Thermal degradation kinetics and isoconversional analysis of biodegradable poly(3-hydroxybutyrate)/organomodified montmorillonite nanocomposites

Thermochimica Acta

Volumn 514, Issue 1-2, 2011, Pages 58-66

  Achilias, Dimitris S ^a   Panayotidou, Elpiniki ^a,b   Zuburtikudis, Ioannis ^b  

^a ARISTOTLE UNIVERSITY OF THESSALONIKI   (Greece)

^b TEI of Western Macedonia ^*  (Greece)

Author keywords

Biodegradable polymers; Degradation kinetics; Isoconversional analysis; Nanocomposites; Poly(3 hydroxybutyrate)

Indexed keywords

DEGRADATION KINETICS; DEGREE OF DEGRADATION; EXPERIMENTAL DATA; INTERCALATED STRUCTURES; ISO-CONVERSIONAL METHOD; ISOCONVERSIONAL ANALYSIS; KINETIC ANALYSIS; KINETIC RATE CONSTANTS; MELT MIXING; MODIFIED CLAYS; NANOFILLER; ONE STEP; ORGANO-MODIFIED MONTMORILLONITES; POLY(3-HYDROXYBUTYRATE); PREEXPONENTIAL FACTOR; REACTION MODEL; THERMAL DEGRADATION KINETICS; THERMAL STABILITY; WIDE-ANGLE X-RAY DIFFRACTION;

ACTIVATION ANALYSIS; ACTIVATION ENERGY; BIODEGRADABLE POLYMERS; CLAY MINERALS; DEGRADATION; FILLERS; KINETIC PARAMETERS; NANOCOMPOSITES; RATE CONSTANTS; SILICATE MINERALS; THERMODYNAMIC STABILITY; X RAY DIFFRACTION;

THERMOGRAVIMETRIC ANALYSIS;

EID: 79551505452     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2010.12.003     Document Type: Article

References (38)

