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38
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85167851578
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note
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From a search in CCDC database for tripodal ligands based on the bis(pyrazolyl)methane fragment not bound to a metal center, 47 ligand structures exhibit the pyrazole rings in an anti conformation, whereas only in 8 structures the pyrazole rings are in a syn conformation. CCDC 2009 Release.
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-
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41
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85167849621
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note
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3 structure would be characterized by a τ[C(33)-C(23)-C(13)-N(11)] of +130.3(7)°.
-
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43
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46749128213
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pyrazole bonds, see:
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44
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