Secondary organic aerosol from ozonolysis of biogenic volatile organic compounds: Chamber studies of particle and reactive oxygen species formation

Environmental Science and Technology

Volumn 45, Issue 1, 2011, Pages 276-282

  Chen, Xi ^a   Hopke, Philip K ^a   Carter, William P L ^b  

^a CLARKSON UNIVERSITY   (United States)

^b University of California Riverside   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AIR EXCHANGE RATES; BIOGENIC VOLATILE ORGANIC COMPOUNDS; DYNAMIC CHAMBER; EMPIRICAL MODELING; HEALTH EFFECTS; LIFE-TIMES; MASS CONCENTRATION; OZONOLYSIS; PARTICULATE MATTER; PHYSICAL CHARACTERIZATION; REACTION CHEMISTRY; REACTIVE OXYGEN SPECIES; REACTIVE SPECIES; ROOM TEMPERATURE; SECONDARY ORGANIC AEROSOLS; TERPENOIDS; TIME SENSITIVITY; VENTILATED INDOOR ENVIRONMENTS;

ATMOSPHERIC AEROSOLS; ATMOSPHERIC COMPOSITION; PARTICLES (PARTICULATE MATTER); VOLATILE ORGANIC COMPOUNDS;

OZONE;

LIMONENE; LINALOOL; PINENE; REACTIVE OXYGEN METABOLITE; TERPENOID; VOLATILE ORGANIC COMPOUND;

AEROSOL FORMATION; EMPIRICAL ANALYSIS; EXPERIMENTAL STUDY; HALF LIFE; HEALTH IMPACT; HYDROCARBON; INDOOR AIR; NUMERICAL MODEL; OZONE; PHYSICAL PROPERTY; VENTILATION; VOLATILE ORGANIC COMPOUND;

AIR CONDITIONING; ARTICLE; CONTROLLED STUDY; EMPIRICISM; HALF LIFE TIME; INDOOR AIR POLLUTION; OZONOLYSIS; PARTICULATE MATTER; ROOM TEMPERATURE; SECONDARY ORGANIC AEROSOL; SIMULATION; STEADY STATE;

AEROSOLS; AIR POLLUTANTS; AIR POLLUTION, INDOOR; CYCLOHEXENES; GREEN CHEMISTRY TECHNOLOGY; MONOTERPENES; OZONE; PARTICLE SIZE; PARTICULATE MATTER; REACTIVE OXYGEN SPECIES; TERPENES; VOLATILE ORGANIC COMPOUNDS;

EID: 78650704064     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es102166c     Document Type: Article

References (37)

