Mechanistic insight into the reactivity of oxotransferases by novel asymmetric dioxomolybdenum(VI) model complexes

Chemistry - A European Journal

Volumn 17, Issue 2, 2011, Pages 704-713

  Mayilmurugan, Ramasamy ^a   Harum, Bastian N ^a   Volpe, Manuel ^a   Sax, Alexander F ^a   Palaniandavar, Mallayan ^b   Mösch Zanetti, Nadia C ^a  

^a UNIVERSITY OF GRAZ   (Austria)

^b BHARATHIDASAN UNIVERSITY   (India)

Author keywords

asymmetric complexes; density functional calculations; electrochemistry; reaction mechanisms; structure activity relationships; transferases

Indexed keywords

ASYMMETRIC COMPLEXES; DENSITY-FUNCTIONAL CALCULATIONS; REACTION MECHANISM; STRUCTURE ACTIVITY RELATIONSHIPS; TRANSFERASES;

DENSITY FUNCTIONAL THEORY; ELECTROCHEMISTRY; ENZYMES; LIGANDS; MASS SPECTROMETRY; MOLYBDENUM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXYGEN; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

MOLYBDENUM COMPOUNDS;

1,4 DIAZEPANE; 1,4-DIAZEPANE; AZEPINE DERIVATIVE; DIMETHYLSULFIDE - ACCEPTOR OXIDOREDUCTASE; DIMETHYLSULFIDE ACCEPTOR OXIDOREDUCTASE; MOLYBDENUM; ORGANOMETALLIC COMPOUND; OXIDOREDUCTASE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; METABOLISM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

AZEPINES; CRYSTALLOGRAPHY, X-RAY; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXIDOREDUCTASES;

EID: 78651232843     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001177     Document Type: Article

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