Dicarbonyl pentaphenylcyclopentadienyl iron complex for living radical polymerization: Smooth generation of real active catalysts collaborating with phosphine ligand

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 49, Issue 2, 2011, Pages 537-544

  Ishio, Muneki ^a   Ouchi, Makoto ^a   Sawamoto, Mitsuo ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

catalysis; FTIR; living polymerization; living radical polymerization (LRP); metal organic catalysts organometallic catalysts; radical polymerization

Indexed keywords

ACTIVE CATALYST; BROMIDE INITIATORS; CARBONYL LIGAND; CATALYTIC ACTIVITY; CATALYTIC AMOUNTS; CYCLOPENTADIENES; FTIR; IN-SITU; IRON COMPLEX; LIGAND EXCHANGES; LIVING RADICAL POLYMERIZATION; METAL-ORGANIC CATALYSTS/ORGANOMETALLIC CATALYSTS; METHYL METHACRYLATES; MODEL REACTIONS; MOLECULAR WEIGHT POLYMERS; MONOMER ADDITION; NARROW MOLECULAR WEIGHT DISTRIBUTIONS; NMR ANALYSIS; PENTAPHENYLCYCLOPENTADIENYL; PHOSPHINE LIGANDS; PRECISE CONTROL; RADICAL POLYMERIZATION; SMOOTH TRANSFORMATION; STABLE COMPLEXES; TRIPHENYL PHOSPHINES;

ATOM TRANSFER RADICAL POLYMERIZATION; BROMINE COMPOUNDS; CATALYSIS; CATALYST ACTIVITY; ESTERS; FREE RADICAL POLYMERIZATION; IRON COMPOUNDS; LIGANDS; MOLECULAR WEIGHT DISTRIBUTION; OLEFINS; PHOSPHORUS; PHOSPHORUS COMPOUNDS; POLYMERS;

ACRYLIC MONOMERS;

EID: 78650287779     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.24468     Document Type: Article

References (42)

1. Crabtree, R. H., The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2001.
2. (a), Kato, M., Kamigaito, M., Sawamoto, M., Higashimura, T., Macromolecules 1995, 28, 1721-1723
3. (b), Ando, T., Kato, M., Kamigaito, M., Sawamoto, M., Macromolecules 1996, 29, 1070-1072.
4. For recent reviews on transition metal-catalyzed living radical polymerization, see
5. (a), Kamigaito, M., Ando, T., Sawamoto, M., Chem Rev 2001, 101, 3689-3745
6. (b), Kamigaito, M., Ando, T., Sawamoto, M., Chem Rec 2004, 4, 159-175
7. (c), Ouchi, M., Terashima, T., Sawamoto, M., Acc Chem Res 2008, 41, 1120-1132
8. (d), Ouchi, M., Terashima, T., Sawamoto, M., Chem Rev 2009, 109, 4963-5050
9. (e), Matyjaszewski, K., Xja, J., Chem Rev 2001, 101, 2921-2990.
10. (a), Bolm, C., Legros, J., Paih, J. L., Zani, L., Chem Rev 2004, 104, 6217-6254
11. (b), Enthaler, S., Junge, K., Beller, M., Angew Chem Int Ed 2008, 47, 3317-3321.
12. Ando, T., Kamigaito, M., Sawamoto, M., Macromolecules 1997, 30, 4507-4510.
13. Matyjaszewski, K., Wei, M., Xia, J., McDermott, N. E., Macromolecules 1997, 30, 8161-8164.
14. Kotani, Y., Kamigaito, M., Sawamoto, M., Macromolecules 1999, 32, 6877-6880.
15. Kotani, Y., Kamigaito, M., Sawamoto, M., Macromolecules 2000, 33, 3543-3549.
16. Zhu, S., Yan, D., Macromolecules 2000, 33, 8233-8238.
17. Louie, Y., Grubbs, R. H., Chem Commun 2000, 1479-1480.
18. Göbelt, B., Matyjaszewski, K., Macromol Chem Phys 2000, 201, 1619-1624.
19. Gibson, V. C., O'Reilly, R. K., Reed, W., Wass, D. F., White, A. J. P., Williams, D. J., Chem Commun 2002, 1850-1851.
20. O'Reilly, R. K., Gibson, V. C., White, A. J. P., Williams, D. J., J Am Chem Soc 2003, 125, 8450-8451.
21. Xue, Z., Lee, B. W., Noh, S. K., Lyoo, W. S., Polymer 2007, 48, 4704-4714.
22. Niibayashi, S., Hayakawa, H., Jin, R.-H., Nagashima, H., Chem Commun 2007, 1855-1857.
23. Uchiike, C., Terashima, T., Ouchi, M., Ando, T., Kamigaito, M., Sawamoto, M., Macromolecules 2007, 40, 8658-8662.
24. Ferro, R., Milione, S., Bertolasi, V., Capacchione, C., Grassi, A., Macromolecules 2007, 40, 8544-8546.
25. Uchiike, C., Ouchi, M., Ando, T., Kamigaito, M., Sawamoto, M., J Polym Sci Part A: Polym Chem 2008, 46, 6819-6827.
26. Ishio, M., Katsube, M., Ouchi, M., Sawamoto, M., Inoue, Y., Macromolecules 2009, 42, 188-193.
27. Takahashi, H., Ando, T., Kamigaito, M., Sawamoto, M., Macromolecules 1999, 32, 3820-3823.
28. Watanabe, T., Ando, T., Kamigaito, M., Sawamoto, M., Macromolecules 2001, 34, 4370-4374.
29. Ouchi, M., Ito, M., Kamemoto, S., Sawamoto, M., Chem Asian J 2008, 3, 1358-1364.
30. Ishio, M., Terashima, T., Ouchi, M., Sawamoto, M., Polym J 2010, 42, 17-24.
31. Ishio, M., Terashima, T., Ouchi, M., Sawamoto, M., Macromolecules 2010, 43, 920-926.
32. Ando, T., Kamigaito, M., Sawamoto, M., Macromolecules 2000, 33, 5825-5829.
33. Janiak, C., Schumann, H., Adv Organomet Chem 1991, 33, 291-393.
34. Adams, H., Bailey, N. A., Browning, A. F., Ramsden, J. A., White, C. J., Organomet Chem 1990, 387, 305-314.
35. Broadley, K., Lane, G. A., Connelly, N. G., Geiger, W. E., J Am Chem Soc 1983, 105, 2486-2487.
36. Fu, G., Acc Chem Res 2000, 33, 412-420.
37. McVey, S., Pauson, P. L., J Chem Soc 1965, AUG, 4312-4318.
38. Ando, T., Kamigaito, M., Sawamoto, M., Tetrahedron 1997, 53, 15445-15457.
39. Fischer, E. O., Moser, E., Inorg Synth 1970, 12, 35-36.
40. King, R. B., Stone, F. G., Inorg Synth 1963, 7, 99-115.
41. Field, L. D., Hambley, T. W., Lindall, C. M., Masters, A. F., Polyhedron 1989, 8, 2425-2430.
42. 2] would be too unstable to generate some divalent species for further catalysis.