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Preparation of 1: The mixture of MnCl2·4H2O (0.365 g, 1.50 mmol, H3PTC (0.201 g, 1.00 mmol, 0.10 mL of triethylamine, and H2O (18.0 ml) was sealed in a 25 mL slainless-sleel reactor with Teflon liner and healed lo 170 °C and kept al constant lemperalure for 120 h; il was ihen cooled to room temperalure, and yellow prismatic cryslals of [Mn2(OH)(H2O)(PTC, 1) were manually separated from me resulting powder samples (yield: 35% based on Ihe initial MnCl2· 4H2O input, Anal. Calcd for C 8H5Mn2NO8, C, 27.19; H, 1.41; O, 36.25. Found: C, 27.25; H, 1.55; O, 36.13. IR data cm-1, KBr, 3361 s, 1621 s, 1608 s, 1556 m, 1456 m, 1442 m, 1367 s, 1278 w, 1226 w, 1105 w, 1026 w, 783 w, 746 m, 696 m, 665 w, 540 w
-
-1, KBr): 3361 s, 1621 s, 1608 s, 1556 m, 1456 m, 1442 m, 1367 s, 1278 w, 1226 w, 1105 w, 1026 w, 783 w, 746 m, 696 m, 665 w, 540 w.
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60
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34247519231
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