Secondary organic aerosol from α-pinene ozonolysis in dynamic chamber system

Indoor Air

Volumn 19, Issue 4, 2009, Pages 335-345

  Chen, X ^a,b   Hopke, P K ^a  

^a CLARKSON UNIVERSITY   (United States)

^b Clarkson University   (United States)

Author keywords

Density; Indoor aerosol; ROS; SOA; Pinene

Indexed keywords

AEROSOLS; OLEFINS; OZONE;

AEROSOL MASS LOADING; CHAMBER SYSTEM; DENSITY; DYNAMIC CHAMBER; INDOOR AEROSOLS; ORGANIC AEROSOL; OZONOLYSIS; ROS; SECONDARY ORGANIC AEROSOL; Α-PINENE;

MONOTERPENES;

2 PINENE OXIDE; 2-PINENE OXIDE; OZONE; TERPENE;

AEROSOL; AIR POLLUTANT; ARTICLE; CHEMISTRY;

AEROSOLS; AIR POLLUTANTS; OZONE; TERPENES;

EID: 67650172795     PISSN: 09056947     EISSN: 16000668     Source Type: Journal    
DOI: 10.1111/j.1600-0668.2009.00596.x     Document Type: Article

References (35)

1. Alfarra, M.R., Prevot, A.S.H., Duplissy, J., Metzger, A., Lanz, V.A., Hueglin, C., Dommen, J., Weingartner, E. Baltensperger, U. (2007) Oxygenated organic aerosols:bridging field and smog chamber observations. Proceedings of European Aerosol Conference 2007, Salzburg, 9-14 September, T01A026.
2. Destaillats, H., Lunden, M.M., Singer, B.C., Coleman, B.K., Hodgson, A.T., Weschler, C.J. Nazaroff, W.W. (2006) Indoor secondary pollutants from household product emissions in the presence of ozone: a bench scale chamber study, Environ. Sci. Technol., 40, 4421 4428.
3. 3, Environ. Sci. Technol., 39, 4049 4059.
4. Fan, Z., Lioy, P., Weschler, C., Fiedler, N., Kipen, H. Zhang, J. (2003) Ozone-initiated reactions with mixtures of volatile organic compounds under simulated indoor conditions, Environ. Sci. Technol., 37, 1811 1821.
5. Fan, Z., Weschler, C.J., Han, I. Zhang, J. (2005) Co-formation of hydroperoxides and ultra-fine particles during the reactions of ozone with a complex VOC mixture under simulated indoor conditions, Atmos. Environ., 39, 6171 5182.
6. Forstner, H.J.L., Flagan, R.C. Seinfeld, J.H. (1997) Molecular speciation of secondary organic aerosol from photooxidation of the higher alenens: 1-octene and 1-decene, Atmos. Environ., 31, 1953 1964.
7. Harris, G.W., Carter, W.P.L., Winer, A.M., Graham, R.A. Potts, J.N. Jr. (1982) Studies of trace non-ozone species produced in a corona discharge ozonizer, J. Air Pollut. Control Assoc., 32, 274 276.
8. Hopke, P.K., Ramamurthi, M., Knutson, E.O., Tu, K.W., Scofield, P., Holub, R.F., Cheng, Y.S., Su, Y.F., Winklmayr, W., Strong, J.C., Solomon, S. Reineking, A. (1992) The Measurement of Activity-Weighted Size Distribution of Radon Progeny: Methods and Laboratory Intercomparison Studies, Health Phys., 63, 560 570.
9. Hung, H.-F. Wang, C.-S. (2001) Experimental determination of reactive oxygen species in Taipei aerosols, J. Aerosol Sci., 32, 1201 1211.
10. Kalberer, M., Yu, J., Cocker, D.R., Flagan, R.C. Seinfeld, J.H. (2000) Aerosol formation in the cyclohexene-ozone system, Environ. Sci. Technol., 34, 4894 4901.
11. Kamens, R., Jang, M., Chien, C. Leach, K. (1999) Aerosol formation from the reaction of -pinene and ozone using a gas phase kinetics aerosol partitioning model, Environ. Sci. Technol., 33, 1430 1438.
12. Lee, A., Goldstein, A.H., Keywood, M.D., Gao, S., Varutbangkul, V., Bahreini, R., Ng, N.L., Flagan, R.C. Seinfeld, J.H. (2006) Gas-phase products and secondary aerosol yields from ozonolysis of ten different terpenes, J. Geophys. Res., 111, doi :.
13. Miguel, A.H. Natusch, D.F.S. (1975) Diffusion Cell for the Preparation of Dilute Vapor Concentrations, Anal. Chem., 47, 1705 1707.
