Interaction of mass transport and reaction kinetics during electrocatalytic co oxidation in a thin-layer flow cell

Journal of Physical Chemistry C

Volumn 115, Issue 2, 2011, Pages 468-478

  Zhang, D ^a   Deutschmann, O ^a   Seidel, Y E ^b   Behm, R J ^b  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF ULM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CO DIFFUSION; CO OXIDATION; DIFFUSION AND CONVECTION; ELECTROCATALYTIC; ELECTROCATALYTIC REACTIONS; ELECTROLYTE FLOWS; EXPERIMENTAL SETUP; FARADAIC CURRENT; FLOW CELLS; MASS TRANSFER LIMITATION; MASS TRANSPORT; NUMERICAL SIMULATION; OVERALL REACTIONS; POLYCRYSTALLINE PLATINUM; REACTION MECHANISM; SPATIAL CONCENTRATION; SURFACE COVERAGES; THIN-LAYER FLOW CELLS; THREE-DIMENSIONAL MODEL; TIME-RESOLVED; TRANSPORT MODELS; ZERO-DIMENSIONAL MODELS;

ELECTROCATALYSIS; MASS TRANSFER; MODELS; OXIDATION; PLATINUM; REACTION RATES;

THREE DIMENSIONAL;

EID: 78651438961     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp106967s     Document Type: Article

References (55)

