Thermal degradation behaviour of a nearly alternating copolymer of vinylidene cyanide with 2,2,2-trifluoroethyl methacrylate

Polymer Degradation and Stability

Volumn 96, Issue 2, 2011, Pages 204-211

  Castelvetro, Valter ^a,b   Raihane, Mustapha ^c   Bianchi, Sabrina ^a   Atlas, Salima ^c   Bonaduce, Ilaria ^a  

^a UNIVERSITY OF PISA   (Italy)

^b AREA DELLA RICERCA   (Italy)

^c CADI AYYAD UNIVERSITY   (Morocco)

Author keywords

Fluorinated copolymer; Pyrolysis GC MS; Thermal degradation kinetics; Vinylidene cyanide

Indexed keywords

ACTIVATION ANALYSIS; ACTIVATION ENERGY; CYANIDES; DEGRADATION; ISOTHERMS; KINETICS; POLYMER BLENDS; REACTION KINETICS; THERMOGRAVIMETRIC ANALYSIS;

ALTERNATING COPOLYMER; DEGRADATION BEHAVIOURS; DEGRADATION STAGES; FLUORINATED COPOLYMERS; ISOTHERMAL METHODS; PYROLYSIS-GC-MS; PYROLYTIC PRODUCTS; THERMAL DEGRADATION KINETICS;

PYROLYSIS;

EID: 78651310207     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2010.11.016     Document Type: Article

References (39)

