Layered organoclay with talc-like structure as agent for thermodynamics of cations sorption at the solid/liquid interface

Chemical Engineering Journal

Volumn 166, Issue 1, 2011, Pages 420-427

  Badshah, Syed ^a   Airoldi, Claudio ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

Author keywords

1,2 Ethanedithiol; Cations removal; Organoclay; Phyllosilicate; Thermodynamic

Indexed keywords

1,2-ETHANEDITHIOL; CADMIUM CATIONS; CALORIMETRIC TITRATION; CATION REMOVAL; CATIONS REMOVAL; COVALENTLY BONDED; ELEMENTAL ANALYSIS; EXOTHERMIC ENTHALPY; FAVORABLE CONDITIONS; GIBBS ENERGY; HYDROLYSIS AND CONDENSATION; LAMELLAR MATERIAL; LANGMUIR MODELS; MAGNESIUM NITRATE; MAGNESIUM PHYLLOSILICATE; NMR SPECTRUM; ORGANIC MOIETY; PHYLLOSILICATE; SILYLATING AGENT; SOLID/LIQUID INTERFACES; SORPTION CAPACITIES; THERMODYNAMIC DATA; TRIETHOXYSILYL;

CADMIUM; CONDENSATION REACTIONS; DIFFRACTION; GELS; HYBRID MATERIALS; INFRARED SPECTROSCOPY; MAGNESIUM; NITROGEN REMOVAL; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOCLAY; OXYGEN; POSITIVE IONS; RESONANCE; SILICATE MINERALS; SOL-GEL PROCESS; SOL-GELS; SOLS; SORPTION; SULFUR; TALC; THERMODYNAMICS; X RAY DIFFRACTION;

CADMIUM COMPOUNDS;

EID: 78650311503     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2010.10.078     Document Type: Article

References (36)

