High-resolution 19F MAS NMR spectroscopy: Structural disorder and unusual J couplings in a fluorinated hydroxy-silicate

Journal of the American Chemical Society

Volumn 132, Issue 44, 2010, Pages 15651-15660

  Griffin, John M ^a   Yates, Jonathan R ^b   Berry, Andrew J ^c,d   Wimperis, Stephen ^e   Ashbrook, Sharon E ^a  

^a UNIVERSITY OF ST ANDREWS   (United Kingdom)

^b UNIVERSITY OF OXFORD   (United Kingdom)

^c IMPERIAL COLLEGE LONDON   (United Kingdom)

^d DEPARTMENT OF LIFE SCIENCES   (United Kingdom)

^e UNIVERSITY OF GLASGOW   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CLINOHUMITE; COVALENT BONDING; CRYSTALLINE SOLIDS; DENSITY FUNCTIONAL THEORY CALCULATIONS; DFT CALCULATION; DIPOLAR COUPLINGS; DOUBLE-QUANTUM; HIGH RESOLUTION; J COUPLING; MAGIC ANGLE SPINNING NMR; MAGNESIUM SILICATES; MAS NMR; MAS-NMR SPECTROSCOPY; NATURALLY OCCURRING; SPATIAL PROXIMITY; SPIN-SPIN INTERACTION; SPLITTINGS; STRUCTURAL DISORDERS; STRUCTURAL MODELS; THROUGH-BOND CONNECTIVITIES;

CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; DEUTERIUM; FLUORINE; MAGNESIUM; MODEL STRUCTURES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC POLYMERS; SILICATES; SULFUR COMPOUNDS;

COUPLINGS;

CLINOHUMITE; FLUORINE DERIVATIVE; HYDROXYSILICATE; MAGNESIUM; SILICATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; FLUORINATION; HIGH RESOLUTION F19 MAGIC ANGLE SPINNING NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLID STATE; STRUCTURE ANALYSIS; SUBSTITUTION REACTION;

EID: 78649724628     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105347q     Document Type: Article

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