Extraction and third phase formation behavior of Eu(III) in CMPO-TBP extractants present in room temperature ionic liquid

Separation and Purification Technology

Volumn 76, Issue 3, 2011, Pages 238-243

  Rout, Alok ^a   Venkatesan, K A ^a   Srinivasan, T G ^a   Vasudeva Rao, P R ^a  

^a INDIRA GANDHI CENTRE FOR ATOMIC RESEARCH   (India)

Author keywords

Europium; Extraction; N Octyl(phenyl) N,N diisobutylcarbamoylmethylphosphine oxide; Room temperature ionic liquid; Third phase

Indexed keywords

BIS(TRIFLUOROMETHANE SULFONYL)IMIDE; DISTRIBUTION RATIO; ENTHALPY CHANGE; EXTRACTANTS; MAXIMUM VALUES; N-OCTYL(PHENYL)-N,N- DIISOBUTYLCARBAMOYLMETHYLPHOSPHINE OXIDE; ORGANIC PHASE; ROOM TEMPERATURE IONIC LIQUIDS; THIRD PHASE; THIRD PHASE FORMATION; TRACE LEVEL; TRI-N-BUTYLPHOSPHATE;

IONIC LIQUIDS; IONS; LOADING; NITRIC ACID; STOICHIOMETRY; TRACE ELEMENTS;

EUROPIUM;

EID: 78650520450     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2010.10.009     Document Type: Article

References (29)

