Air-sea exchange of dimethylsulfide in the Southern Ocean: Measurements from so GasEx compared to temperate and tropical regions

Journal of Geophysical Research: Oceans

Volumn 116, Issue 8, 2011, Pages

  Yang, M ^a   Blomquist, B W ^a   Fairall, C W ^b   Archer, S D ^c   Huebert, B J ^a  

^a UNIVERSITY OF HAWAII   (United States)

^b NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^c PLYMOUTH MARINE LABORATORY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; OCEANOGRAPHY; SEAWATER; SOLUBILITY;

AIR-SEA EXCHANGE; BREAKING WAVES; DIMETHYLSULFIDE; EAST PACIFIC; EDDY COVARIANCE; FIELD STUDIES; GAS EXCHANGE; HIGH WINDS; NORTH EAST ATLANTIC; SOLUBLE GAS; SOUTHERN OCEAN; TEMPERATURE DEPENDENCE; TRANSFER VELOCITY; TROPICAL REGIONS;

DIAMONDS;

AIR-SEA INTERACTION; DIFFUSION; DIMETHYLSULFIDE; EDDY COVARIANCE; EXPERIMENTAL STUDY; GAS EXCHANGE; MEASUREMENT METHOD; POTASSIUM; SOLUBILIZATION; TEMPERATE ENVIRONMENT; TEMPERATURE EFFECT; TROPICAL REGION;

ATLANTIC OCEAN; ATLANTIC OCEAN (NORTHEAST); PACIFIC OCEAN; PACIFIC OCEAN (SOUTHEAST); SOUTHERN OCEAN;

EID: 79251505333     PISSN: None     EISSN: 21699291     Source Type: Journal    
DOI: 10.1029/2010JC006526     Document Type: Article

References (46)

