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Volumn 48, Issue 11, 2010, Pages 1043-1065

Onsager reciprocity as a consequence of Maxwell reciprocity for "equidiffuse" fluids

Author keywords

Constitutive equations; Irreversible thermodynamics; Maxwell reciprocity; Molecular diffusion; Onsager reciprocity

Indexed keywords

COLEMAN; CONSTITUTIVE LAW; DIFFUSE TRANSPORT; DIFFUSION COEFFICIENTS; DILUTE GAS; EQUILIBRIUM THERMODYNAMICS; HOMOLOGOUS SERIES; IRREVERSIBLE THERMODYNAMICS; LIMITING CASE; MACROSCOPIC PHYSICS; MAXWELL RECIPROCITY; MOLECULAR DIFFUSION; MULTICOMPONENTS; NON EQUILIBRIUM THERMODYNAMICS; ONSAGER; ONSAGER RECIPROCITY; ONSAGER SYMMETRY; PHYSICAL LAWS; PHYSICAL TRANSPORT PHENOMENA; RECIPROCAL RELATIONS;

EID: 78649632921     PISSN: 00207225     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijengsci.2010.07.006     Document Type: Article
Times cited : (14)

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    • For example, a system of fixed composition is stable to thermal fluctuations when (∂ u ̂ / ∂T ) v ̂ ≡ c ̂ v > 0 and to pressure fluctuations when (∂ v ̂ / ∂p ) T < 0. These expressions involve only equilibrium properties. Comparable inequalities also exist governing stability to compositional fluctuations occurring in binary mixtures at constant pressure and temperature. These involve only derivatives of the respective species chemical potentials with respect to composition, again all equilibrium properties
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.