1. T. Welton Room-temperature ionic liquids. Solvents for synthesis and catalysis Chem. Rev. 99 8 1999 2071 2084
2. J.G. Huddleston, H.D. Willauer, R.P. Swatloski, A.E. Visser, and R.D. Rogers Room temperature ionic liquids as novel media for 'clean' liquid-liquid extraction Chem. Commun. 1998 1765 1766
3. J.F. Brennecke, and E.J. Maginn Ionic liquids: innovative fluids for chemical processing AlChE J. 47 11 2001 2384 2389
4. A.E. Visser, R.P. Swatloski, W.M. Reichert, S.T. Griffin, and R.D. Rogers Traditional extractants in non-traditional solvents: group 1 and 2 extraction by crown ethers in room temperature ionic liquids Ind. Eng. Chem. Res. 39 10 2000 3596 3604
5. M.L. Dietz, and D.C. Stepinski Anion concentration-dependent partitioning mechanism in the extraction of uranium into room-temperature ionic liquids Talanta 75 2 2008 598 603
6. P. Giridhar, K.A. Venkatesan, T.G. Srinivasan, and P.R. Vasudeva Rao Extraction of uranium (VI) by 1.1 M tri-n-butylphosphate/ionic liquid and the feasibility of recovery by direct electrodeposition from organic phase J. Alloys Compd. 448 1-2 2008 104 108
7. 2N] Inorg. Chem. 44 25 2005 9497 9505
8. 2] Inorg. Chem. 44 14 2005 4934 4940
9. P. Giridhar, K.A. Venkatesan, T.G. Srinivasan, and P.R. Vasudeva Rao Electrochemical behavior of uranium(VI) in 1-butyl-3-methylimidazolium chloride and thermal characterization of uranium oxide deposit Electrochim. Acta 52 9 2007 3006 3012
10. M. Jayakumar, K.A. Venkatesan, and T.G. Srinivasan Electrochemical behavior of rhodium(III) in 1-butyl-3-methylimidazolium chloride ionic liquid Electrochim. Acta 53 6 2008 2794 2801
11. P.V. Natalia, and K.R. Seddon Applications of ionic liquids in the chemical industry Chem. Soc. Rev. 37 1 2008 123 150
12. K. Binnemans Lanthanides and actinides in ionic liquids Chem. Rev. 107 6 2007 2592 2614
13. V.A. Cocalia, K.E. Gutowski, and R.D. Rogers The coordination chemistry of actinides in ionic liquids. A review of experiment and simulation Coord. Chem. Rev. 250 7-8 2006 755 764
14. K.A. Venkatesan, T.G. Srinivasan, and P.R. Vasudeva Rao A review on the electrochemical applications of room temperature ionic liquids in nuclear fuel cycle J. Radiochem. Nucl. Sci. 10 1 2009 R1
15. J.L. Swanson, and J.L. Swanson PUREX process flow-sheets W.W. Schulz, L.L. Burger, J.D. Navratil, K.P. Bender, Science and Technology of Tributyl Phosphate vol. III 1984 CRC Press, Inc. Boca Raton pp. 55
16. W.W. Schulz, and E.P. Horwitz Recent progress in the extraction chemistry of actinide ions J. Less-Common Met. 122 2 1986 125 138
17. E.P. Horwitz, D.G. Kalina, L. Kalpan, G.W. Mason, and H.D. Diamond Selected alkyl(phenyl)-N,N-dialkylcarbamoylmethylphosphine oxides as extractants for Am(III) from nitric acid media Sep. Sci. Technol. 17 10 1982 1261 1279
18. A.E. Visser, and R.D. Rogers Room-temperature ionic liquids: new solvents for f-element separations and associated solution chemistry J. Solid State Chem. 171 1-2 2003 109 113
19. K. Nakashima, F. Kubota, T. Maruyama, and M. Goto Feasibility of ionic liquids as alternative separation media for industrial solvent extraction process Ind. Eng. Chem. Res. 44 12 2005 4368 4372
20. A. Rout, K.A. Venkatesan, T.G. Srinivasan, and P.R. Vasudev Rao Extraction of americium(III) from nitric acid medium by CMPO-TBP extractants in ionic liquid diluent Radiochim. Acta 97 12 2009 719 725
21. A. Suresh, C.V.S. Brahmananda Rao, K.N. Sabharwal, T.G. Srinivasan, and P.R. Vasudeva Rao Third phase formation in the extraction of Nd(III) by octyl(phenyl)-N,N-diisobutyl carbamoyl methylphosphinoxide (OΦCMPO) Solvent Extr. Ion Exch. 17 1 1999 73 78
22. P.R. Vasudev Rao, and Z. Kolarik A review of third phase formation in extraction of actinides by neutral organophosphorus extractants Solvent Extr. Ion Exch. 14 6 1996 955 993
23. S. Belair, A. Labet, C. Mariet, and P. Dannus Modeling of the extraction of nitric acid and neodymium nitrate from aqueous solutions over a wide range of activities by CMPO Solvent Extr. Ion Exch. 23 4 2005 481 499
24. M.L.P. Reddy, A. Damodaran, J.N. Mathur, M.S. Murali, M.V. Balarama Krishna, and R.H. Iyer The itinerant extraction behavior of f-elements and yttrium with octyl(phenyl)-N,N-diisobutylcarbamoyl-methylphosphine oxide Solvent Extr. Ion Exch. 14 5 1996 793 816
25. M.Y. Koma, S. Watanabe, and Y. Namoto Trivalent f-element intra-group separation by solvent extraction with CMPO-complexant system J. Nucl. Sci. Technol. 35 2 1998 130 136
26. E.P. Horwitz, M.A. Kalina, and L. Kaplan The extraction of selected transplutonium (III) and lanthanide (III) ions by dihexyl-N,N- diethylcarbamoylmethylphosphonate from aqueous nitrate media Sep. Sci. Technol. 16 4 1981 417 437
27. S. Nagasaki, D.S. Wisnubroto, Y. Enokida, and A. Suzuki Third phase formation in nitric acid extraction by octyl(phenyl)-N,N-diisobutyl carbamoyl methylphosphinoxide Solvent Extr. Ion Exch. 12 2 1994 459 473
28. J.N. Mathur, M.S. Murali, P.R. Natrajan, L.P. Badheka, and A. Banerji Extraction of actinides and fission products by octyl(phenyl)-N,N- diisobutylcarbamoylmethyl-phosphine oxide from nitric acid media Talanta 39 5 1992 493 496
29. W. Liansheng, M. Casarci, and G.M. Gasparini The extraction of Eu(III) from acidic media by octyl(phenyl)-N,N-diisobutyl carbamoyl methylphosphinoxide Solvent Extr. Ion Exch. 8 1 1990 49 64