Theoretical study of 1,6-anhydrosugar formation from phenyl d-glucosides under basic condition: Reasons for higher reactivity of β-anomer

Journal of Organic Chemistry

Volumn 75, Issue 24, 2010, Pages 8400-8409

  Hosoya, Takashi ^a   Nakao, Yoshihide ^a   Sato, Hirofumi ^a   Sakaki, Shigeyoshi ^b  

^a KYOTO UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; ANOMERIC CARBON; ANOMERICS; BASIC CONDITIONS; COMPUTATIONAL RESULTS; EXPERIMENTAL OBSERVATION; LEVOGLUCOSAN; METHYLENE GROUPS; OH GROUP; OXYANIONS; STEREOELECTRONIC EFFECT; THEORETICAL STUDY; TRANSITION STATE;

ACTIVATION ENERGY; CARBOHYDRATES; CHARGE TRANSFER; ION EXCHANGE; OXYGEN; POSITIVE IONS;

DEGRADATION;

ACID ANHYDRIDE; ANION; CARBENE; CARBON; GLUCOSIDE; HYDROXYL GROUP; LEVOGLUCOSAN; NUCLEOPHILE; OXYGEN; PHENYL GROUP; SUGAR;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CONFORMATION; DEGRADATION; ELECTRON; ELECTRON TRANSPORT; PROTON TRANSPORT; STEREOCHEMISTRY; THEORY;

EID: 78650376444     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101494g     Document Type: Article

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