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-1). The measurements showed the presence of a broad unimodal distribution centered at an average hydrodynamic radius of RH=49a nm, a value which was reproducible at different angles (see Figurea S3 in the Supporting Information). This observation confirms the formation of large aggregates in solution by means of hydrogen-bond interactions as the driving force.
-
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47
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max=323a nm). As expected, this band was not shifted after aging for over a week. We could thus rule out a π-π interaction between triazine and stilbene moieties as the driving force for supramolecular assembly.
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48
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note
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+ was used as the reference electrode. Pt wire was the counter electrode, and glassy carbon (GC) was used as the working electrode. Although the experimental data showed that the cyanurate moiety is a better acceptor than the s-triazine unit, the formation of the radical anion of the s-triazine unit cannot be ruled out (see Figurea S10 in the Supporting Information).
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