Mechanistic and computational study of a palladacycle-catalyzed decomposition of a series of neutral phosphorothioate triesters in methanol

Journal of the American Chemical Society

Volumn 132, Issue 46, 2010, Pages 16599-16609

  Liu, C Tony ^a   Maxwell, Christopher I ^a   Edwards, David R ^a   Neverov, Alexei A ^a   Mosey, Nicholas J ^a   Brown, R Stan ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYZED REACTIONS; COMPLEX MECHANISMS; COMPUTATIONAL STUDIES; DFT CALCULATION; LEAVING GROUPS; METHANOL SOLUTION; PALLADACYCLES; PHOSPHORANES; PHOSPHOROTHIOATES; RATE-LIMITING STEPS; TRANSITION STATE; TRIESTERS; TRIFLATES; TRIMETHYL; TRIMETHYL PHOSPHATE;

BROMINE; CATALYSIS; METHANOL; PALLADIUM; PALLADIUM COMPOUNDS; PHENOLS; PYRIDINE; REACTION INTERMEDIATES; SOLVENTS; SUBSTRATES;

REACTION KINETICS;

COORDINATION COMPOUND; LEAD; METHANOL; PALLADIUM; PHENOL; PHOSPHORANE DERIVATIVE; PHOSPHOROTHIOIC ACID DERIVATIVE; PYRIDINE; PYRIDINE DERIVATIVE; SULFUR;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; DECOMPOSITION; METHANOLYSIS; PH; SOLVOLYSIS;

CATALYSIS; COMPUTER SIMULATION; ETHERS; METHANOL; MODELS, MOLECULAR; ORGANOTHIOPHOSPHORUS COMPOUNDS; PALLADIUM;

EID: 78649911497     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja107144c     Document Type: Article

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