1. Archer, S. D., L. E. Goldson, M. I. Liddicoat, D. G. Cummings, and P. D. Nightingale (2007), Marked seasonality in the concentrations and sea-to-air flux of volatile iodocarbon compounds in the western English Channel, J. Geophys. Res., 112, C08009, doi:10.1029/2006JC003963. (Pubitemid 47604125)
2. Asher, W. E., L. M. Karle, B. J. Higgins, P. J. Farley, E. C. Monahan, and I. S. Leifer (1996), The influence of bubble plumes on air-water gas transfer velocities, J. Geophys. Res., 101, 12,027-12,041, doi:10.1029/ 96JC00121. (Pubitemid 126668262)
3. Banner, M. L., and W. L. Peirson (1998), Tangential stress beneath wind-driven air-water interfaces, J. Fluid Mech., 364, 115-145, doi:10.1017/S0022112098001128. (Pubitemid 128488637)
4. Banner, M. L., I. S. F. Jones, and J. C. Trinder (1989), Wave number spectra of short gravity waves, J. Fluid Mech., 198, 321-344, doi:10.1017/S0022112089000157.
5. Bates, T. S., P. K. Quinn, D. S. Covert, D. J. Coffman, J. E. Johnson, and A. Wiedensohler (2000), Aerosol physical properties and processes in the lower marine boundary layer: A comparison of shipboard sub-micron data from ACE-1 and ACE-2, Tellus, Ser. B, 52, 258-272, doi:10.1034/j.1600-0889.2000. 00021.x. (Pubitemid 30333962)
6. Blomquist, B., C. W. Fairall, B. J. Huebert, D. Kieber, and G. Westby (2006), DMS sea-air transfer velocity: Direct measurements by eddy covariance and parameterization based on the NOAA/COARE gas transfer model, Geophys. Res. Lett, 33, L07601, doi:10.1029/2006GL025735. (Pubitemid 43772892)
7. Blomquist, B. W., B. J. Huebert, C. W. Fairall, and I. C. Faloona (2010), Determining the sea-air flux of dimethylsulfide by eddy correlation using mass spectrometry, Atmos. Meas. Tech., 3, 1-20, doi:10.5194/amt-3-1-2010.
8. Charlson, R. J., J. E. Lovelock, M. O. Andreae, and S. G. Warren (1987), Oceanic phytoplankton, atmospheric sulfur, cloud albedo and climate, Nature, 326, 655-661, doi:10.1038/326655a0. (Pubitemid 17604026)
9. Cipriano, R. J., and D. C. Blanchard (1981), Bubble and aerosol spectra produced by a laboratory 'breaking wave,' J. Geophys. Res., 86, 8085-8092, doi:10.1029/JC086iC09p08085.
10. Csanady, G. T. (1978), Turbulent interface layers, J. Geophys. Res., 83, 2329-2342, doi:10.1029/JC083iC05p02329.
11. Csanady, G. T. (1990), The role of breaking wavelets in air-sea gas transfer, J. Geophys. Res., 95, 749-759, doi:10.1029/JC095iC01p00749.
12. Dacey, J. W. H., S. G. Wakeham, and B. L. Howes (1984), Henry's law constants for dimethylsulfide in freshwater and seawater, Geophys. Res. Lett, 11, 991-994, doi:10.1029/GL011i010p00991.
13. Elliott, S. (2009), Dependence of DMS global sea-air flux distribution on transfer velocity and concentration field type, J. Geophys. Res., 114, G02001, doi:10.1029/2008JG000710.
14. Fairall, C. W., E. F. Bradley, J. E. Hare, A. A. Grachev, and J. B. Edson (2003), Bulk parameterization of air-sea fluxes: Updates and verification for the COARE algorithm, J. Clim., 16, 571-591, doi:10.1175/1520-0442(2003) 016〈0571:BPOASF〉2.0.CO;2. (Pubitemid 37164410)
15. Frew, N. M., et al. (2004), Air-sea gas transfer: Its dependence on wind stress, small-scale roughness, and surface films, J. Geophys. Res., 109, C08S17, doi:10.1029/2003JC002131. (Pubitemid 39437410)
16. Gabric, A. J., R. Simó, R. A. Cropp, A. C. Hirst, and J. Dachs (2004), Modeling estimates of the global emission of dimethylsulfide under enhanced greenhouse conditions, Global Biogeochem. Cycles, 18, GB2014, doi:10.1029/2003GB002183. (Pubitemid 39333037)
17. Ho, D. T., C. S. Law, M. J. Smith, P. Schlosser, M. Harvey, and P. Hill (2006), Measurements of air-sea gas exchange at high wind speeds in the Southern Ocean: Implications for global parameterizations, Geophys. Res. Lett, 33, L16611, doi:10.1029/2006GL026817. (Pubitemid 44945736)
18. Ho, D. T., R. Wanninkhof, P. Schlosser, D. S. Ullman, D. Hebert, and K. F. Sullivan (2011a), Toward a universal relationship between wind speed and gas exchange: Gas transfer velocities measured with 3He/SF6 during the Southern Ocean Gas Exchange Experiment, J. Geophys. Res., doi:10.1029/2010JC006854, in press.
19. Ho, D. T., C. L. Sabine, D. Hebert, D. S. Ullman, R. Wanninkhof, R. C. Hamme, P. G. Strutton, B. Hales, J. B. Edson, and B. R. Hargreaves (2011b), Southern Ocean Gas Exchange Experiment: Setting the stage, J. Geophys. Res., doi:10.1029/2010JC006852, in press.
20. Horst, T. W., and J. C. Weil (1994), How far is far enough? The fetch requirements for micrometeorological measurement of surface fluxes, J. Atmos. Oceanic Technol., 11, 1018-1025, doi:10.1175/1520-0426(1994) 011〈1018:HFIFET〉2.0.CO;2.
21. Huebert, B. J., B. W. Blomquist, J. E. Hare, C. W. Fairall, J. E. Johnson, and T. S. Bates (2004), Measurement of the sea-air DMS flux and transfer velocity using eddy correlation, Geophys. Res. Lett., 31, L23113, doi:10.1029/2004GL021567. (Pubitemid 40482421)
22. Huebert, B., B. Blomquist, M. Yang, S. Archer, P. Nightingale, M. Yelland, J. Stephens, R. Pascal, and B. Moat (2010), Linearity of DMS transfer coefficient with both friction velocity and wind speed in the moderate wind speed range, Geophys. Res. Lett., 37, L01605, doi:10.1029/2009GL041203.
