Ketene functionalized polyethylene: Control of cross-link density and material properties

Journal of the American Chemical Society

Volumn 132, Issue 42, 2010, Pages 14706-14709

  Leibfarth, Frank A ^a,b,c   Schneider, Yanika ^a,b,c   Lynd, Nathaniel A ^b   Schultz, Alison ^b   Moon, Bongjin ^c   Kramer, Edward J ^b   Bazan, Guillermo C ^a,b   Hawker, Craig J ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of California   (United States)

^c Sogang University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CO-MONOMER; COMONOMER INCORPORATION; CROSS-LINK DENSITIES; CROSS-LINKING DENSITY; CROSSLINKED POLYETHYLENE; FUNCTIONALIZATIONS; FUNCTIONALIZED; HIGH-MELTING; IN-SITU; MATERIAL PROPERTY; MELDRUM'S ACIDS; POLYETHYLENE PROCESSING; POST-POLYMERIZATION; RADICAL SOURCE; REACTIVE GROUP; SEMI-CRYSTALLINE POLYMER; SMALL MOLECULES;

ACIDS; FUNCTIONAL GROUPS; FUNCTIONAL POLYMERS; PROCESSING; THERMOPLASTICS;

POLYETHYLENES;

ACID; KETENE DERIVATIVE; NICKEL COMPLEX; NORBORNENE DERIVATIVE; POLYETHYLENE;

ARTICLE; CROSS LINKING; DENSITY; DIMERIZATION; FLOW KINETICS; POLYMERIZATION; SYNTHESIS; TENSILE STRENGTH;

EID: 78649745196     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1060643     Document Type: Article

References (33)

1. Boaen, N. K.; Hillmyer, M. A. Chan. Soc. Rev. 2005, 34, 267-275.
2. Atkinson, J. R.; Ciecek, R. Z. Biomaterials 1983, 4, 267-670.
3. Chodak, I. Prog. Patym. Sci. 1995, 20, 1165-1199.
4. Datta, S.; Lohse, D. J. Polymeric Compatibilizeis: Uses and Benefits in Polymer Blends; Carl Hanser Verlag: Munich, 1996.
5. (a) Rijke, A. M.; Mandelkern, L. Macromolecules 1971, 4, 594-599.
6. (b) Dole, M. J. Macromol. Sci., Part A: Pure Appl. Chem. 1981, 15, 1403-1409.
7. (a) Matsuo, M.; Sawatari, C. Macromolecules 1986, 19, 2028-2035.
8. (b) Matsuo, M.; Sawatari, C. Macromolecules 1987, 20, 1745-1747.
9. Leibfarth, F. A.; Kang, M.; Ham, M.; Kim, J.; Campos, L. M.; Gupta, N.; Moon, B.; Hawker, C. J. Nat. Chem. 2010, 2, 207-212.
10. Meldrum, A. N. J. Chem. Soc. 1908, 93, 598-601.
11. (a) Brown, R. F. C.; Eastwood, F. W.; Harrington, K. J. Aust. J. Chem. 1974, 27, 2373-2384.
12. (b) Hyatt, J. A.; Raynolds, P. W. Org. React. 1994, 45, 159-646.
13. (a) Boffa, L. S.; Novak, B. M. Chem. Rev. 2000, 100, 1479-1493.
14. (b) Domski, G. J.; Rose, J. M.; Coates, G. W.; Bolig, A. D.; Brookhart, M. Prog. Polym. Sci. 2007, 32, 30-92.
15. (c) Nakamura, A.; Ito, S.; Nozaki, K. Chem. Rev. 2009, 109, 5215-5244.
16. (d) Johnson, L. K.; Mecking, S.; Brookhart, M. J. Am. Chem. Soc. 1996, 118, 267-268.
17. (e) Mecking, S.; Johnson, L. K.; Wang, L.; Brookhart, M. J. Am. Chem. Soc. 1998, 120, 888-899.
18. (f) Younkin, T. R.; Connor, E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A. Science 2000, 287, 460-462.
19. Boardman, B. M.; Bazan, G. C. Acc. Chem. Res. 2009, 42, 1597-1606.
20. (a) Schneider, Y.; Azoulay, J. D.; Coffin, R. C.; Bazan, G. C. J. Am. Chem. Soc. 2008, 130, 10464-10465.
21. (b) Schneider, Y.; Lynd, N. A.; Kramer, E. J.; Bazan, G. C. Macromolecules 2009, 42, 8763-8768.
22. Zia-Ebrahimi, M.; Huffman, G. W. Synthesis 1996, 215-218.
23. Anbarasan, R.; Babot, O.; Maillard, B. J. Appl. Polym. Sci. 2004, 93, 75-81.
24. Hiemenz, P. C.; Lodge, T. P. Polymer Chemistry, 2nd ed.; Taylor & Francis Group: FL, 2007.
25. Munier, C. J. Mater. Sci. 2002, 37, 4159-4163.
26. The sample deemed to have 100% gel content was prepared by rigorous extraction with refluxing chlorobenzene of a material with 95% gel content.
27. Lazár, M.; Rado, R.; Rychlý, J. Adv. Polym. Sci. 1990, 95, 149-197.
28. Khonakdar, H. A.; Morshedian, J.; Wagenknecht, U.; Jafari, S. H. Polymer 2003, 44, 4301-4309.
29. (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. 1995, 34, 1143-1170.
30. (b) Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem. Rev. 2000, 100, 1169-1203.
31. (c) Schellekens, M.; Klumperman, B. J. Macromol. Sci., Polym. Rev. 2000, 40 (2), 167-192.
32. (d) Lin, W.; Shao, Z.; Dong, J.; Chung, T. C. M. Macromolecules 2009, 42, 3750-3754.
33. (e) Stehling, U. M.; Malmstrom, E. E.; Waymouth, R. M.; Hawker, C. J. Macromolecules 1998, 31, 4396-4398.