Determination of kinetics and controlling regimes for H2 oxidation on Pt/Al2O3 monolithic catalyst using high space velocity experiments

Applied Catalysis B: Environmental

Volumn 102, Issue 3-4, 2011, Pages 484-495

  Joshi, Saurabh Y ^a   Ren, Yongjie ^a   Harold, Michael P ^a   Balakotaiah, Vemuri ^a  

^a UNIVERSITY OF HOUSTON   (United States)

Author keywords

Hydrogen; Kinetic regime; Mass transfer controlled regime; Monolith reactor; Platinum; Washcoat diffusion; Water

Indexed keywords

AMBIENT TEMPERATURES; CATALYST AGING; CATALYST TEMPERATURE; CATALYTIC-KINETIC; DIFFUSION REGIMES; FRESH CATALYSTS; HIGH ACTIVITY; HIGH DISPERSION; KINETIC REGIME; MASS TRANSPORT COEFFICIENTS; MASS-TRANSPORT PROCESS; MONOLITH REACTOR; MONOLITHIC CATALYSTS; PORE DIFFUSION; PREEXPONENTIAL FACTOR; REGIME TRANSITION; RELATIVE IMPORTANCE; SPACE VELOCITIES; WASHCOATS;

ACTIVATION ANALYSIS; ACTIVATION ENERGY; DIFFUSION; ENZYME IMMOBILIZATION; EXPERIMENTS; HYDROGEN; MONOLITHIC INTEGRATED CIRCUITS; OXIDATION; PLATINUM; REACTION KINETICS; SINTERING; VELOCITY;

CATALYSTS;

EID: 79551540860     PISSN: 09263373     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcatb.2010.12.030     Document Type: Article

References (33)

1. Ogle K.M., White J.M. Surface Science 1984, 139:43-62.
2. Fisher G.B., Gland J.L., Schmieg S.J. Journal of Vacuum Science & Technology 1982, 20:518-521.
3. Hanson F.V., Boudart M. Journal of Catalysis 1978, 53:56-67.
4. Younis L.B. Journal of the Energy Institute 2006, 79:222-227.
5. Brown N.J., Schefer R.W., Robben F. Combustion and Flame 1983, 51:263-277.
6. Rinnemo M., Fassihi M., Kasemo B. Chemical Physics Letters 1993, 211:60-64.
7. Fassihi M., Zhdanov V.P., Rinnemo M., Keck K.E., Kasemo B. Journal of Catalysis 1993, 141:438-452.
8. Pacia N., Dumesic J.A. Journal of Catalysis 1976, 41:155-167.
9. Joshi S.Y., Harold M.P., Balakotaiah V. Chemical Engineering Science 2010, 65:1729-1747.
10. Bhatia D., Harold M.P., Balakotaiah V. Chemical Engineering Science 2009, 64:1544-1558.
11. S.Y. Joshi, Y. Ren, M.P. Harold, V. Balakotaiah, Chemical Engineering Science, to be submitted (2011).
12. Caton J.A. Mechanical Engineering 1977, 99:96-196.
13. Marschall K.J., Mleczko L. Industrial & Engineering Chemistry Research 1999, 38:1813-1821.
14. Deutschmann O., Schmidt L.D. AIChE Journal 1998, 44:2465-2477.
15. Beretta A., Ranzi E., Forzatti P. Chemical Engineering Science 2001, 56:779-787.
16. Bizzi M., Basini L., Saracco G., Specchia V. Industrial & Engineering Chemistry Research 2003, 42:62-71.
17. Kabin K.S., Muncrief R.L., Harold M.P. Catalysis Today 2004, 96:79-89.
18. K. Nagashima, M. Nagata, SAE Technical Paper 2007-01-1134 (2007).
19. Joshi S.Y., Harold M.P., Balakotaiah V. AIChE Journal 2009, 55:1771-1783.
20. West D.H., Balakotaiah V., Jovanovic Z. Catalysis Today 2003, 88:3-16.
21. Balakotaiah V., West D.H. Chemical Engineering Science 2002, 57:1269-1286.
22. Bhattacharya M., Harold M.P., Balakotaiah V. AIChE Journal 2004, 50:2939-2955.
23. Joshi S.Y., Harold M.P., Balakotaiah V. Chemical Engineering Science 2009, 64:4976-4991.
24. Ullah U., Waldram S.P., Bennett C.J., Truex T. Chemical Engineering Science 1992, 47:2413-2418.
25. Santos H., Costa M. International Journal of Heat and Mass Transfer 2008, 51:1409-1422.
26. Bennett C.J., Kolaczkowski S.T., Thomas W.J. Process Safety and Environmental Protection 1991, 69:209-220.
27. Holmgren A., Andersson B. Chemical Engineering Science 1998, 53:2285-2298.
28. Votruba J., Mikus O., Nguen K., Hlavacek V., Skrivanek J. Chemical Engineering Science 1975, 30:201-206.
29. Gupta N., Balakotaiah V. Chemical Engineering Science 2001, 56:4771-4786.
30. Clayton R.D., Harold M.P., Balakotaiah V., Wan C.Z. Applied Catalysis B-Environmental 2009, 90:662-676.
31. Mukadi L.S., Hayes R.E. Computers and Chemical Engineering 2002, 26:439-455.
32. Rajagopalan K., Luss D. Industrial & Engineering Chemistry Process Design and Development 1979, 18:459-465.
33. Balakotaiah V. Chemical Engineering Science 2008, 63:5802-5812.