1. Bard, A. J.; Faulkner, L. R. Electrochemical Methods-Fundamentals and Applications; John Wiley & Sons: New York, 1980.
2. Hamann, C. H.; Hamnett, A.; Vielstich, W. Electrochemistry, 2 nd ed.; Wiley VCH: Weinheim, 2007.
3. Thomas, J. M.; Thomas, W. J. Principles and Practice of Heterogeneous Catalysis; VCH: Weinheim, 1997.
4. Chen, S.; Kucernak, A. J. Phys. Chem. B 2004, 108, 3262-3276
5. Schneider, A.; Colmenares, L.; Seidel, Y. E.; Jusys, Z.; Wickman, B.; Kasemo, B.; Behm, R. J. Phys. Chem. Chem. Phys. 2008, 10, 1931-1943
6. Seidel, Y. E.; Schneider, A.; Jusys, Z.; Wickman, B.; Kasemo, B.; Behm, R. J. Faraday Discuss. 2008, 140, 167-184
7. Lindström, R.; Seidel, Y. E.; Jusys, Z.; Gustavsson, M.; Kasemo, B.; Behm, R. J. J. Electroanal. Chem. 2010, 644, 90-102
8. Breiter, M.; Hoffmann, K. Z. Elektrochem. 1960, 64, 462-467
9. Bard, A. J.; Faulkner, L. R. Electrochemical Methods; Wiley & Sons: New York, 1980.
10. Jusys, Z.; Kaiser, J.; Behm, R. J. Phys. Chem. Chem. Phys. 2001, 3, 4650-4660
11. Beden, B.; Lamy, C.; De Tacconi, N. R.; Arvia, A. J. Electrochim. Acta 1990, 35, 691-704
12. Vielstich, W. Encyclopedia of Electrochemistry-Interfacial Kinetics and Mass Transport; VCH: Weinheim, 2003.
13. Iwasita, T. Handbook of Fuel Cells, Vol. 2: Electrocatalysis; John Wiley & Sons: Chichester, 2003; Chapter 41, pp 603 - 624.
14. Batista, E. A.; Iwasita, T.; Vielstich, W. J. Phys. Chem. B 2004, 108, 14216-14222
15. Arenz, M.; Mayrhofer, K. J.; Stamenkovic, V.; Blizanac, B. B.; Tomoyuki, T.; Ross, P. N.; Markovic, N. M. J. Am. Chem. Soc. 2005, 127, 6819-6829
16. Lu, G. Q.; Lagutchev, A.; Dlott, D. D.; Wieckowski, A. Surf. Sci. 2005, 585, 3-16
17. Mayrhofer, K. J. J.; Arenz, M.; Blizanac, B. B.; Stamenkovic, V.; Ross, P. N.; Markovic, N. M. Electrochim. Acta 2005, 50, 5144-5154
18. Morschl, R.; Bolten, J.; Bonnefont, A.; Krischer, K. J. Phys. Chem. C 2008, 112, 9548-9551
19. Fromondi, I.; Scherson, D. Faraday Discuss. 2008, 140, 59-68
20. Heinen, M.; Chen, Y.-X.; Jusys, Z.; Behm, R. J. Electrochim. Acta 2007, 53, 1279-1289
21. Heinen, M.; Chen, Y. X.; Jusys, Z.; Behm, R. J. Electrochim. Acta 2007, 52, 5634-5643
22. Stonehart, P. J. Electroanal. Chem. 1967, 15, 239-244
23. Bergelin, M.; Herrero, E.; Feliu, J. M.; Wasberg, M. J. Electroanal. Chem. 1999, 467, 74-84
24. Koper, M. T. M.; Schmidt, T. J.; Markovic, N. M.; Ross, P. N. J. Phys. Chem. B 2001, 105, 8381-8386
25. Holzbecher, E.; Halseid, R.; Jusys, Z.; Fuhrmann, J.; Behm, R. J. Modellierung von Dünnschichtzellen-Thin Layer Flow Cell Modelling. Conference Proceeding, 2006.
26. Fuhrmann, J.; Zhao, H.; Holzbecher, E.; Langmach, H.; Chojak, M.; Halseid, R.; Jusys, Z.; Behm, R. J. Phys. Chem. Chem. Phys. 2008, 10, 3784-3795
27. Fuhrmann, J.; Linke, A.; Langmach, H.; Baltruschat, H. Electrochim. Acta 2009, 55, 430-438
28. Fuhrmann, J.; Zhao, H.; Holzbecher, E.; Langmach, H. J. Fuel Cell Sci. Technol. 2008, 5, 021008/1-021008/10
29. Koper, M. T. M.; Jansen, A. P. J.; van Santen, R. A. J. Chem. Phys. 1998, 109, 6051
30. Saravanan, C.; Markovic, N. M.; Head-Gordon, M.; Ross, P. N. J. Chem. Phys. 2001, 114, 6404-6412
31. Saravanan, C.; Koper, M. T. M.; Markovic, N. M.; Head-Gordon, M.; Ross, P. N. Phys. Chem. Chem. Phys. 2002, 4, 2660-2666
32. Housmans, T. H. M.; Hermse, C. G. M.; Koper, M. T. M. J. Electroanal. Chem. 2007, 607, 69-82
33. Bonnefont, A.; Varela, H.; Krischer, K. ChemPhysChem 2003, 4, 1260-1263
34. Kee, R. J.; Coltrin, M. E.; Glarborg, P. Chemically Reacting Flow; Wiley-Interscience: New York, 2003.
35. Deutschmann, O. Handbook of Heterogeneous Catalysis, 2 nd ed.; Ertl, G., Knazinger, H., Schath, F., Weitkamp, J., Eds.; Wiley-VCH: New York, 2007; Chapter 6.6.
36. Pineda, M.; Imbhil, R.; Schimansky-Geier, L. Physica A 2010, 389, 1178-1188
37. Jusys, Z.; Massong, H.; Baltruschat, H. J. Electrochem. Soc. 1999, 146, 1093-1098
38. Seidel, Y. E.; Müller, M.; Jusys, Z.; Wickman, B.; Hanarp, P.; Kasemo, B.; Hörmann, U.; Kaiser, U.; Behm, R. J. J. Electrochem. Soc. 2008, 155, K171-K179
39. Seidel, Y. E.; Jusys, Z.; Wickman, B.; Kasemo, B.; Behm, R. J. ECS Trans. 2010, 25, 91-102
40. Markovic, N. M. Electrocatalysis; Wiley & Sons: Chichester, 2003; pp 386 - 393.
41. Janik, M. J.; Neurock, M. Electrochim. Acta 2007, 52, 5517-5528
42. Heinen, M.; Chen, Y.-X.; Jusys, Z.; Behm, R. J. ChemPhysChem 2006, 8, 2484-2489
43. Cuesta, A.; del Carmen Perez, M.; Rincón, A.; Gutierrez, C. ChemPhysChem 2006, 7, 2346-2351
44. Cuesta, A.; Couto, A.; Rincón, A.; Perez, M. C.; Lopez-Cudero, A.; Gutierrez, C. J. Electroanal. Chem. 2006, 586, 184-195
45. Davies, J. C.; Nielsen, R. M.; Thomsen, L. B.; Chorkendorff, I.; Logadottir, A.; Lodziana, Z.; Nørskov, J. K.; Li, W. X.; Hammer, B.; Longwitz, S. R.; Schnadt, J.; Vestergaard, E. K.; Vang, R. T.; Besenbacher, F. Fuel Cells 2003, 4, 1-11
46. Davies, J. C.; Tsotridis, G. J. Phys. Chem. C 2008, 112, 3392-3397
47. Bird, R. B.; Stewart, W. E.; Lightfoot, E. N. Transport Phenomena, 2 nd ed.; Wiley & Sons: New York, 2007; Chapter 3, pp 75 - 104.
48. Wilke, C. R.; Chang, P. AIChE J. 1955, 1, 264-270
49. Fisk, P. R.; Jonathan, P.; Whitstable, K. Comprehensive Chemical Kinetics; Elsevier: Amsterdam, 1999; pp 543 - 571.
50. Green, D. W.; Perry, R. H. Perrys Chemical Engineers Handbook, 8 th ed.; The MacGraw Hill Co.: New York, 2008.
51. Gilman, S. J. Phys. Chem. 1963, 67, 1989-1905
52. Markovic, N. M.; Grgur, B. N.; Lucas, C. A.; Ross, P. N. J. Phys. Chem. B 1999, 103, 487-495
53. Stalnionis, G.; Tamasauskaite-Tamasiunaite, L.; Pautieniene, V.; Jusys, Z. J. Electroanal. Chem. 2006, 590, 198-206
54. Schmidt, T. J.; Gasteiger, H. A.; Behm, R. J. J. Electrochem. Soc. 1999, 146, 1296-1304
55. Gasteiger, H. A.; Markovic, N. M.; Ross, P. N. J. Phys. Chem. 1995, 99, 8290-8301