Supercritical phase behavior for biotransformation processing

Journal of Supercritical Fluids

Volumn 55, Issue 2, 2010, Pages 635-642

  Brandenbusch, Christoph ^a   Sadowski, Gabriele ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

PC SAFT; Phase behavior; Solubilities; Supercritical carbon dioxide; Supercritical extraction; Whole cell biocatalysis

Indexed keywords

2-PHENYLETHANOL; BI-PHASIC; BIOTRANSFORMATION REACTIONS; DOWNSTREAM-PROCESSING; FLUID EXTRACTION; ORGANIC COMPONENTS; PC-SAFT; PC-SAFT EQUATION; PHTHALATES; STYRENE OXIDE; SUPER-CRITICAL; SUPERCRITICAL CARBON DIOXIDES; SUPERCRITICAL EXTRACTION; SUPERCRITICAL PHASE; WHOLE-CELL BIOCATALYSIS; WHOLE-CELL BIOTRANSFORMATIONS;

BIOCONVERSION; CARBON DIOXIDE; EQUATIONS OF STATE; ESTERS; ETHANOL; MATHEMATICAL MODELS; ORGANIC CARBON; PHASE BEHAVIOR; SOLUBILITY; STYRENE; TERNARY SYSTEMS;

SUPERCRITICAL FLUID EXTRACTION;

EID: 78649800888     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2010.10.025     Document Type: Article

References (32)

