Effect of Pt: Pd atomic ratio in Pt-Pd/C electrocatalyst-coated membrane on the electrocatalytic activity of ORR in PEM fuel cells

Renewable Energy

Volumn 36, Issue 6, 2011, Pages 1795-1801

  Thanasilp, Sarawalee ^a   Hunsom, Mali ^a  

^a CHULALONGKORN UNIVERSITY   (Thailand)

Author keywords

Catalyst coated membrane; ORR; Palladium; PEM fuel cells; Platinum

Indexed keywords

A-CARBON; ATOMIC RATIO; CATALYST COATED MEMBRANES; ELECTROCATALYST LOADING; ELECTROCATALYTIC ACTIVITY; ELECTROCHEMICAL SURFACE AREA; EXCHANGE CURRENT DENSITIES; MASS ACTIVITY; NAFION FILM; ORR; OXYGEN PERMEABILITY; OXYGEN REDUCTION; OXYGEN REDUCTION REACTION; PARTICLE DISPERSION; PEAK POWER; PEM FUEL CELL; ROTATING DISK ELECTRODES; TOTAL RESISTANCE;

ATOMS; ELECTROCATALYSTS; ELECTROCHEMICAL SENSORS; ELECTROLYTIC REDUCTION; GAS FUEL PURIFICATION; MEMBRANES; OXYGEN; PALLADIUM; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); ROTATING DISKS;

PLATINUM;

CATALYST; ELECTRODE; FUEL CELL; HYDROGEN; MEMBRANE; OXYGEN; PALLADIUM; PLATINUM;

EID: 78751705481     PISSN: 09601481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.renene.2010.10.024     Document Type: Article

References (36)

