Protonation behavior of 6-deoxy-6-(2-aminoethyl)amino cellulose: A potentiometric titration study

Cellulose

Volumn 18, Issue 1, 2011, Pages 33-43

  Zemljič, Lidija Fras ^a   Čakara, Duško ^b   Michaelis, Nico ^c   Heinze, Thomas ^c   Kleinschek, Karin Stana ^a  

^a UNIVERSITY OF MARIBOR   (Slovenia)

^b Centre for High throughput Technologies Radmile Matej i 2   (Croatia)

^c FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

Aminocellulose; Cationic polysaccharides; Charging; Isotherms; Model; pK; Potentiometric; Protonation; Titration

Indexed keywords

AMINATION; AMINES; BINDING ENERGY; BINDING SITES; CELLULOSE; CHARGING (FURNACE); FREE ENERGY; ISOTHERMS; MODELS; POTENTIOMETERS (ELECTRIC MEASURING INSTRUMENTS); PROTONATION; VOLTAMMETRY;

AMINOCELLULOSE; CATIONIC POLYSACCHARIDE; DEGREE OF PROTONATION; ELECTROSTATIC REPULSION; POTENTIOMETRIC; POTENTIOMETRIC TITRATIONS; PRIMARY AND SECONDARY AMINE; PROTONATION FREE ENERGY;

TITRATION;

EID: 79251597938     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-010-9467-x     Document Type: Article

References (49)

