2008.
16. Barbé, C. J.; Kong, L.; Finnie, K. S.; Calleja, S.; Hanna, J. V.; Drabarek, E.; Cassidy, D. T.; Blackford, M. G. J. Sol-Gel Sci. Technol 2008, 46, 393.
17. Barbé, C.; Bartlett, J.; Kong, L.; Finnie, V.; Lin, H. Q.; Larkin, M.; Calleja, S.; Bush, A.; Calleja, G. Adv. Mater. 2004, 16, 1959.
18. Backov, R. Soft Matter 2006, 2, 452.
19. Arsenault, A.; Ozin, G. A. Nanochemistry: A Chemical Approach to Nanomaterials; RSC Publishing: Cambridge, 2005.
20. Baccile, N.; Babonneau, F.; Thomas, B.; Coradin, T. J. Mater. Chem. 2009, 19, 8537.
21. Pagliaro, M.; Ciriminna, R.; Palmisano, G. Chem. Soc. Rev. 2007, 36, 932.
22. Ciriminna, R.; Palmisano, G.; Pagliaro, M. Chem. Rec. 2010, 10, 17.
23. http://www.ceramisphere.com.au.
24. Holmberg, K.; Jönsson, B.; Kronberg, B.; Lindman, B. Surfactants and Polymers in Aqueous Solution, 2nd ed.; Wiley: New York, 2002.
25. Meixner, D. L.; Dyer, P. N. J. Sol-Gel Sci. Technol. 1999, 14, 223.
26. Finnie, K. S.; Bartlett, J. R.; Barbe, C. J. A.; Kong, L. Langmuir 2007, 25, 3017.
27. Brinker, C. J.; Drotning, W. D.; Scherer, G. W. A comparison between the densification kinetics of colloidal and polymeric silica gels. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research. Society: New York, 1984.
28. Wang, J.-X.; Wang, Z.-H.; Chen, J.-F.; Yun, J. Mater. Res. Bull 2008, 43, 3374.
29. Singh, R. K.; Garg, A.; Bandyopadhyaya, R.; Mishra, B. K. Colloids Surf., A: Physicochem. Eng. Aspects 2007, 310, 39.
30. Lee, M. H.; Oh, S. G.; Moon, S. K.; Bae, S. Y. J. Colloid Interface Sci. 2001, 240, 83.
31. Fujiwara, M.; Shiokawa, K.; Hayashi, K.; Morigaki, K.; Nakahara, Y. J. Biomed. Mater. Res. 2007, 81A, 103.
32. Hideo, O.; Takahashi, K. J. Chem. Eng. Jpn. 1998, 31, 808.
33. The original 2001 patent describing the technology is: Magdassi, S.; Avnir, D.; Seri-levy, A.; Lapidot, N.; Rottman, C.; Sorek, Y.; Gans, O. Method for the preparation of oxide microcapsules loaded with, functional molecules and the products obtained thereof, US 6303149 (Granted to Sol-Gel Technologies Ltd.).
34. Zhang, H.; Wu, J.; Zhou, L.; Zhang, D.; Qi, L. Langmuir 2007, 25, 1107.
35. Teng, Z.; Han, Y.; Li, J.; Yan, F.; Yang, W. Microporous Mesoporous Mater. 2010, 127, 67.
36. Radin, S.; Chen, T.; Ducheyne, P. Biomaterials 2009, 30, 850.
37. Fei, B.; Lu, H.; Wang, R. H.; Xin, J. H. Chem. Lett. 2006, 35, 622.
38. Ottenbrite, R. M.; Wall, J. S.; Siddiqui, J. A. J. Am. Ceram. Soc. 2004, 83, 3214.
39. Liu, J.; Bai, S.; Zhong, H.; Li, C.; Yang, Q. J. Phys. Chem. C 2010, 114, 953.
40. Arkhireeva, A.; Hay, J. N.; Oware, W. J. Non-Cryst. Solids 2005, 351, 1688.
41. Asefa, T.; MacLachalan, M. J.; Coombs, N.; Ozin, G. A. Nature 1999, 402, 867.
42. Yang, Q.; Liu, J.; Zhang, L.; Li, C. J. Mater. Chem. 2009, 19, 1945.
43. In the Laboratories of Prof. P. Ducheyne at Pennsylvania University.
44. Wang, J.-.X.; Wang, Z.-H.; Chen, J.-F.; Yun, J. Mater. Res. Bull. 2008, 43, 3374.
45. Zhu, Y. F.; Shi, J. L.; Li, Y. S.; Chen, H. R.; Shen, W. H.; Dong, X. P. J. Mater. Res. 2005, 20, 54.
46. Higuchi, T. J. Pharm. Sci. 1963, 52, 1145.
47. Zhu, Y.; Shi, J.; Shen, W.; Dong, X.; Feng, J.; Ruan, M.; Li, Y. Angew. Chem., Int. Ed. 2005, 44, 5083.
48. Zhua, Y.; Shi, J. Microporous Mesoporous Mater. 2007, 103, 243.
49. Finnie, K. S.; Waller, D. J.; Perret, F. L.; Krause-Heuer, A. M.; Lin, H. Q.; Hanna, J. V.; Barbé, C. J. J. Sol-Gel Sci. Technol, 2008, 49, 12.