1. R. Souzy, and B. Ameduri Functional fluoropolymers for fuel cell membranes Progr Polym Sci 30 2005 644 687 (Pubitemid 40718176)
2. B. Ameduri, B. Boutevin, and G. Kostov Fluoroelastomers: synthesis, properties and applications Progr Polym Sci 26 2001 105 187
3. H. Gao, C. Yan, S. Guan, and Z. Jiang Hyperbranched fluorinated polyimides with tunable refractive indices for optical waveguide applications Polymer 51 2010 694 701
4. G. Kostov, F. Boschet, and B. Ameduri Original fluorinated surfactants potentially non-bioaccumulable J Fluor Chem 130 2009 1192 1199
5. A. Meskini, M. Raihane, B. Ameduri, C. Hakme, D. Sage, and I. Stevenson Dielectric behaviour of copoljymers based on 2,2,2-trifluoroethyl methacrylate and cyano co-monomers Eur Polym J 45 2009 804 812
6. A. Meskini, M. Raihane, and B. Ameduri Unexpected Alternated radical copolymerization of vinylidene cyanide with a vinyl ether for superhydrophobic and highly oleophobic films Macromolecules 42 2009 3532 3539
7. S. Miyata, M. Yoshikawa, S. Tasaka, and M. Ko Piezoelectricity revealed in the copolymer of vinylidene cyanide and vinyl acetate Polym J 12 1980 857 860
8. J.P. Montheard, A. Zerroukhi, I. Ouillon, M. Raihane, and Q.T. Pham Copolymers of cyano coumpounds with captodative monomers. Studies of their microstructures J. Macrom Sci Pure Appl Chem A34 1997 291 313
9. B. Ameduri From vinylidene fluoride (VDF) to the applications of VDF-containing polymers and copolymers: recent developments and future trends Chem Rev 109 2009 6632 6686
10. T. Furukawa, M. Date, K. Nakajima, T. Kosaka, and I. Seo Large dielectric relaxations in an alternate copolymer of vinylidene cyanide and vinyl acetate Jap J Appl Phys Part 1 25 1986 1178 1182
11. Z.-Y. Wang, K.-H. Su, H.-Q. Fan, and Z.-Y. Wen Possible reasons that piezoelectricity has not been found in bulk polymer of polyvinylidene cyanide Polymer 49 2008 2542 2547
12. Gilbert H, Miller FF. Copolymers of vinylidene cyanide with difluorodichloroethylenes. U.S. Pat. 2,654,728; 1953.
13. J.P. Montheard, A. Zerroukhi, I. Ouillon, B. Boinon, and Q.T. Pham Copolymerization reactions of vinylidene cyanide with styrenes carrying a fluorocarbon segment: preliminary studies of their microstructure Macromol Rep A32 Suppl. 1and 2 1995 1 11
14. M. Raihane, V. Castelvetro, S. Bianchi, S. Atlas, and B. Ameduri Radical copolymerization of vinylidene cyanide with 2,2,2-trifluoroethyl methacrylate: structure and characterization J Polym Sci Part A: Polym Chem 48 2010 4900 4908
15. M. Raihane, and B. Ameduri Radical copolymerization of 2,2,2-trifluoroethyl methacrylate with cyano compounds for dielectric materials: synthesis and characterization J Fluor Chem 127 2006 391 399
16. H. Gilbert, F.F. Miller, S.J. Averill, R.F. Schmidt, F.D. Stewart, and H.L. Trumbull Vinylidene cyanide. III J Am Chem Soc 76 1954 1074 1076
17. N. Grassie, and R. McGuchan Pyrolysis of polyacrylonitrile and related polymers. VI. Acrylonitrile copolymers containing carboxylic acid and amide structures Eur Polym J 8 1972 257 269
18. V.V. Zuev, F. Bertini, and G. Audisio Investigation on the thermal degradation of acrylic polymers with fluorinated side-chains Polym Degrad Stab 91 2006 512 516
19. M. Lazzari, D. Scalarone, C. Riedo, and O. Chiantore Compositional analysis of fluorinated and unfluorinated acrylic copolymers J Anal Appl Pyrol 85 2009 321 326
20. F. Boschet, G. Kostov, B. Ameduri, T. Yoshida, and K. Kawada Kinetics of the radical copolymerization of 2,2,2-trifluoroethyl methacrylate with tert-butyl α-trifluoromethacrylate J Polym Sci Part A: Polym Chem 48 2010 1029 1037
21. P.K. Dhal, G.N. Babu, and J.C.W. Chien Resist polymers: part VII - thermolysis of fluoroalkyl methacrylates Polym Degrad Stab 16 1986 135 145
22. M. Raihane, N. Laleque, and B. Boinon Etude cinétique de la dégradation thermique dun copolymre de cyanure de vinylidene et de cyanovinylacetate Thermochimica Acta 265 1995 1 13
23. I. Ouillon, A. Zerroukhi, M. Raihane, and B. Boinon Thermal degradation of two copolymers of vinylidene cyanide and methyl α-acetoxyacrylate. Thermogravimetric and gas chromatography- mass spectrometry studies Polym Degrad Stab 61 1998 519 525
24. N. Mignard, A. Zeroukhi, and B. Boinon Etude cinétique de la degradation thermique de copolymers du cyanure de vinylidene et de styrnes para substitués par analyse thermogravimétrique et chromatographie en phase gazeuse couplée la spectroscopie de masse Eur Polym J 37 2001 1591 1598
25. 13C NMR studies of their structure Macromol Rep A31 1994 1 8
26. A. Belfkira, A. Sadel, J.P. Montheard, G. Boiteux, J.M. Lucas, and G. Seytre Dielectric studies of amorphous vinylidene cyanide alternating copolymers Polymer 34 1993 4015 4019
27. M. Raihane, J.P. Montheard, and B. Boinon Kinetics of thermal degradation of copolymers of methylvinylidene cyanide with substituted styrenes. Thermogravimetric and gas chromatography-mass spectroscopy studies Polym Degrad Stab 46 1994 171 179
28. H. Tanaka Thermal analysis and kinetics of solid state reactions Thermochimica Acta 267 1995 29 44
29. J.T. Sun, Y.D. Huang, G.F. Gong, and H.L. Cao Thermal degradation kinetics of poly(methylphenylsiloxane) containing methacryloyl groups Polym Degrad Stab 91 2005 339 346
30. K. Pielichowski, and K. Flejtuch Non-oxidative thermal degradation of poly(ethylene oxide): kinetic and thermoanalytical study J Anal Appl Pyrolysis 73 2005 131 138
31. H. Liang, J. Ding, and W. Shi Kinetics and mechanism of thermal oxidative degradation of UV cured epoxy acrylate/phosphate triacrylate blends Polym Degrad Stab 86 2004 217 223
32. J.M. Barrales-Rienda, M. Sanchez Chaves, J.M. Mazon-Arechederra, and F. Fernandez-Martin Polymer precursors of polyacetylene. Thermal degradation of poly(vinyl esters). Part II. Effect of the n-acyl chain length on the autocatalytic thermal degradation of a homologous series of poly(vinyl n-alkyl esters) (PV-n-AEs) Polym Degrad Stab 23 1989 279 298
33. H.L. Friedman Kinetics of thermal degradation of char-forming plastics from thermogravimetry-application to a phenolic resin J Polym Sci 6 1964 183 195
34. J.H. Flynn, and L.A. Wall General treatment of the thermogravimetry of polymers J Res Natl Bur Stand, A: Phys Chem 70 1966 487 523
35. T. Ozawa A new method of analyzing thermogravimetric data Bull Chem Soc Japan 38 1965 1881 1886
36. H.E. Kissinger Reaction kinetics in differential thermal analysis Anal Chem 29 1957 1702 1706
37. M.J. Starink Thedetermination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversional methods Thermochimica Acta 404 2003 163 176
38. T. Akahira, and T. Sunose Res Rep Chiba Inst Technol 16 1971 22 31
39. C.D. Doyle Estimating isothermal life from thermogravimetric data J Appl Polym Sci 6 1962 639 642