A novel method for sulfonation of microporous polystyrene divinyl benzene copolymer using gaseous SO2 in the waste air streams

Chemical Engineering and Processing: Process Intensification

Volumn 50, Issue 1, 2011, Pages 16-21

  Ergenekon, Pinar ^a   Gürbulak, Ercan ^a   Keskinler, Bülent ^a  

^a GEBZE TECHNICAL UNIVERSITY   (Turkey)

Author keywords

Clean technologies; Microporous styrene divinyl benzene copolymer; SO2 control; Sulfonation; Sulfonation method

Indexed keywords

ADSORPTION CAPACITIES; BREAK THROUGH CURVE; CLEAN TECHNOLOGIES; DIVINYL BENZENES; EFFLUENT GAS; IR ANALYSIS; MICRO-POROUS; MORPHOLOGICAL STRUCTURES; NOVEL METHODS; POLYMER DISKS; SEM; SO2 CONTROL; SULFONATION DEGREE; VOLUME PERCENTAGE; WASTE AIR; WASTE GAS STREAM;

ADSORPTION; BENZENE; COPOLYMERIZATION; COPOLYMERS; DISKS (STRUCTURAL COMPONENTS); EFFLUENTS; MICROPOROSITY; POLYMERS; POLYSTYRENES; STYRENE;

SULFONATION;

EID: 79251601299     PISSN: 02552701     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cep.2010.10.009     Document Type: Article

References (20)

1. Naderi M., Dale J.A., Parkes G.M.B., Brown D.R. Solvation of exchangeable cations in sulfonated polystyrene ion-exchange resins: an ESR study. React. Funct. Polym. 2002, 51:25-31. doi:10.1016/S1381-5148(02)00026-3.
2. Rubinger C.P.L., Martins C.R., De Paoli M.A., et al. Sulfonated polystyrene polymer humidity sensor: synthesis and characterization. Sens. Actuators B 2007, 123:42-49. doi:10.1016/j.snb.2006.07.019.
3. Opekar F., Stulik K. Electrochemical sensors with solid polymer electrolytes. Anal. Chim. Acta 1999, 385:151-162.
4. Carreta N., Tricoli V., Picchioni F. Ionomeric membranes based on partially poly(styrene): synthesis, proton conduction and methanol permeation. J. Membr. Sci. 2000, 166:189-197.
5. Hickner M.A., Ghassemi H., Kim Y.S., Einsla R., McGrath J. Alternative polymer systems for proton exchange membranes (PEMs). Chem. Rev. 2004, 104:4587-4611. doi:10.1021/cr020711a.
6. Alberti G., Casciola M., Massinelli L., Bauer B. Polymeric proton conducting membranes for medium temperature fuel cells (110-160°C). J. Membr. Sci. 2001, 185:73-81. doi:10.1016/S0376-7388(00)00635-9.
7. Kučera F., Jančář J. Homogeneous and heterogeneous sulfonation of polymers: a review. Polym. Eng. Sci. 1998, 38:783-792.
8. F. Kučera, Homogeneous and heterogeneous sulfonation of polystyrene, PhD Thesis, Brno University of Technology, Brno, Czech Repuclic, 2001.
9. D. Barby, Z. Haq, Low density porous cross linked polymeric materials and their preparation and use as carriers for included liquids, U.S. Patent 4,522,953, 1985.
10. Meyer U., Svec F., Frechet J.M.J., Hawker C.J. Use of stable free radicals for the sequential preparation and surface grafting of functionalized macroporous monoliths. Macromolecules 2000, 33:7769-7775.
11. Svec F., Peters E.C., Sykora D., Frechet J.M.J. Design of the monolithic polymers used in capillary electrochromatography columns. J. Chromatogr. A 2000, 887:3-29.
12. Akay G., Birch M.A., Bokhari M.A. Microcellular polyHIPE polymer supports osteoblast growth and bone formation in vitro. Biomaterials 2004, 25:3991-4000. doi:10.1016/j.biomaterials.2003.10.086.
13. Hayman M.W., Smith K.H., Cameron N.R., Przyborski S.A. Growth of human stem cell-derived neurons on solid three-dimensional polymers. J. Biochem. Biophys. Meth. 2005, 62:231-240.
14. Kara S., Keskinler B., Erhan E. A novel microbial BOD biosensor developed by the immobilization of P. Syringae in micro-cellular polymers. J. Chem. Technol. Biotechnol. 2009, 84:511-518. doi:101002/jctb.2071.
15. Karagöz P., Erhan E., Keskinler B., Ozkan M. The use of microporous divinyl benzene copolymer for yeast cell immobilization and ethanol production in packed-bed reactor. Appl. Biochem. Biotechnol. 2009, 152:66-73. doi:10.1007/s12010-008-8336-7.
16. Cameron N.R. High internal phase emulsion templating as a route to well-defined porous polymers. Polymer 2005, 46:1439-1449.
17. Gupta A., Gaur V., Verma N. Breakthrough analysis for adsorption of sulfur-dioxide over zeolites. Chem. Eng. Process. 2004, 43:9-22.
18. Davini P. The effect of certain metallic derivatives on the adsorption of sulphur dioxide on active carbon. Carbon 2001, 39:419-424.
19. Kim H., Park D.W., Woo H.C., Chung J.S. Reduction of SO2 by CO to elemental sulfur over Co3O4-TiO2 catalysts. Appl. Catal. B 1998, 10:233.
20. Wang X., Wang A., Ning L., Wang X., Liu Z., Zhang T. Catalytic reduction of SO2 with CO over supported iron catalysts. Ind. Eng. Chem. Res. 2006, 45:4582-4588.