14. Nazaroff, W.M. Weschler, C.J. (2004) Cleaning products and air fresheners: exposure to primary and secondary air pollutants, Atmos. Environ., 38, 2841 2865.
15. Ng, N.L., Kroll, J.H., Keywood, M.D., Bahreini, R., Varubangkul, V., Flagan, R.C. Seinfeld, J.H. (2006) Contribution of first versus second generation products to secondary organic aerosols formed in the oxidation of biogenic hydrocarbons, Environ. Sci. Technol., 40, 2283 2297.
16. Nozière, B., Barnes, I. Becker, K.H. (1999) Product study and mechanisms of the reactions of -pinene and pinonaldehyde with OH radicals, J. Geophys. Res., 104, 23, 645 23, 656.
17. Odum, J.R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R.C. Seinfeld, J.H. (1996) Gas-particle partitioning and secondary organic aerosol yields, Environ. Sci. Technol., 30, 2580 2585.
18. Pankow, J.F. (1994a) An absorption model of gas-particle partitioning of organic compounds in the atmosphere, Atmos. Environ., 28, 185 188.
19. Pankow, J.F. (1994b) An absorption model of gas aerosol partitioning involved in the formation of secondary organic aerosol, Atmos. Environ., 28, 189 193.
20. x Cluster Aerosol, J. Aerosol Sci., 21, 203 211.
21. Rogge, W.F., Hildemann, L.M. Cass, G.R. (1993) Quantification of urban organic aerosols at a molecular level: Identification, abundance and seasonal variation, Atmos. Environ., 27, 1309 1330.
22. Sarwar, G., Corsi, R., Kimura, Y., Allen, D. Weschler, C.J. (2002) Hydroxyl radicals in indoor environments, Atmos. Environ., 36, 3973 3988.
23. Sarwar, G., Corsi, R., Allen, D. Weschler, C. (2003) The significance of secondary organic aerosol formation and growth in building: experimental and computational evidence, Atmos. Environ., 37, 1365 1381.
24. Singer, B.C., Coleman, B.K., Destaillats, H., Hodgson, A.T., Lunden, M.M., Weschler, C.J. Nazaroff, W.W. (2006) Indoor secondary pollutants from cleaning product and air freshener use in the presence of ozone, Atmos. Environ., 40, 6696 6710. (Pubitemid 46550292)
25. 2.5 mass concentrations: revisiting common assumptions for estimating organic mass, Aerosol Sci. Technol., 35, 602 610.
26. Venkatachari, P. Hopke, P.K. (2008) Characterization of Products Formed in the Reaction of Ozone with -Pinene: Case for Organic Peroxides, J. Environ. Monitor., 10, 966 974.
27. Venkatachari, P., Hopke, P.K., Grover, B.D. Eatough, D.J. (2005) Measurement of particle-bound reactive oxygen species in Rubidoux aerosols, J. Atmos. Chem., 50, 49 58.
28. Venkatachari, P., Hopke, P.K., Brune, W.H., Ren, X., Lesher, R., Mao, J. Mitchell, M. (2007) Characterization of wintertime reactive oxygen species concentrations in Flushing, New York, Aerosol Sci. Technol., 41, 97 111.
29. Weschler, C.J. (2000) Ozone in indoor environments: concentration and chemistry, Indoor Air, 10, 269 288.
30. Weschler, C.J. (2004) Chemical reactions among indoor pollutants: what we've learned in the new millennium, Indoor Air, 14, 184 194.
31. Weschler, C.J. Shields, H.C. (1996) Production of hydroxyl radicals in indoor air, Environ. Sci. Technol., 30, 3250 3258.
32. Weschler, C.J. Shields, H.C. (1999) Indoor ozone-terpene reactions as a source of indoor particles, Atmos. Environ., 33, 2301 2312.
33. Yu, J., Flagan, R.C. Seinfeld, J.H. (1998) Identification of products containing -COOH, -OH, -C=O in atmospheric oxidation of hydrocarbons, Environ. Sci. Technol., 32, 2357 2370.
34. Yu, J., Cocker, D.R., Griffin, R.J., Flagan, R.C. Seinfeld, J.H. (1999a) Gas phase ozone oxidation of monoterpenenes: gaseous and particulate products, Journal of Atmospheric Chemistry, 34, 207 258. (Pubitemid 29414656)
35. x, Atmos. Environ., 42, 5044 5060.