1. E.G. Fernandes, M. Pietrini, and E. Chiellini Thermo-mechanical and morphological characterization of plasticized poly [(R)-3-hydroxybutyric acid] Macrom. Symp. 218 2004 157 164
2. S.N. Lee, M.Y. Lee, and W.H. Park Thermal stabilization of poly(3-hydroxybutyrate) by poly(glycidyl methacrylate) J. Appl. Polym. Sci. 83 2002 2945 2952
3. P. Bordes, E. Pollet, and L. Averous Nano-biocomposites: biodegradable polyester/nanoclay systems Prog. Polym. Sci. 34 2009 125 155
4. D.S. Achilias, M.M. Karabela, and I.D. Sideridou Thermal degradation of light-cured dimethacrylate resins Part I. Isoconversional kinetic analysis Thermochim. Acta 472 2008 74 83
5. D.S. Achilias, M.M. Karabela, and I.D. Sideridou Thermal degradation and isoconversional kinetic analysis of light-cured dimethacrylate copolymers J. Therm. Anal. Calorim. 99 2010 917 923
6. S. Vyazovkin, and N. Sbirrazzuoli Isoconversional kinetic analysis of thermally stimulated processes in polymers Macromol. Rapid Commun. 27 2006 1515 1532
7. C. Chen, B. Fei, S. Peng, Y. Zhuang, L. Dong, and Z. Feng The kinetics of the thermal decomposition of poly(3-hydroxybutyrate) and maleated poly(3-hydroxybutyrate) J. Appl. Polym. Sci. 84 2002 1789 1796
8. M.Y. Lee, T.S. Lee, and W.H. Park Effect of side chains on the thermal degradation of poly(3-hydroxybutyrate) Macromol. Chem. Phys. 202 2001 1257 1261
9. S.D. Li, J.D. He, P.H. Yu, and M.K. Cheung Thermal degradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hysroxyvalerate) as studied by TG TG-FTIR and Py-GC/MS J. Appl. Polym. Sci. 89 2003 1530 1536
10. A.F. Santos, L. Polese, M.S. Crespi, and C.A. Ribeiro Kinetic model of poly(3-hydroxybutyrate) thermal degradation from experimental non-isothermal data J. Therm. Anal. Calorim. 96 2009 287 291
11. H. Ariffin, H. Nishida, Y. Shirai, and M.H. Hassan Determination of multiple thermal degradation mechanisms of poly(3-hydroxybutyrate) Polym. Degrad. Stabil. 93 2008 1433 1439
12. M. Kawalec, H. Janeczek, G. Adamus, P. Kurcok, M. Kowalczuk, and M. Scandola The study of kinetics of poly[(R,S)-3-hydroxybutyrate] degradation induced by carboxylate Macromol. Symp. 272 2008 63 69
13. E. Hablot, P. Bordes, E. Pollet, and L. Averous Thermal and thermo-mechanical degradation of poly(3-hydroxybutyrate)-based multiphase systems Polym. Degrad. Stab. 93 2008 413 421
14. P. Bordes, E. Hablot, E. Pollet, and L. Averous Effect of clay organomodifiers on degradation of polyhydroxyalkanoates Polym. Degrad. Stab. 94 2009 789 796
15. M. Erceg, T. Kovacic, and S. Perinovic Kinetic analysis of the non-isothermal degradation of poly(3-hydroxybutyrate) nanocomposites Thermochim. Acta 476 2008 44 50
16. M. Erceg, T. Kovacic, and I. Klaric Thermal degradation and kinetic analysis of poly(3-hydroxybutyrate)/organoclay nanocomposites Macromol. Symp. 267 2008 57 62
17. M. Erceg, T. Kovacic, and I. Klaric Poly(3-hydroxybutyrate) nanocomposites: isothermal degradation and kinetic analysis Thermochim. Acta 485 2009 26 32
18. T.M. Wu, S.F. Hsu, Y.F. Shih, and C.S. Liao Thermal degradation kinetics of biodegradable poly(3-hydroxybutyrate)/layered double hydroxide nanocomposites J. Polym. Sci.: Part B: Polym. Phys. 46 2008 1207 1213
19. S.I. Marras, A. Tsimpliaraki, I. Zuburtikudis, and C. Panayiotou Thermal and colloidal behavior of amine-treated clays: the role of amphiphilic organic cation concentration J. Colloid Interf. Sci. 315 2007 520
20. J.D. Peterson, S. Vyazovkin, and C.A. Wight Kinetics of the thermal and thermo-oxidative degradation of polystyrene, polyethylene and polypropylene Macromol. Chem. Phys. 202 2001 775 784
21. H.L. Friedman Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to phenolic plastic J. Polym. Sci. C: Polym. Symp 6PC 1964 183 195
22. C.D. Doyle Kinetic analysis of thermogravimetric data J. Appl. Polym. Sci. 5 1961 285 292
23. J.H. Flynn, and L.A. Wall General treatment of the thermogravimetry of polymers J. Res. Natl. Bur. Stand. 70A 1966 487 523
24. T. Ozawa A new method of analyzing Thermogravimetric data Bull. Chem. Soc. Jpn. 38 1965 1881 1886
25. S. Vyazovkin Modification of the integral isoconversional method to account for variation in the activation energy J. Comput. Chem. 22 2001 178 183
26. S. Vyazovkin Evaluation of activation energy of thermally stimulated solid state reactions under arbitrary variation of temperature J. Comput. Chem. 18 1997 393 402
27. H.E. Kissinger Anal. Chem. 29 1957 1702
28. P. Budrugeac, and E. Segal Applicability of the Kissinger equation in thermal analysis, Revisited J. Therm. Anal. Calorim. 88 2007 703 707
29. F.J. Gotor, J.M. Criado, J. Malek, and N. Koga Kinetic analysis of solid-state reactions: the universality of master plots for analyzing isothermal and nonisothermal experiments J. Phys. Chem. A 104 46 2000 10777 10782
30. J.M. Criado, J. Malek, and A. Ortega Applicability of the master plots in kinetic analysis of non-isothermal data Thermochim. Acta 147 1989 377 385
31. L.A. Perez-Maqueda, J.M. Criado, F.J. Gotor, and J. Malek Advantages of combined kinetic analysis of experimental data obtained under any heating profile J. Phys. Chem. A 106 12 2002 2862 2868
32. P. Budrugeac, E. Segal, L.A. Perez-Maqueda, and J.M. Criado The use of the IKP method for evaluating the kinetic parameters and the conversion function of the thermal dehydrochlorination of PVC from non-isothermal data Polym. Degrad. Stabil. 84 2004 311 320
33. A.W. Coats, and J.P. Redfern Nature 201 1964 68
34. A.I. Lesnikovich, and S.V. Levchik A method of finding invariant values of kinetic-parameters J. Therm. Anal. 27 1983 89 94
35. F.D. Kopinke, and K. Mackenzie Mechanistic aspects of the thermal degradation of poly(lactic acid) and poly(β-hydroxybutyric acid) J. Anal. Appl. Pyrol. 40-41 1997 43 53
36. L. Nunez, F. Fraga, M.R. Nunez, and M. Villanueva Thermogravimetric study of the decomposition process of the system BADGE (n = 0)/1, 2 DCH Polymer 41 2000 4635 4641
37. K. Chen, C.A. Wilkie, and S. Vyazovkin Nanoconfinement revealed in degradation and relaxation studies of two structurally different polystyrene-clay systems J. Phys. Chem. B 111 2007 12685 12692
38. K. Chen, K. Harris, and S. Vyazovkin Tacticity as a factor contributing to the thermal stability of polystyrene Macromol. Chem. Phys. 208 2007 2525 2532