1. Colón-Mercado H.R., Popov B.N. Stability of platinum based alloy cathode catalysts in PEM fuel cells. J Power Sources 2006, 155(2):253-263.
2. Trongchuankij W., Poochinda K., Pruksathorn K., Hunsom M. A study on novel combined processes for preparation of high performance Pt-Co/C electrocatalyst for oxygen reduction in PEM fuel cell. Renew Energy 2010, 35(12):2839-2843.
3. 4 (1.0 ≤ x ≤ 1.4) spinel particles/polypyrrole composite electrodes. Int J Hydrogen Energy 2008, 33:4945-4954.
4. Zhong H., Zhang H., Liu G., Liang Y., Hu J., Yi B. A novel non-noble electrocatalyst for PEM fuel cell based on molybdenum nitride. Electrochem Commun 2006, 8:707-712.
5. Baker R., Wilkinson D.P., Zhang J. Electrocatalytic activity and stability of substituted iron phthalocyanines towards oxygen reduction evaluated at different temperatures. Electrochimica Acta 2008, 53:6906-6919.
6. Fuerte A., Corma A., Iglesias M., Morales E., Sanchez F. Approaches to the synthesis of heterogenised metalloporphyrins application of new materials as electrocatalysts for oxygen reduction. J Mol Cat A 2006, 246:109-117.
7. Liu G., Li X., Ganesan P., Popov B.N. Development of non-precious metal oxygen-reduction catalysts for PEM fuel cells based on N-doped ordered porous carbon. Appl Catal B Environ 2009, 93:156-165.
8. Wood T.E., Tan Z., Schmoeckel A.K., O'Neill D., Atanasoski R. Non-precious metal oxygen reduction catalyst for PEM fuel cells based on nitroaniline precursor. J Power Sources 2008, 178:510-516.
9. Liu G., Li X., Ganesan P., Popov P.N. Studies of oxygen reduction reaction active sites and stability of nitrogen-modified carbon composite catalysts for PEM fuel cells. Electrochim Acta 2010, 55(8):2853-2858.
10. Jalan V., Taylor E.J. Importance of interatomic spacing in catalytic reduction of oxygen in phosphoric acid. J Electrochem Soc 1983, 130:2299-3201.
11. 0.35, Pt0.2Cr0.8 and roughened platinum. J Electrochem Soc 1988, 135:1431-1436.
12. Beard B.C., Ross P.N. The structure and activity of Pt-Co alloys as oxygen reduction electrocatalysts. J Electrochem Soc 1990, 137:3368-3374.
13. Toda T., Igarashi H., Uchida H., Watanabe M. Enhancement of electroreduction of oxygen on Pt alloys with Fe, Ni and Co. J Electrochem Soc 1999, 146:3750-3756.
14. Antolini E., Salgado J.R.C., Giz M.J., Gonzalez E.R. Effects of geometric and electronic factors on ORR activity of carbon supported Pt-Co electrocatalysts in PEM fuel cells. Inter J Hydro Energy 2005, 30(11):1213-1220.
15. Yu P., Pemberton M., Plasse P. PtCo/C cathode catalyst for improved durability in PEMFCs. J Power Sources 2005, 144:11-20.
16. Gasteiger H.A., Kocha S.S., Sompalli B., Wagner F.T. Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl Catal B Environ 2005, 56:9-35.
17. xNi alloy nanoparticles as cathode catalyst for PEM fuel cells with enhanced catalytic activity. J Alloys Compd 2009, 488:195-198.
18. Wen T.C., Hu C.H., Hu C.C. Voltammetric investigation of nickel-platinum codeposits for methanol oxidation in KOH solutions. J Chin Inst Chem Engrs 1999, 30:515.
19. 1 catalysts as cathode in PEM fuel cells. Electrochem Commun 2004, 6(8):795-799.
20. Travitsky N., Ripenbein T., Golodnitsky D., Rosenberg Y., Burshtein L., Peled E. Pt-, PtNi- and PtCo-supported catalysts for oxygen reduction in PEM fuel cells. J Power Sources 2006, 161(2):782-789.
21. Ralph T.R., Hogarth M.P. Catalysis for low temperature fuel cells. Platinum Met Rev 2002, 46(1):3-14.
22. Noto V.D., Negro E. A new Pt-Rh carbon nitride electrocatalyst for the oxygen reduction reaction in polymer electrolyte membrane fuel cells: synthesis, characterization and single-cell performance. J Power Sources 2010, 195(2):638-648.
23. Fčçčcčlar B., Bayrakçeken A., Eroĝlu I. Effect of Pd loading in Pd-Pt bimetallic catalysts doped into hollow core mesoporous shell carbon on performance of proton exchange membrane fuel cells. J Power Sources 2009, 193(1):17-23.
24. Cho Y.H., Choi B., Cho Y.H., Park H.S., Sung Y.E. Pd-based PdPt (19:1)/C electrocatalyst as an electrode in PEM fuel cell. Electrochem Commun 2007, 9(3):378-381.
25. Konishita K. Electrochemical oxygen technology 1992, John Wiley & Sons.
26. Lopes T., Antolini E., Gonzalez E.R. Carbon supported Pt-Pd alloy as an ethanol tolerant oxygen reduction electrocatalyst for direct ethanol fuel cells. Int J Hydrogen Energy 2008, 33:5563-5570.
27. Xu J.B., Zhao T.S., Yang W.W., Shen S.Y. Effect of surface composition of Pt-Aualloy cathode catalyst on the performance of direct methanol fuel cells. Int J Hydrogen Energy 2010, 35(16):8699-8706.
28. van der Klink J.J. NMR spectroscopy as a probe of surfaces of supported metal catalysts. Adv Catal 2000, 44:1-117.
29. 3Ni alloy surfaces. J Electroanal Chem 2003, 554-555:191-199.
30. Mayrhofer K.J.J., Blizanac B.B., Arenz M., Stamenkovic V.R., Ross P.N., Markovic N.M. The impact of geometric and surface electronic properties of Pt-catalysts on the particle size effect in electrocatalysis. J Phys Chem B 2005, 109(30):14433-14440.
31. Li J., Ye F., Chen L., Wang T., Li J., Wang X. Correlation of electrochemical and physical properties of PtRu alloy electrocatalysts for PEM fuel cells. J Power Sources 2009, 186:320-327.
32. Antolini E., Giorgi L., Pozio A., Passalacqua E. Influence of Nafion loading in the catalyst layer of gas-diffusion electrodes for PEFC. J Power Sources 1999, 77:136-142.
33. Yuan X.Z., Wang H. PEM fuel cell fundamental. PEM fuel cell electrocatalysts and catalyst Layers Fundamentals and applications 2008, Springer-Verlag London Limited. J. Zhange (Ed.).
34. Huang S.Y., Ganesan P., Popov B.N. Electrocatalytic activity and stability of niobium-doped titanium oxide supported platinum catalyst for polymer electrolyte membrane fuel cells. Appl Catal B Environ 2010, 96:224-231.
35. Moreira J., del Angel P., Ocampo A.L., Sebastián P.J., Montoya J.A., Castellanos R.H. Synthesis, characterization and application of a Pd/Vulcan and Pd/C catalyst in a PEM fuel cell. Inter J Hydrogen Energy 2004, 29:915-920.
36. ®. J Power Sources 2004, 130:50-55.