Mixed matrix membranes prepared from poly(vinyl alcohol) (PVA) incorporated with zeolite 4A-graft-poly(2-hydroxyethyl methacrylate) (zeolite-g-PHEMA) for the pervaporation dehydration of water-acetone mixtures

Journal of Membrane Science

Volumn 367, Issue 1-2, 2011, Pages 182-189

  Khoonsap, Santi ^a   Amnuaypanich, Sittipong ^a  

^a Khon Kaen University   (Thailand)

Author keywords

Grafting; Mixed matrix membrane; Pervaporation; Poly(2 hydroxyethyl methacrylate); Poly(vinyl alcohol); Zeolite

Indexed keywords

ACETONE MIXTURE; CROSS-LINKED PVA; FEED TEMPERATURE; FEED WATER CONCENTRATION; GRAFT POLYMERIZATION; GRAFTING; INTERFACIAL ADHESIONS; LIQUID MIXTURE; LOW WATER; MIXED MATRIX MEMBRANES; PERVAPORATION DEHYDRATION; POLY (2HYDROXYETHYL METHACRYLATE); PREFERENTIAL SORPTION; SELECTIVE LAYERS; SILYLATIONS; SORPTION EXPERIMENTS; SWELLING DEGREE; WATER SELECTIVITY; WATER SORPTION; ZEOLITE 4A; ZEOLITE LOADING;

ACETONE; DEHYDRATION; DEWATERING; EVAPORATION; LOADING; MEMBRANES; MIXTURES; ORGANIC POLYMERS; PERVAPORATION; SORPTION;

GRAFTING (CHEMICAL);

ACETONE; HYDROXYL GROUP; MONOMER; POLY(2 HYDROXYETHYLMETHACRYLIC ACID); POLYMETHACRYLIC ACID DERIVATIVE; POLYVINYL ALCOHOL; SILANE; UNCLASSIFIED DRUG; VINYL DERIVATIVE; WATER; ZEOLITE;

ARTICLE; CONCENTRATION (PARAMETERS); CROSS LINKING; MEMBRANE PERMEABILITY; PERVAPORATION; POLYMERIZATION; PRIORITY JOURNAL; SILYLATION; TEMPERATURE; WATER FLOW; WATER PERMEABILITY;

EID: 78649952825     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2010.10.058     Document Type: Article

References (43)