23. Kaimal, J., J. Wyngaard, Y. Izumi, and O. Coté (1972), Spectral characteristics of surface layer turbulence, Q. J. R. Meteorol. Soc, 98, 563-589, doi:10.1002/qj.49709841707.
24. Keeling, R. F. (1993), On the role of large bubbles in air-sea gas exchange and supersaturation in the ocean, J. Mar. Res., 51, 237-271, doi:10.1357/0022240933223800. (Pubitemid 24395246)
25. Kiene, R. P., and S. K. Service (1991), Decomposition of dissolved DMSP and DMS in estuarine waters: Dependence on temperature and substrate concentration, Mar. Ecol. Prog. Ser., 76(1), 1-11, doi:10.3354/meps076001.
26. Liss, P. S., and L. Merlivat (1986), Air-sea gas exchange rates: Introduction and synthesis, in The Role of Air-Sea Interactions in Geochemical Cycling, edited by P. Buat-Menard, pp. 113-129, D. Reidel, Hingham, Mass.
27. Liss, P. S., and P. G. Slater (1974), Flux of gases across the air-sea interface, Nature, 247, 181-184, doi:10.1038/247181a0.
28. Lovelock, J. E., R. J. Maggs, and R. A. Rasmussen (1972), Atmospheric dimethyl sulphide and the natural sulphur cycle, Nature, 237, 452-453, doi:10.1038/237452a0.
29. Marandino, C. A., W. J. De Bruyn, S. D. Miller, and E. S. Saltzman (2009), Open ocean DMS air/sea fluxes over the eastern South Pacific Ocean, Atmos. Chem. Phys., 9, 345-356, doi:10.5194/acp-9-345-2009.
30. McGillis, W. R., J. W. H. Dacey, N. M. Frew, E. J. Bock, and R. K. Nelson (2000), Water-air flux of dimethylsulfide, J. Geophys. Res., 105,1187-1193, doi:10.1029/1999JC900243.
31. McGillis, W. R., et al. (2004), Air-sea CO2 exchange in the equatorial Pacific, J. Geophys. Res., 109, C08S02, doi:10.1029/2003JC002256. (Pubitemid 39437395)
32. Memery, L., and L. Merlivat (1985), Modelling of gas flux through bubbles at the air-water interface, Tellus, Ser. B, 37, 272-285, doi:10.1111/j.1600- 0889.1985.tb00075.x.
33. Monahan, E. C, and I. G. O'Muircheartaigh (1980), Optimal power-law description of oceanic whitecap coverage on wind speed, J. Phys. Oceanogr., 10, 2094-2099, doi:10.1175/1520-0485(1980)010〈2094: OPLDOO〉2.0.CO;2.
34. Monahan, E. C, and M. C. Spillane (1984), The role of whitecaps in air-sea gas exchange, in Gas Transfer at Water Surfaces, edited by G. H. Jirka and W. Brutsaert, pp. 495-504, D. Reidel, Norwell, Mass.
35. Monahan, E. C, and C. R. Zeitlow (1969), Laboratory comparisons of freshwater and salt-water whitecaps, J. Geophys. Res., 74, 6961-6966, doi:10.1029/JC074i028p06961.
36. Mueller, J. A., and F. Veron (2009), Nonlinear formulation of the bulk surface stress over breaking waves: Feedback mechanisms from air-flow separation, Boundary Layer Meteorol, 130(1), 117-134, doi: 10.1007/s10546-008- 9334-6.
37. Nightingale, P. D., G. Malin, C. S. Law, A. J. Watson, P. S. Liss, M. J. Liddicoat, J. Boutin, and R. C. Upstill-Goddard (2000), In situ evaluation of air-sea gas exchange using novel conservative and volatile tracers, Global Biogeochem. Cycles, 14, 373-387, doi:10.1029/1999GB900091.
38. Rhee, T. S., P. D.Nightingale, D. K. Woolf, G. Caulliez,P. Bower, andM. O. Andreae (2007), Influence of energetic wind and waves on gas transfer in a large wind-wave tunnel facility, J. Geophys. Res., 112, C05027, doi:10.1029/2005JC003358.
39. Saltzman, E. S., D. B. King, K. Holmen, and C. Leck (1993), Experimental determination of the diffusion coefficient of dimethylsulfide in water, J. Geophys. Res., 98, 16,481-16,486, doi:10.1029/93JC01858.
40. Smith, S. D. (1988), Coefficients for sea surface wind stress, heat flux, and wind profiles as a function of wind speed and temperature, J. Geophys. Res., 93, 15,467-15,472, doi:10.1029/JC093iC12p15467.
41. Soloviev, A. V., and P. Schlüssel (1994), Parameterization of the cool skin of the ocean and of the air-ocean gas transfer on the basis of modeling surface renewal, J. Phys. Oceanogr., 24, 1339-1346, doi:10.1175/1520-0485(1994)024〈1339:POTCSO〉2.0.CO;2.
42. Soloviev, A. V., and P. Schlüssel (1996), Evolution of cool skin and direct air-sea gas transfer coefficient during daytime, Boundary Layer Meteorol., 77, 45-68, doi:10.1007/BF00121858. (Pubitemid 26472462)
43. Wanninkhof, R. H. (1992), Relationship between wind speed and gas exchange over the ocean, J. Geophys. Res., 97, 7373-7382, doi:10.1029/92JC00188.
44. Wanninkhof, R. H., and W. R. McGillis (1999), A cubic relationship between air-sea CO2 exchange and wind speed, Geophys. Res. Lett., 26, 1889-1892, doi:10.1029/1999GL900363.
45. Woolf, D. K. (1997), Bubbles and their role in gas exchange, in The Sea Surface and Global Change, edited by R. Duce and P. Liss, pp. 173-205, Cambridge Univ. Press, New York, doi:10.1017/CBO9780511525025.007.
46. Yang, M., B. W. Blomquist, and B. J. Huebert (2009), Constraining the concentration of the hydroxyl radical in a stratocumulus-topped marine boundary layer from sea-to-air eddy covariance flux measurements of dimethylsulfide, Atmos. Chem. Phys., 9, 9225-9236, doi:10.5194/acp-9-9225-2009.