Rare 5-connected BN topology in homochiral Cd(II) camphorate with 2-(4-pyridyl)benzimidazole

Inorganic Chemistry Communications

Volumn 14, Issue 1, 2011, Pages 228-230

  Li, Fei ^a,b   Kang, Yao ^a   Dai, Yu Mei ^b   Zhang, Jian ^a  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b FUJIAN NORMAL UNIVERSITY   (China)

Author keywords

Cadmium; Crystal structure; Homochiral; Hydrogen bond; Topology

Indexed keywords

EID: 78651297482     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.10.029     Document Type: Article

References (31)

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21. Synthesis of 1: A solution of Cd(NO3)2•4H2O (0.0683 g, 0.22 mmol), 4-PyBIm (0.0386 g, 0.02 mmol), H2cam acid (0.0500 g, 0.25 mmol), Na2CO3 (0.0233 g, 0.22 mmol) and H2O (4 mL) was stirred 20 minutes under ambient conditions, then sealed in a Teflon-lined steel autoclave, heated at 160 °C for 3 days. After the vessel was cooled naturally to room temperature, The resulting product was recovered by filtration, washed with distilled water and then colorless block crystals were obtained. (80% yield) Anal. Calcd. for C44H46Cd2N6O8: C, 52.24H, 4.58N, 8.31 %. Found: C, 51.81; H, 4.52; N, 8.29 %.
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