Effect of fabrication and process parameters on the morphology and performance of a PAN-based zeolite-filled pervaporation membrane

Journal of Membrane Science

Volumn 223, Issue 1-2, 2003, Pages 23-38

  Okumus E ^a   Gurkan T ^b   Yilmaz, L ^b  

^a ONDOKUZ MAYIS UNIVERSITY   (Turkey)

^b MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

Ethanol water separation; Layered morphology; PAN membrane; Pervaporation; Zeolite filled membranes

Indexed keywords

BINARY MIXTURES; FLUXES; MORPHOLOGY; PERVAPORATION; ZEOLITES;

FEED COMPOSITION;

POLYMERIC MEMBRANES;

ALCOHOL; POLYACRYLONITRILE; POLYMER; SOLVENT; WATER; ZEOLITE;

ETHANOL; LIQUID-LIQUID SEPARATION; MEMBRANE STRUCTURE; PERVAPORATION; POLYACRYLONITRILE; WATER; ZEOLITE;

ARTICLE; DEHYDRATION; MEMBRANE; MORPHOLOGY; PERVAPORATION; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPY; SKIN; TEMPERATURE;

EID: 0141888205     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(03)00287-4     Document Type: Article

References (35)

1. Aptel P., Cuny J., Jozefowics J., Morel G., Neel J. Liquid transport through membranes prepared by grafting of polar monomers onto poly(tetra-fluoro-ethylene) films. 1. Some fractionations of liquid mixtures by pervaporation. J. Appl. Polym. Sci. 16:1972;1061.
2. Mulder M.H.V., Smolders C.A. On the separation of ethanol/water mixtures by pervaporation. I. Calculations of concentration profiles. J. Membr. Sci. 17:1984;289.
3. Hennepe H.J.C., Bargeman D., Mulder M.H.V., Smolders C.A. Zeolite-filled silicone rubber membranes. Part I. Membrane reparation and pervaporation results. J. Membr. Sci. 35:1987;39-55.
4. H.J.C. Hennepe, Zeolite-filled polymeric membranes, Ph.D. Thesis, University of Twente, The Netherlands, October 1988.
5. Goldman M., Frankel D., Levin G. A zeolite-polymer membrane for the separation of ethanol-water azeotrope. J. Appl. Polym. Sci. 37:1989;1791.
6. Jia M., Peinemann K.V., Behling R.D. Preparation and characterization of thin-film zeolite-PDMS composite membranes. J. Membr. Sci. 73:1992;119-128.
7. Y. Cen, R.N. Lichtenthaler, Pervaporation characteristics of zeolite-filled PDMS composite membranes, in: Proceedings of the Sixth International Conference on the Pervaporation Proceedings in Chemical Industry, Ottawa, Canada, 27-30 September 1992.
8. Okumuş E., Gürkan T., Yilmaz L. Development of a mixed-matrix membrane for pervaporation. Sep. Sci. Technol. 29:1994;2451-2473.
9. Duval J.M., Folkers B., Mulder M.H.V., Desgrandchamps G., Smolders C.A. Separation of a toluene-ethanol mixture by pervaporation using active carbon-filled polymeric membranes. Sep. Sci. Technol. 29:1994;357-373.
10. Ji W., Sindar S.K., Hwang S.T. Sorption, diffusion and permeation of 1,1,1-trichloroethane through adsorbent-filled polymeric membranes. J. Membr. Sci. 103:1995;243.
11. Gao Z., Yue Y., Li W. Application of zeolite-filled pervaporation membrane. Zeolites. 16:1996;70-74.
12. Ji W., Sindar S.K. Prevaporation using adsorbent-filled membranes. Ind. Eng. Chem. Res. 35:1996;1124-1132.
13. Semenova I.S., Ohya H., Soontarapa K. Hydrophilic membranes for pervaporation: an analytical review. Desalination. 110:1997;251-286.
14. Roda G.C. Performances of filled and unfilled PTMSP membranes in pervaporation. Chem. Eng. Commun. 163:1998;3-22.
15. Boom J.P., Pünt I.G.M., Zwijnenberg H., Boer R., Bargeman D., Smolders C.A., Strathmann H. Transport through zeolite filled polymeric membranes. J. Membr. Sci. 138:1998;237-258.
16. Lu S.Y., Chiu C.P., Huang H.Y. Pervaporation of acetic acid/water mixtures through silicalite filled polydimethylsiloxane membranes. J. Membr. Sci. 176:2000;159-167.