1. Weschler, C. J. Changes in indoor pollutants since the 1950s Atmos. Environ. 2009, 43, 153-169
2. Weschler, C. J. Ozone's Impact on Public Health: Contributions from indoor exposures to ozone and products of ozone-initiated chemistry Environ. Health Perspect. 2006, 114, 1489-1496
3. Fan, Z.; Lioy, P.; Weschler, C.; Fiedler, N.; Kipen, H.; Zhang, J. Ozone initiated reactions with mixtures of volatile organic compounds under simulated indoor conditions Environ. Sci. Technol. 2003, 37, 1811-1821
4. Leungskul, S.; Jaoui, M.; Kamens, R. M. Kinetic mechanism for predicting secondary organic aerosol formation from the reaction of d-limonene with ozone Environ. Sci. Technol. 2005, 39, 9583-9594
5. Sarwar, G.; Corsi, R. The effects of ozone/limonene reactions on indoor secondary organic aerosols Atmos. Environ. 2007, 41, 959-973
6. Weschler, C. J.; Shields, H. C. Experimental probing the influence of air exchange rates on secondary organic aerosols derived from indoor chemistry Atmos. Environ. 2003, 37, 5621-5631
7. Singer, B. C.; Coleman, B. K.; Destaillats, H.; Hodgson, A. T.; Lunden, M. M.; Weschler, C. J.; Nazaroff, W. W. Indoor secondary pollutants from cleaning product and air freshener use in the presence of ozone Atmos. Environ. 2006, 40, 6696-6710 (Pubitemid 46550292)
8. Destaillats, H.; Lunden, M. M.; Singer, B. C.; Coleman, B. K.; Hodgson, A. T.; Weschler, C. J.; Nazaroff, W. W. Indoor secondary pollutants from household product emissions in the presence of ozone: A bench-scale chamber study Environ. Sci. Technol. 2006, 40, 4421-4428 (Pubitemid 44092376)
9. Toftum, J.; Freund, S.; Salthammer, T.; Weschler, C. J. Secondary organic aerosols from ozone-initiated reactions with emissions from wood-based materials and a "green" paint Atmos. Environ. 2008, 42, 7632-7640
10. Fan, Z.; Weschler, C. J.; Han, I.; Zhang, J. Co-formation of hydroperoxides and ultra-fine particles during the reactions of ozone with a complex VOC mixture under simulated indoor conditions Atmos. Environ. 2005, 39, 6171-5182
11. 3 Environ. Sci. Technol. 2005, 39, 4049-4059
12. Venkatachari, P.; Hopke, P. K.; Brune, W. H.; Ren, X.; Lesher, R.; Mao, J.; Mitchell, M. Characterization of wintertime reactive oxygen species concentrations in Flushing, New York Aerosol Sci. Technol. 2007, 41, 97-111
13. Friedlander, S. K.; Yeh, E. K. The submicron atmospheric aerosol as a carrier of reactive chemical species: Case of peroxides Appl. Occup. Environ. Hyg. 1998, 13, 416-420
14. Gurgueira, S. A.; Lawrence, J.; Coull, B.; Murthy, G. G. K.; Gonzalez-Flecha, B. Rapid increases in the steady state concentration of reactive oxygen species in the lungs and heart after particulate air pollution inhalation Environ. Health Perspect. 2002, 110, 749-755
15. Kehrer, J. P. Free radicals as mediators of tissue injury and disease Crit. Rev. Toxicol. 1993, 23, 21-48
16. Antonini, J. M.; Clarke, R. W.; Krishna Murthy, G. G.; Sreekanthan, P.; Jenkins, N.; Eagar, T. W.; Brain, J. D. Freshly generated stainless steel welding fume induces greater lung inflammation in rats as compared to aged fume Toxicol. Lett. 1998, 98, 77-86
17. Hasson, A. S.; Paulson, S. E. An investigation of the relationship between gas-phase and aerosol-bourne hydroperoxides in urban air J. Aerosol Sci. 2003, 34, 459-468
18. Hung, H.-F.; Wang, C.-S. Experimental determination of reactive oxygen species in Taipei aerosols J. Aerosol Sci. 2001, 32, 1201-1211
19. Venkatachari, P.; Hopke, P. K.; Grover, B. D.; Eatough, D. J. Measurement of particle-bound reactive oxygen species in Rubidoux aerosols J. Atmos. Chem. 2005, 50, 49-58
20. Chen, X.; Hopke, P. K. Secondary organic aerosol from á-pinene ozonolysis in dynamic chamber system Indoor Air 2009, 19, 335-345
21. Chen, X.; Hopke, P. K. A chamber study of secondary organic aerosol formation by linalool ozonolysis Atmos. Environ. 2009, 43, 3935-3940
22. Chen, X.; Hopke, P. K. A chamber study of secondary organic aerosol formation by limonene ozonolysis Indoor Air 2010, 20, 320-328
23. Cho, A. K.; Sioutas, C.; Miguel, A. H.; Kumagai, Y.; Schmitz, D. A.; Singh, M.; Eiguren-Fernandez, A.; Froines, J. R. Redox activity of airborne particulate matter at different sites in the Los Angeles Basin Environ. Res. 2005, 99, 40-47
24. Hasson, A. S.; Paulson, S. E. An investigation of the relationship between gas-phase and aerosol-bourne hydroperoxides in urban air J. Aerosol Sci. 2003, 34, 459-468
25. Venkatachari, P.; Hopke, P. K. Development and Laboratory Testing of an Automated Monitor for the Measurement of Atmospheric Particle-bound Reactive Oxygen Species (ROS) Aerosol Sci. Technol. 2008, 42, 629-635
26. 3 Environ. Sci. Technol. 1997, 31, 896-904
27. Kwok, E. S.; Atkinson, R. Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: an update Atmos. Environ. 1995, 29, 1685-1695
28. 3 with a series of monoterpenes J. Atmos. Chem. 1994, 18, 75-102
29. Ng, N. L.; Kroll, J. H.; Keywood, M. D.; Bahreini, R.; Varubangkul, V.; Flagan, R. C.; Seinfeld, J. H. Contribution of first versus second generation products to secondary organic aerosols formed in the oxidation of biogenic hydrocarbons Environ. Sci. Technol. 2006, 40, 2283-2297
30. Hoffmann, T.; Odum, J. R.; Bowman, F.; Collins, D.; Klockow, D.; Flagan, R. C.; Seinfeld, J. H. Formation of organic aerosols from the oxidation of biogenic hydrocarbons J. Atmos. Chem. 1997, 26, 189-222
31. Venkatachari, P.; Hopke, P. K. Characterization of products formed in the reaction of ozone with α-pinene: Case for organic peroxides J. Environ. Monit. 2008, 10, 966-974
32. Pankow, J. F. An absorption model of gas-particle partitioning of organiccompounds in the atmosphere Atmos. Environ. 1994, 28, 185-188
33. Pankow, J. F. An absorption model of gas aerosol partitioning involved in the formation of secondary organic aerosol Atmos. Environ. 1994, 28, 189-193
34. Kroll, J. H.; Seinfeld, J. H. Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere Atmos. Environ. 2008, 42, 3593-3624
35. Alfarra, M. R.; Prevot, A. S. H.; Duplissy, J.; Metzger, A.; Lanz, V. A.; Hueglin, C.; Dommen, J.; Weingartner, E.; Baltensperger, U. Oxygenated organic aerosols: bridging field and smog chamber observations Proceedings of European Aerosol Conference, T01A026, Salzburg, September 9-14, 2007.
36. Bäcktorp, G.; Tobias Johanson Wass, J. R.; Panas, I.; Sköld, M.; Börje, A.; Nyman, G. Theoretical investigation of linalool oxidation J. Phys. Chem. A 2006, 110, 12204-12212
37. Venkatachari, P.; Hopke, P. K. Development and evaluation of a particle-bound reactive oxygen species generator J. Aerosol Sci. 2008, 39, 168-174