1. Agadic I.L., Mitchell M.K., Payne B.R. Highly effective adsorption of heavy metal ions by a thiol functionalized magnesium phyllosilicate clay. Environ. Sci. Technol. 2001, 35:984-990.
2. O'Connell D.W., Birkinshaw C., O'Dwyer T.F. Heavy metal adsorbents prepared from the modification of cellulose: a review. Bioresour. Technol. 2008, 99:6709-6724.
3. Flora S.J.S., Mittal M., Mehta A. Heavy metal induced oxidative stress & its possible reversal by chelation therapy. Indian J. Med. Res. 2008, 128:501-523.
4. Agbozu I.E., Ekweozor I.K.E., Opuene K. Survey of heavy metals in the catfish Synodontis clarias. Int. J. Environ. Sci. Technol. 2007, 4:93-97.
5. Ray S.A., Ray M.K. Bioremediation of heavy metal toxicity with special reference to chromium. Al Ameen J. Med. Sci. 2009, 2:57-63.
6. White L.D., Slechta D.A.C., Gilbert M.E., Castiglioni E.T., Zawia N.H., Virgolini M., George A.R., Lasley S.M., Qian Y.C., Basha M.R. New and evolving concepts in the neurotoxicology of lead. Toxicol. Appl. Pharmacol. 2007, 225:1-27.
7. Needleman H. Lead poisoning. Annu. Rev. Med. 2004, 55:209-222.
8. Yousif A.S., Ahmed A.A. Effects of cadmium (Cd) and lead (Pb) on the structure and function of thyroid gland. Afr. J. Environ. Sci. Technol. 2009, 3:78-85.
9. Namasivayam C., Sangeetha D., Gunasekaran R. Removal of anions, heavy metals, organics and dyes from water by adsorption onto a new activated carbon from Jatropha husk, an agro-industrial solid waste. Process Saf. Environ. Prot. 2007, 85:181-184.
10. Erdem E., Karapinar N., Donate R. The removal of heavy metal cations by natural zeolites. J. Colloid Interface Sci. 2004, 280:309-314.
11. Potgieter J.H., Potgieter-Vermaak S.S., Kalibantonga P.D. Heavy metals removal from solution by palygorskite clay. Miner. Eng. 2006, 19:463-470.
12. Bailey S.E., Olin T.J., Bricka R.M., Adrian D.D. A review of potentially low-cost sorbents for heavy metals. Water Res. 1999, 33:2469-2479.
13. Mercier L., Detellier C. Preparation, characterization and applications as heavy metals sorbents of covalently grafted thiol functionalities on the interlamelar surface of montmorillonite. Environ. Sci. Technol. 1995, 29:1318-1323.
14. Sheng G., Boyd S.A. A dual function organoclay sorbent for lead and chlorobenzene. Soil Sci. Soc. Am. J. 1999, 63:73-78.
15. Mercier L., Pinnavaia T.J. A functionalized porous clay heterostructure for heavy metal ion (Hg2+) trapping. Microporous Mesoporous Mater. 1998, 20:101-106.
16. Fonseca M.G., Silva C.R., Barone J.A.S., Airoldi C. Layered hybrid nickel phyllosilicates and reactivity of the gallery space. J. Mater. Chem. 2000, 10:789-795.
17. Dey R.K., Oliveira A.S., Patnaik T., Singh V.K., Tiwary D., Airoldi C. Grafting of organosilane derived from 3-glycidoxypropyltrimethoxysilane thiourea onto magnesium phyllosilicate by sol-gel process and investigation of metal adsorption properties. J. Solid State Chem. 2009, 182:2010-2017.
18. Fonseca M.G., Airoldi C. Mercaptopropyl magnesium phyllosilicate-thermodynamic data on the interaction with divalent cations in aqueous solution. Thermochim. Acta 2000, 359:1-9.
19. Fonseca M.G., Airoldi C. New layered inorganic-organic nanocomposites containing n-propylmercapto copper phyllosilicates. J. Mater. Chem. 2000, 10:1457-1463.
20. Mizutani T., Fukushima Y., Okada A., Kamigaito O. Synthesis of nickel and magnesium phyllosilicates with 1:1 and 2:1 layer structures. Bull. Chem. Soc. Jpn. 1990, 63:2094-2298.
21. Carrado K.A., Xu L., Csencsits R., Muntean J.V. Use of organo- and alkoxysilanes in the synthesis of grafted and pristine clays. Chem. Mater. 2001, 13:3766-3773.
22. Sales J.A.A., Petrucelli G.C., Oliveira F.J.E., Airoldi C. Some features associated with organosilane groups grafted by the sol-gel process onto synthetic talc-like phyllosilicate. J. Colloid Interface Sci. 2006, 297:95-103.
23. Moscofian A.S.O., Airoldi C. Synthesized layered inorganic-organic magnesium organosilicate containing a disulfide moiety as a promising sorbent for cations removal. J. Hazard. Mater. 2008, 160:63-69.
24. Ukrainczky L., Bellman R.A., Anderson A.B. Template synthesis and characterization of layered Al- and Mg-silsesquioxanes. J. Phys. Chem. B 1997, 107:531-539.
25. Melo M.A., Airoldi C. Energetic features of copper and lead sorption by innovative aminoalcohol-functionalized cobalt phyllosilicates. Dalton Trans. 2010, 39:10217-10227.
26. Oliveira F.J.V.E., da Filho E.C.S., Melo M.A., Airoldi C. Modified coupling agents based on thiourea, immobilized onto silica. Thermodynamics of copper adsorption. Surf. Sci. 2009, 603:2200-2206.
27. Lima C.B.A., Airoldi C. Crystalline calcium phenylphosphonate-thermodynamic data on n-alkylmonoamine intercalations. Thermochim. Acta 2003, 400:51-59.
28. Burkett S.L., Press A., Mann S. Layered inorganic-organic nanocomposites based on 2:1 trioctahedral phyllosilicates. Chem. Mater. 1997, 9:1071-1073.
29. Quintanilla D.P., Del Hierro I., Fajardo M., Serra I. 2-Mercaptothiazoline modified mesoporous silica for mercury removal from aqueous media. J. Hazard. Mater. 2006, 134:245-256.
30. Silva C.R., Fonseca M.G., Barone J.S., Airoldi C. Layered inorganic-organic talc-like nanocomposites. Chem. Mater. 2002, 14:3829-3836.
31. Fonseca M.G., Silva C.R., Airoldi C. Aminated phyllosilicates synthesized via a sol-gel process. Langmuir 1999, 15:5048-5055.
32. Jaber M., Brandle J.M., Delmotte L., Dred R.L. New range of Al-Mg organoclays with tailored hydrophobicity: incorporation of fluoride as a local probe to study the octahedral character. Microporous Mesoporous Mater. 2003, 65:155-163.
33. Jaber M., Brandle J.M., Delmotte L., Dred R.L. Formation of organoclays by a one step synthesis. Solid State Sci. 2005, 7:610-615.
34. Melo M.A., Oliveira F.J.V.E., Airoldi C. Novel talc-like nickel phyllosilicates functionalized with ethanolamine and diethanolamine. Appl. Clay Sci. 2008, 42:130-136.
35. Marcus Y. Ion Solvation 1985, John Wiley, New York.
36. Macedo T.R., Petrucelli G.C., Airoldi C. Sorption and thermodynamics of cation-basic center interactions of inorganic-organic hybrids synthesized from RUB-18. Thermochim. Acta 2010, 502:30-34.