1. Aksberg R, Ödberg L (1990) Adsorption of an anionic polyacrylamide on cellulosic fibers with pre-adsorbed cationic polyelectrolytes. Nord Pulp and Paper Res J 411990: 168-171.
2. Avci D, Nuri M, Dagusan L (2002) New cationic polyelectrolytes for flocculation processes of baker's yeast waste water. Polym Bull 48(4-5): 353-359.
3. Baumann H, Keller B, Ruzicka E (1991) Partially cationized cellulose for non-thrombogenic membrane in the presence of heparin and endothelial-cell-surface-heparansulfate (ES-HS). J Membrane Sci 61: 253-268.
4. Berger J, Reist M, Mayer JM, Felt O, Peppas NA, Gurny R (2004) Structure and interactions in covalently and ionically crosslinked chitosan hydrogels for biomedical applications. Eur J Pharm Biopharm 57: 19-34.
5. Berlin P, Klemm D, Jung A, Liebegott H, Rieseler R, Tiller J (2003) Film-forming aminocellulose derivatives as enzyme-compatible support matrices for biosensor developments. Cellulose 10: 343-367.
6. Berscht PC, Nies B, Liebendorfer A, Kreuter J (1994) Incorporation of basic fibroblast growth factor into methylpyrrolidinone chitosan fleeces and determination of the in vitro release characteristics. Biomaterials 15: 593-600.
7. Borkovec M, Koper GJM (1994) Ising models of polyprotic acids and bases. J Phys Chem 98: 6038-6045.
8. Borkovec M, Jönsson B, Koper GJM (2001) Ionization processes and proton binding in polyprotic systems: small molecules, proteins, interfaces and polyelectrolytes. In: Matijević E (ed) Prog Coll Pol Sci 16: 99-339.
9. Borkovec M, Koper GJM, Piguet C (2006) Ion binding to polyelectrolytes. Curr Opin Colloid Interface Sci 11(5): 280-289.
10. Čakara D, Fras L, Bračič M, Stana Kleinschek K (2009) Protonation behaviour of cotton fabric with irreversibly adsorbed chitosan: a potentiometric titration study. Carbohyd Polym 78: 36-40.
11. Culler MD, Bitman J, Thompson MJ, Robbins WE, Dutky SR (1979) Mastitis: I. In vitro antimicrobial activity of alkyl amines against mastitic bacteria. J Dairy Sci 62: 584-595.
12. Czaja W, Krystynowicz A, Bielecki Sand Brown RM (2006) Microbial cellulose. The natural power to heal wounds. Biomaterials 27(2): 145-151.
13. Dobrynin AV, Rubinstein M (1999) Hydrophobic polyelectrolytes. Macromolecules 32(3): 915-922.
14. Dobrynin AV, Rubinstein M (2005) Theory of polyelectrolytes in solutions and at surfaces. Prog Poly Sci 30(11): 1049-1118.
15. Dumitriu S (2002) Polymeric biomaterials, 2nd edn (revised and expanded). Marcel Dekker, Inc., New York, pp 1-213.
16. Gärdlund L, Norgren M, Wägberg L, Marklund A (2007) The use of polyelectrolyte complexes (PEC) as strength additives for different pulps used for production of fine paper. Nord Pulp Paper Res 22(2): 210-216.
17. Goyal S, Dhull SK, Kapoor KK (2005) Chemical and biological changes during composting of different organic wastes and assessment of composting maturity. Bioresour Technol 96: 1584-1591.
18. Hashem A, Shishtawy RME (2001) Preparation and characterization of cationized cellulose for the removal of anionic dyes. Adsorpt Sci Technol 19: 197-210.
19. Hattori K, Yoshida T, Nakashima H, Premanathan M, Aragaki R, Mimura T, Kaneko Y, Yamamo N, Uryu T (1998) Synthesis of sulfonated amino polysaccharides having anti-HIV and blood anticoagulant activities. Carbohyd Res 312: 1-8.
20. Hebeish A, Hashem M, EL-Hosamy M, Abass S (2006) Cationization of linen fabric: studying the process parameters. RJTA 10(1): 73-88.
21. Hoenich N (2006) Cellulose for medical applications: past, present, and future. BioResources 1(2): 270-280.
22. Holm C, Joanny JF, Kremer K, Netz RR, Reineker P, Seidel C, Vilgis TA, Winkler RG (2004) Polyelectrolyte theory. In: Polyelectrolytes with defined molecular architecture II, vol 166. Springer, Berlin, pp 67-111.
23. 2+-chelating properties. Cellulose 12: 67-84.
24. Kaputskii FN, Gert EV, Torgashov VI, Zubets OV (2005) Hydrogels for medical applications fabricated by oxidative-hydrolytic modification of cellulose. Fibre Chem 37: 485-489.
25. Katchalsky A, Mazur J, Spitnik P (1957) Section II: polybase properties of polyvinylamine. J Polym Sci 23(104): 513-532.
26. Koper GJM, van Genderen MHP, Elissen Roman C, Baars M, Meijer EW, Borkovec M (1997) Protonation mechanism of poly(propylene imine) dendrimers and some associated oligo amines. J Am Chem Soc 119(28): 6512-6521.
27. Koper GJM, van Duijvenbode RC, Stam D, Steuerle U, Borkovec A (2003) Synthesis and protonation behavior of comblike poly(ethyleneimine). Macromolecules 36(7): 2500-2507.
28. Li H, Du Y, Xu Y (2004) Adsorption and complexation of chitosan wet-end additives in papermaking systems. J Appl Polym Sci 91: 2642-2648.
29. Liesene J (2009) Synthesis of water-soluble cationic cellulose derivatives with tertiary amino groups. Cellulose 17: 167-172.
30. Lim SH, Hudson SM (2004) Synthesis and antimicrobial activity of a water-soluble chitosan derivative with a fiber-reactive group. Carbohyd Res 339(2): 313-319.
31. Manning GS (1981) Limiting laws and counterion condensation in polyelectrolyte solutions. 6. Theory of the titration curve. J Phys Chem US 85(7): 870-877.
32. Marcus RA (1954) Titration of polyelectrolytes at higher ionic strengths. J Phys Chem US 58(8): 621-623.
33. Mesquita JP, Donnici LC, Pereira FV (2010) Biobased nanocomposites from layer by-layer assembly of cellulose nanowhiskers with chitosan. Biomacromolecules 11: 473-480.
34. Montplaisir D, Daneault C, Chabot B (2008) Surface composition of grafted thermomechanical pulp through XPS measurements. BioResources 3(4): 1118-1129.
35. Muzzarelli RAA (2009) Chitins and chitosan for the repair of wound skin, nerve, cartilage and bone. Carbohyd Polym 76: 167-182.
36. Muzzarelli RAA, Mattioli-Belmonte M, Tietz C, Biagini R, Ferioli G, Brunelli MA, Fini M, Giardino R, Ilari P, Biagini G (1994) Stimulatory effect on bone formation exerted by a modified chitosan. Biomaterials 15: 1075-1081.
37. Myllytie P, Salmi J, Laine J (2009) The influence of pH on the adsorption and interaction of chitosan with cellulose. BioResources 4(4): 1647-1662.
38. Packham RF (2007) The laboratory evaluation of polyelectrolyte flocculants. Brit Polym J 4(4): 305-315.
39. Pecse A, Jordane AA, Carluci G, Cintio A (2005) Articles comprising caionic polysaccharides and acidic pH buffering means. US Patent Application Publication: 0124799 A1.
40. Ravi Kumar MNV (2000) A review of chitin and chitosan applications. React Funct Polym 46: 1-27.
41. Rodríguez R, Alvarez-Lorenzo C, Concheiro A (2003) A Cationic cellulose hydrogels: kinetics of the cross-linking process and characterization as pH-/ion-sensitive drug delivery systems. J Control Release 86(2-3): 253-265.
42. Smith RM, Martell AE (1989) Critical stability constants, vol 6. Plenum Press, New York.
43. Swerin A, Wägberg L (1994) Size exclusion chromatography for characterisation of cationic polyelectrolytes used in papermaking. Nordic Pulp Paper Res J 411994: 18-26.
44. Swerin A, Odberg L, Lindström T (1990) Deswelling of hardwood kraft pulp fibres by cationic polymers. Nordic Pulp Paper Res J 411990: 188-196.
45. Szakacs Z, Kraszni M, Noszal B (2004) Determination of microscopic acid-base parameters from NMR-pH titrations. Anal Bioanal Chem 378(6): 1428-1448.
46. Ulrich S, Laguecir A, Stoll S (2005) Titration of hydrophobic polyelectrolytes using Monte Carlo simulations. J Chem Phys 122(9): 094911-094919.
47. van Duijvenbode RC, Rajanayagam A, Koper GJM, Borkovec M, Paulus W, Steuerle U, Haussling L (1999) Influence of the distance between ionizable groups on the protonation behavior of various hexaamines. Phys Chem Chem Phys 1(24): 5649-5652.
48. Wu M, Kuga S (2006) Cationization of cellulose fabrics by polyallyamine binding. J Appl Polym Sci 100: 1668-1672.
49. Yang S, Fu S, Li X, Zhore Y, Zhan H (2010) Preparation of salt-sensitive and antibacterial hydrogel based on quaternized cellulose. BioResources 5(2): 1114-1125.