1. B. Bühler, and A. Schmid Process implementation aspects for biocatalytic hydrocarbon oxyfunctionalization J. Biotechnology 113 2004 183 210
2. B. Bühler, and A. Schmid Selective enzymatic hydroxylations G. Dyker, Handbook of C-H Transformations 2005 Wiley-VCH Weinheim 516 529
3. D.J. Leak, R.A. Sheldon, J.M. Woodley, and P. Adlercreutz Biocatalysts for selective introduction of oxygen Biocatalysis and Biotransformation 27 2009 1 26
4. A. Liese, K. Seelbach, and C. Wandrey Industrial Biotransformations 2006 Wiley-VCH Weinheim, Germany
5. C. Brandenbusch, B. Bühler, P. Hoffmann, G. Sadowski, and A. Schmid Efficient phase separation and product recovery in organic-aqueous bioprocessing using supercritical carbon dioxide Biotechnology and Bioengineering 107 2010 642 651
6. G. Sadowski, A. Schmid, B. Bühler, C. Brandenbusch, G. Goernert, TU Dortmund, Verfahren zur Aufarbeitung von koaleszenzgehemmten Emulsionen aus Ganzzell-Biotransformationen mit Kohlendioxid patent PCT/DE 2008/001177 (2007).
7. D. Kuhn, M.A. Kholiq, E. Heinzle, B. Buhler, and A. Schmid Intensification and economic and ecological assessment of a biocatalytic oxyfunctionalization process Green Chemistry 12 2010 815 827
8. J.D. van der Waals Over de Continuiteit van den Gas-en Vloeistoftoestand 1873 Sijthoff Leiden
9. D. Peng, and D.B. Robinson New two-constant equation of state Industrial and Engineering Chemistry Fundamentals 15 1976 59 64
10. G. Soave Equilibrium constants from a modified Redlich-Kwong equation of state Chemical Engineering Science 27 1972 1197 1203
11. F.J. Blas, and L.F. Vega Thermodynamic behaviour of homonuclear and heteronuclear Lennard-Jones chains with association sites from simulation and theory Molecular Physics 92 1997 135 150
12. W.G. Chapman, K.E. Gubbins, G. Jackson, and M. Radosz Saft - equation-of-state solution model for associating fluids Fluid Phase Equilibria 52 1989 31 38
13. A. GilVillegas, A. Galindo, P.J. Whitehead, S.J. Mills, G. Jackson, and A.N. Burgess Statistical associating fluid theory for chain molecules with attractive potentials of variable range J. Chemical Physics 106 1997 4168 4186
14. T. Hino, and J.M. Prausnitz A perturbed hard-sphere-chain equation of state for normal fluids and polymers using the square-well potential of variable width Fluid Phase Equilibria 138 1997 105 130
15. S.H. Huang, and M. Radosz Equation of state for small, large, polydisperse, and associating molecules Industrial and Engineering Chemistry Research 29 1990 2284 2294
16. Y.H. Song, S.M. Lambert, and J.M. Prausnitz A perturbed hard-sphere-chain equation of state for normal fluids and polymers Industrial and Engineering Chemistry Research 33 1994 1047 1057
17. J. Gross, and G. Sadowski Perturbed-chain SAFT: an equation of state based on a perturbation theory for chain molecules Industrial and Engineering Chemistry Research 40 2001 1244 1260
18. F. Becker, M. Buback, H. Latz, G. Sadowski, and F. Tumakaka Cloud-point curves of ethylene-(meth)acrylate copolymers in fluid ethene up to high pressures and temperatures - experimental study and PC-SAFT modeling Fluid Phase Equilibria 215 2004 263 282
19. M. Gornert, and G. Sadowski Phase-equilibrium measurement and modeling of the PMMA/MMA/carbon dioxide ternary system J. Supercritical Fluids 46 2008 218 225
20. J. Gross, O. Spuhl, F. Tumakaka, and G. Sadowski Modeling copolymer systems using the perturbed-chain SAFT equation of state Industrial and Engineering Chemistry Research 42 2003 1266 1274
21. M. Kleiner, F. Tumakaka, G. Sadowski, H. Latz, and M. Buback Phase equilibria in polydisperse and associating copolymer solutions: poly(ethene-co-(meth)acrylic acid)-monomer mixtures Fluid Phase Equilibria 241 2006 113 123
22. I. Stoychev, J. Galy, B. Fournel, P. Lacroix-Desmazes, M. Kleiner, and G. Sadowski Modeling the phase behavior of PEO-PPO-PEO surfactants in carbon dioxide using the PC-SAFT equation of state: application to dry decontamination of solid substrates J. Chemical and Engineering Data 54 2009 1551 1559
23. R. Span, and W. Wagner A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa J. Physical and Chemical Reference Data 25 1996 1509 1596
24. W.G. Chapman, G. Jackson, and K.E. Gubbins Phase-equilibria of associating fluids chain molecules with multiple bonding sites Molecular Physics 65 1988 1057 1079
25. W.G. Chapman, K.E. Gubbins, G. Jackson, and M. Radosz New reference equation of state for associating liquids Industrial and Engineering Chemistry Research 29 1990 1709 1721
26. P.K. Jog, S.G. Sauer, J. Blaesing, and W.G. Chapman Application of dipolar chain theory to the phase behavior of polar fluids and mixtures Industrial and Engineering Chemistry Research 40 2001 4641 4648
27. J. Gross An equation-of-state contribution for polar components: quadrupolar molecules AIChE Journal 51 2005 2556 2568
28. V.A. Durov, C. Puchala, and N.V. Lifanova The structure and dielectric-properties of aromatic alcohols - phenylmethanol, 2-phenylethanol Vestnik Moskovskogo Universiteta Seriya 2 Khimiya 23 1982 33 37
29. C.S. Tan, S.J. Yarn, and J.H. Hsu Vapor-liquid-equilibria for the systems carbon-dioxide ethylbenzene and carbon-dioxide styrene J. Chemical and Engineering Data 36 1991 23 25
30. W.L. Weng, and M.J. Lee Vapor-liquid-equilibrium of the octane/carbon dioxide, octane/ethane, and octane/ethylene systems J. Chemical and Engineering Data 37 1992 213 215
31. M. Kleiner, and G. Sadowski Modeling of polar systems using PCP-SAFT: an approach to account for induced-association interactions J. Physical Chemistry C 111 2007 15544 15553
32. M. Kleiner, F. Tumakaka, and G. Sadowski Thermodynamic modeling of complex systems X. Lu, Y. Hu, Molecular Thermodynamics of Complex Systems 2009 Springer Berlin 75 108