1. Semenova S.I., Ohya H., Soontarapa K. Hydrophilic membranes for pervaporation: an analytical review. Desalination 1997, 110:251-286.
2. Duval J.M., Kemperman A.J.B., Folkers B., Mulder M.H.V., Desgrandchamps G., Smolders C.A. Preparation of zeolite filled glassy polymer membranes. J. Appl. Polym. Sci. 1994, 54:409-418.
3. Suer M.G., Ba N., Yilmaz L. Gas permeation characteristics of polymer-zeolite mixed matrix membranes. J. Membr. Sci. 1994, 91:77-86.
4. Clarizia G., Algieri C., Drioli E. Filler-polymer combination: a route to modify gas transport properties of a polymeric membrane. Polymer 2004, 45:5671-5681.
5. Okumuş E., Gürkan T., Yilmaz L. Effect of fabrication and process parameters on the morphology and performance of a PAN-based zeolite-filled pervaporation membrane. J. Membr. Sci. 2003, 223:23-38.
6. Huang Z., Guan H., Tan W., Qiao X.Y., Kulprathipanja S. Pervaporation study of aqueous ethanol solution through zeolite-incorporated multilayer poly(vinyl alcohol) membranes: effect of zeolites. J. Membr. Sci. 2006, 276:260-271.
7. Fu Y.J., Hu C.C., Lee K.R., Lai J.Y. Separation of ethanol/water mixtures by pervaporation through zeolite-filled polysulfone membrane containing 3-aminopropyltrimethoxysilane. Desalination 2006, 193:119-128.
8. Bhat S.D., Aminabhavi T.M. Pervaporation-aided dehydration and esterification of acetic acid with ethanol using 4A zeolite-filled cross-linked sodium alginate-mixed matrix membranes. J. Appl. Polym. Sci. 2009, 113:157-168.
9. Amnuaypanich S., Patthana J., Phinyocheep P. Mixed matrix membranes prepared from natural rubber/poly(vinyl alcohol) semi-interpenetrating polymer network (NR/PVA Semi-IPN) incorporating with zeolite 4A for the pervaporation dehydration of water-ethanol mixtures. Chem. Eng. Sci. 2009, 64:4908-4918.
10. te Hennepe H.J.C., Bargeman D., Mulder M.H.V., Smolders C.A. Zeolite-filled silicone rubber membranes: Part 1. Membrane preparation and pervaporation results. J. Membr. Sci. 1987, 35:39-55.
11. Jia M., Peinemann K.V., Behling R.D. Molecular sieving effect of zeolite filled silicone rubber membranes in gas permeation. J. Membr. Sci. 1991, 57:289-292.
12. Semenova S.I. Polymer membranes for hydrocarbon separation and removal. J. Membr. Sci. 2004, 231:189-207.
13. Vankelecom I.F.J., van der Broeck S., Merckx E., Geerts H., Grobet P., Uytterhoeven J.B. Silylation to improve incorporation of zeolites in polyimide films. J. Phys. Chem. 1996, 100:3753-3758.
14. Li Y., Guan H.M., Chung T.S., Kulprathipanja S. Effects of novel silane modification of zeolite surface on polymer chain rigidification and partial pore blockage in polyethersulfone (PES)-zeolite A mixed matrix membranes. J. Membr. Sci. 2006, 275:17-28.
15. Clarizia G., Algieri C., Regina A., Drioli E. Zeolite-based composite PEEK-WC membranes: gas transport and surface properties. Micropor. Mesopor. Mater. 2008, 115:67-74.
16. Sun H., Lu L., Chen X., Jiang Z. Surface-modified zeolite-filled chitosan membranes for pervaporation dehydration of ethanol. Appl. Surf. Sci. 2008, 254:5367-5374.
17. Marquez M., Grady B.P., Robb I. Different methods for surface modification of hydrophilic particulates with polymers. Colloid Surf. A 2005, 266:18-31.
18. Khan A.L., Cano-Odena A., Guitiérrez B., Minguillón C., Vankelecom I.F.J. Hydrogen separation and purification using polysulfone acrylate-zeolite mixed matrix membranes. J. Membr. Sci. 2010, 350:340-346.
19. Bolto B., Tran T., Hoang M., Xie Z. Crosslinked poly(vinyl alcohol) membranes. Prog. Polym. Sci. 2009, 34:969-981.
20. Vankelecom I.F.J., Dotremont C., Morobé M., Uytterhoeven J.-B., Vandecasteele C. Zeolite-filled PDMS membranes. 1. Sorption of halogenated hydrocarbons. J. Phys. Chem. B 1997, 101:2154-2159.
21. Bowen T.C., Noble R.D., Falconer J.L. Fundamentals and applications of pervaporation through zeolite membranes. J. Membr. Sci. 2004, 245:1-33.