50. Lapidot, N.; Gans, O.; Biagini, F.; Sosonkin, L.; Rottman, C. J. SolGel Sci. Technol, 2003, 26, 67.
51. Schlumpf, M.; Cotton, B.; Conscience, M.; Haller, V.; Steinmann, B.; Lichtensteiger, W. Environ. Health Perspect 2001, 109, 239.
52. Weinreb, G. Globes, January 24, 2008.
53. Cool Pearls Anti Acne Kits. See at the URL: www.sol-gel.com/Main.Page. aspx?id=133.
54. Mellati, A.; Attar, H.; Farahani, M. F. Asian J. Biotechnol. 2010, 2, 127.
55. Pérez-Lombard, L.; Ortiz, J.; Pout, C. Energy Build. 2008, 40, 394.
56. According to the company's information, a layer of PCM. plaster approximately 1.5 cm thick has the same heat capacity as a concrete or brick wall, meaning that one can reap the benefits of lightweight design while still storing heat. They have been incorporated in numerous buildings, including the Haus der Gegenwart in Munich. See at the URL: www.micronal.de.
57. Zhang, H.; Wang, X.; Wu, D. J. Colloid Interface Sci. 2010, 343, 246.
58. Sobolev, K.; Ferrada-Gutiérrez, M. Am. Ceram. Soc. Bull. 2005, 11, 16.
59. Yang, Z.; Hollar, J.; He, X.; Shi, X. Proc. SPIE 2009, 7493, 74934L.
60. Stöber, W.; Fink, A.; Bohn, E. J. Colloid Interface Sci. 1968, 26, 62.
61. Brinker, C. J.; Scherer, G. W. Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing; Academic Press: New York, 1990.
62. Hilarius, V. Farbe und Funktion-Von neuen Effekten zu innovativen Produkten; Merck KGaA: 2009. Available at the URL: http://www.nano.mat.de/pdf/ hilarius.pdf.
63. BCC Research, Sol-Gel Processing of Ceramics and Glass; London, 2006.
64. For an account on aqueous sol-gel routes of interest in biochemistry,
65. see: Coiffier, A.; Coradin, T.; Roux, C.; Bouvet, O. M. M.; Livage, J. J. Mater. Chem. 2001, 11, 2039.
66. Cited from www.dy.nasilan.com.
67. First Research Ltd. 2010. Data available at the URL: http://www. firstresearch.com/industry-research/Chemical-ManufacturingIndustrial.html (last time accessed, May 30, 2010).
68. The Future of the Chemical Industry; Jones, R., Ed.; American Chemical Society: Washington, DC, 2010.
69. Remarkably, some of these venture funds were Government-owned, such, as in the case of Canada's SiliCycle Inc.
70. Chem. Eng. News, 2009, 87 (17), 15.
71. For comparison, BASF claims annual cost savings of over 25,000 € using the more expensive acrylic glass entrapped wax as phase change material in a building in Germany. See at the URL: www.micronal.de (Last time accessed: May 27, 2010).
72. Ozin, G. A.; Cademartiri, L. Small 2009, 5, 1240.
73. Lomborg, B. The Wall Street Journal, November 2, 2006.
74. Anastas, P.; Warner, J. Green Chemistry: Theory and Practice; Oxford University Press: Oxford, 2000.
75. Wan, Y.; Zhao, D. Chem. Rev. 2007, 107, 2821.
76. Anderson, P. W. Science 1972, 177, 393. For a recent account on the implications of systems theory for chemistry,
77. see: Reiher, M. Found. Chem. 2003, 5, 23.
78. Yang, Q.; Liu, J.; Zhang, L.; Li, C. J. Mater. Chem. 2009, 19, 1945.
79. Broadwater, S. J.; Roth, S. L.; Price, K. E.; Kobašlija, M.; McQuade, D. T. Org. Biomol. Chem. 2005, 3, 2899.
80. Catalysts for Fine Chemical Synthesis; Roberts, S. M., Ed.; Wiley: New York, 2007.
81. A single report, dealing with core-satellite nanocomposite catalysts protected by a layer of mesoporous silica, shows that these composite structures are good recyclable catalysts:Ge, J.; Zhang, Q.; Zhang, T.; Yin, Y. Angew. Chem., Int. Ed. 2008, 47, 8924.
82. Dahl, J. A.; Maddux, B. L. S.; Hutchison, J. E. Chem. Rev. 2007, 107, 2228.
83. Murphy, C. J. J. Mater. Chem. 2008, 18, 2173.
84. Wiesner, M. R.; Lecoanet, R; Cortalezzi, M. Nanomaterials, Sustainability, and Risk Minimization; IWA International Conference on Nano and Microparticles in Water and Wastewater Treatment, Zurich, Switzerland, 22-24 September 2003.