17. Huang J., Meagher M.M. Pervaporative recovery of n-butanol from aqueous solution and ABE fermentation broth using thin-film silicalite-filled silicone composite membranes. J. Membr. Sci. 192:2001;231-242.
18. Kang Y.S., Lee S.W., Kim U.Y., Shim J.S. Pervaporation of water-ethanol mixtures through crosslinked and surface-modified poly(vinylalcohol) membranes. J. Membr. Sci. 51:1990;215-226.
19. Hu C.M., Chiang W.Y. Separation of liquid mixtures by using polymer membranes. III. Water-alcohol separation by pervaporation through modified PAN membrane. J. Appl. Polym. Sci. 42:1991;1829-1833.
20. Nguyen Q.T., Blanc L.L., Neel J. Preparation of membranes from polyacrylonitrile-polyvinylpyrolidone blends and the study of their behaviour in the pervaporation of water-organic liquid mixtures. J. Membr. Sci. 22:1985;245-255.
21. Xu Y.F., Huang R.Y.M. Pervaporation separation of ethanol-water mixtures using ionically crosslinked blended polyacrylic acid (PAA)-Nylon-6 membranes. J. Appl. Polym. Sci. 36:1988;1121-1128.
22. Shieh J.J., Huang R.Y.M. Pervaporation with chitosan membranes. II. Blend membranes of chitosan and polyacrylicacid and comparison of homogeneous and composite membrane based on polyelectrolyte complexes of chitosan and polyacrylicacid for the separation of ethanol-water mixtures. J. Membr. Sci. 127:1997;185-202.
23. Vauclair C., Tarjus H., Schaetzel P. Permselective properties of PVA-PAA blended membrane used for dehydration of fusel oil by pervaporation. J. Membr. Sci. 125:1997;293-301.
24. Jiraratananon R., Chanachai A., Huang R.Y.M., Uttapap D. Pervaporation dehydrtion of ethanol-water mixtures with chitosan/hydroxyethylcellulose (CS/HEC) composite membranes. I. Effect of operating conditions. J. Membr. Sci. 195:2002;143-151.
25. Yoshikawa M., Wano T., Kitao T. Specialty polymeric membranes. Modified polybutadiene membranes for alcohol separation. J. Membr. Sci. 76:1993;255-259.
26. Ishihara K., Matsui K. Pervaporation of ethanol-water mixture through composite membranes composed of styrene-fluoroalkyl acrylate graft copolymers and cross-linked polydimethylsiloxane membrane. J. Appl. Polym. Sci. 34:1987;437-440.
27. Hu H.L., Lee K.R., Lail J.Y. Chematical-modified nylon 4 membrane for pervaporation. J. Macromol. Sci., Pure Appl. Chem. A30:1993;815-827.
28. Uragami T., Matsuda T., Okuno H., Miyata T. Structure of chemically modified chitosan membranes and their characteristic of permeation and separation of aqueous ethanol solutions. J. Membr. Sci. 88:1994;243-251.
29. Yamasaki A., Iwatsubo T., Masuoka T., Mizoguchi K. Pervaporation of asymmetric crosslinked PVA membranes. J. Appl. Polym. Sci. 58:1995;1657-1660.
30. J. Yu, C.H. Lee, W.H. Hong, Performances of crosslinked asymmetric poly(vinyl alcohol) membranes for isopropanol dehydration by pervaporation, Chem. Eng. Proc., in press.
31. Kusumocahyo S.P., Sano K., Sudoh M., Kensaka M. Water permselectivity in the pervaporation of acetic acid-water mixture using crosslinked poly(vinyl alcohol) membranes. Sep. Purif. Technol. 18:2000;141-150.
32. Chen H.L., Wu L.G., Tan J., Zhu C.L. PVA membrane filled B-cyclodextrin for separation of isomeric xylenes by pervaporation. Chem. Eng. J. 78:2000;159-164.
33. A. Shanley, Pervaporation finds its niche, Chem. Eng. Sep. (1994) 35-37.
34. Lee Y.M., Won K. Pervaporation separation of water-ethanol through modified PAN membranes. Polym. J. 22:1990;578-586.
35. Nguyen Q.T., Neel J., Clement R., Leblanc L. Fractionation of a binary-liquid mixture by continuous pervaporation. J. Membr. Sci. 15:1983;43-62.