Interfacial molecular structures of polyelectrolyte brush in contact with dry nitrogen, water vapor, liquid water, and aqueous electrolyte solution studied by sum frequency generation spectroscopy

Journal of the American Chemical Society

Volumn 132, Issue 48, 2010, Pages 17271-17276

  Uosaki, Kohei ^a,b   Noguchi, Hidenori ^a,b   Yamamoto, Rie ^b   Nihonyanagi, Satoshi ^b,c  

^a NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^b HOKKAIDO UNIVERSITY   (Japan)

^c RIKEN   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS ELECTROLYTE SOLUTIONS; CONFORMATION CHANGE; CONFORMATIONAL ORDER; CONFORMATIONAL STRUCTURES; DOUBLE LAYERS; DRY NITROGEN; ELECTROLYTE CONCENTRATION; GAUCHE DEFECTS; INTERFACIAL MOLECULAR STRUCTURES; INTERFACIAL STRUCTURES; LIQUID WATER; METHYL GROUP; METHYLENE GROUPS; OH STRETCHING VIBRATIONS; ORIENTATION CHANGES; POLYELECTROLYTE BRUSHES; POLYMER BRUSHES; POLYVINYLPYRIDINE; RELATIVE INTENSITY; SIDE CHAIN LENGTHS; SIDE CHAINS; STRETCHING REGION; SUM-FREQUENCY GENERATION SPECTROSCOPY; SURFACE NORMALS; TILT ANGLE; TRANS CONFORMATIONS;

BRUSHES; CHAIN LENGTH; ELECTROLYTES; FUNCTIONAL GROUPS; LIQUIDS; NITROGEN; PERMITTIVITY; POLYMERS; STRETCHING; WATER VAPOR;

PHASE INTERFACES;

ALKYL GROUP; CARBENE; ELECTROLYTE; METHYL GROUP; NITROGEN; POLYELECTROLYTE; POLYMER; POLYVINYLPYRIDINE BRUSH; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG; WATER;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; CONCENTRATION RESPONSE; CONFORMATION; SPECTROSCOPY; STRUCTURE ANALYSIS; SUM FREQUENCY GENERATION SPECTROSCOPY; THICKNESS; VIBRATION; WATER VAPOR;

ALKYLATION; ELECTROLYTES; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NITROGEN; OSMOLAR CONCENTRATION; POLYVINYLS; SOLUTIONS; SPECTRUM ANALYSIS; VOLATILIZATION; WATER;

EID: 78650097314     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja107265q     Document Type: Article

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