22. Mulder M. Basic Principles of Membrane Technology 1991, Kluwer, The Netherlands.
23. Wijmans J.G., Baker R.W. The solution-diffusion model: a review. J. Membr. Sci. 1995, 107:1-21.
24. Guo W.F., Chung T.S., Matsuura T. Pervaporation study on the dehydration of aqueous butanol solutions: a comparison of flux vs. permeance, separation factor vs. selectivity. J. Membr. Sci. 2004, 245:199-210.
25. Foust A.S., Wenzel L.A., Clump C.W., Maus L., Andersen L.B. Principles of Unit Operations 1980, John Wiley and Sons, New York. second ed.
26. Aronne A., Esposito S., Ferone C., Pansini M., Pernice P. FTIR study of the thermal transformation of barium-exchanged zeolite A to celsian. J. Mater. Chem. 2002, 12:3039-3045.
27. Nguyen V., Yoshida W., Cohen Y. Graft polymerization of vinyl acetate onto silica. J. Appl. Polym. Sci. 2002, 87:300-310.
28. Demirelli K., Coşkun M., Kaya E. A detailed study of thermal degradation of poly(2-hydroxyethyl methacrylate). Polym. Degrad. Stabil. 2001, 72:75-80.
29. Chuang W.Y., Young T.H., Wang D.M., Luo R.L., Sun Y.M. Swelling behavior of hydrophobic polymers in water/ethanol mixtures. Polymer 2000, 41:8339-8347.
30. Ng E.P., Mintova S. Nanoporous materials with enhanced hydrophilicity and high water sorption capacity. Micropor. Mesopor. Mater. 2008, 114:1-26.
31. Tadros T.F. Adsorption of polyvinyl alcohol on silica at various pH values and its effect on the flocculation of the dispersion. J. Colloid Interface Sci. 1978, 64:36-47.
32. Moore T.T., Mahajan R., Vu D.Q., Koros W.J. Hybrid membrane materials comprising organic polymers with rigid dispersed phases. AIChE J. 2004, 50:311-321.
33. Hatakeyama H., Hatakeyama T. Interaction between water and hydrophilic polymers. Thermochim. Acta 1998, 308:3-22.
34. Kim S.J., Park S.J., Kim S.I. Swelling behavior of interpenetrating polymer network hydrogels composed of poly(vinyl alcohol) and chitosan. React. Funct. Polym. 2003, 55:53-59.
35. Ping Z.H., Nguyen Q.T., Chen S.M., Zhou J.Q., Ding Y.D. States of water in different hydrophilic polymers-DSC and FTIR studies. Polymer 2001, 42:8461-8467.
36. Li W., Xue F., Cheng R. States of water in partially swollen poly(vinyl alcohol) hydrogels. Polymer 2005, 46:12026-12031.
37. Adoor S.G., Prathab B., Manjeshwar L.S., Aminabhavi T.M. Mixed matrix membranes of sodium alginate and poly(vinyl alcohol) for pervaporation dehydration of isopropanol at different temperatures. Polymer 2007, 48:5417-5430.
38. Stephen R., Ranganathaiah C., Varghese S., Joseph K., Thomas S. Gas transport through nano and micro composites of natural rubber (NR) and their blends with carboxylated styrene butadiene rubber (XSBR) latex membranes. Polymer 2006, 47:858-870.
39. Kariduraganavar M.Y., Kittur A.A., Kulkarni S.S., Ramesh K. Development of novel pervaporation membranes for the separation of water-isopropanol mixtures using sodium alginate and NaY zeolite. J. Membr. Sci. 2004, 238:165-175.
40. Kittur A.A., Kulkarni S.S., Aralaguppi M.I., Kariduraganavar M.Y. Preparation and characterization of novel pervaporation membranes for the separation of water-isopropanol mixtures using chitosan and NaY zeolite. J. Membr. Sci. 2005, 247:75-86.
41. Guan H.M., Chung T.S., Huang Z., Chng M.L., Kulprathipanja S. Poly(vinyl alcohol) multilayer mixed matrix membranes for the dehydration of ethanol-water mixture. J. Membr. Sci. 2006, 268:113-122.
42. Huang Z., Shi Y., Wen R., Guo Y.H., Su J.F., Matsuura T. Multilayer poly(vinyl alcohol)-zeolite 4A composite membranes for ethanol dehydration by means of pervaporation. Sep. Purif. Technol. 2006, 51:126-136.
43. Veerapur R.S., Patil M.B., Gudasi K.B., Aminabhavi T.M. Poly(vinyl alcohol)-zeolite T mixed matrix composite membranes for pervaporation separation of water+1,4-dioxane mixtures. Sep. Purif. Technol. 2008, 58:377-385.