Generic Issues of Batch Dissolution Exemplified by Gypsum Rock

Aquatic Geochemistry

Volumn 17, Issue 1, 2011, Pages 21-50

  Truesdale, Victor W ^a  

^a OXFORD BROOKES UNIVERSITY   (United Kingdom)

Author keywords

Batch dissolution; Biogenic silica; Carbonate dissolution; Common ion; Dissolution kinetics; Geo engineering; Gypsum; Gypsum dissolution; Shrinking object; Shrinking sphere; Silica dissolution; Stirring rate; Transition State Theory

Indexed keywords

DISSOLUTION; FLUIDIZATION; GYPSUM; LAMINAR FLOW; REACTION KINETICS; SILICA; SURFACE AREA;

EID: 78649527882     PISSN: 13806165     EISSN: 15731421     Source Type: Journal    
DOI: 10.1007/s10498-010-9105-0     Document Type: Article

References (52)

1. Aagaard P, Helgeson HC (1982) Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. 1. Theoretical considerations. Am J Sci 282: 237-285.
2. Balbach S, Korn C (2004) Pharmaceutical evaluation of early development candidates-"the 100 mg-approach". Int J Pharm 275: 1-12.
3. Bard AJ (1965) Chemical equilibrium. Harper International, New York.
4. Barton AFM, Wilde NM (1971) Dissolution rates of polycrystalline samples of gypsum and orthorhombic forms of calcium sulphate by a rotating disc method. Trans Faraday Soc 67: 3590-3697.
5. Berner RA (1980) Early diagenesis: a theoretical approach. Princeton University Press, Princeton, pp 241.
6. Bunnett JF (1974) From kinetic data to reaction mechanism. In: Lewis ES (ed) Techniques of chemistry vol. VI: investigation of rates and mechanisms of reactions, (part 1). Wiley-Interscience, New York, pp 129-210.
7. Burch TE, Nagy KL, Lasaga AC (1993) Free energy dependence of albite dissolution kinetics at 80°C and pH 8. 8. Chem Geol 105: 137-162.
8. Busenberg E, Plummer LN (1986) A comparative study of the dissolution and crystal growth kinetics of calcite and aragonite. In: Mumpton FA (ed). Studies in diagenesis. US Geol Surv Bull, 1578, pp 139-169.
9. Chang R (1994) Chemistry, 5th edn. McGraw-Hill, New York.
10. Christoffersen J, Christoffersen MR (1976) The kinetics of dissolution of calcium sulphate dihydrate in water. J Cryt Growth 35: 79-88.
11. Colombani J (2008) Measurement of the pure dissolution rate constant of a mineral in water. Geochim Cosmochim Acta 72: 5634-5640.
12. Colombani J, Bert J (2007) Holographic interferometry study of the dissolution and diffusion of gypsum in water. Geochim Cosmochim Acta 71: 1913-1920.
13. Crow DR (1994) Principles and applications of electrochemistry. Chapman and Hall.
14. Dove PM, Han N, De Yoreo JJ (2005) Mechanisms of classical crystal growth theory explain quartz and silicate dissolution behavior. PNAS 102: 15357-15362.
15. Dreybrodt W, Gabrovsek F (2000) Comments on: mixed transport/reaction control of gypsum dissolution kinetics in aqueous solutions and initiation of gypsum karst In: Michael A. Raines, Thomas A. Dewers (eds) Chemical geology 140, 29-48, 1997. Chem Geol 168, pp 169-172.
16. Gobran GR, Miyamoto S (1985) Dissolution rate of gypsum in aqueous salt solutions. Soil Sci 140: 89-93.
17. Greenwood JE, Truesdale VW, Rendell AR (2001) Biogenic silica dissolution in seawater-in vitro chemical kinetics. Prog Oceanogr 48: 1-23.
18. Helgeson HC, Murphy WM, Aagaard P (1984) Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar. Geochim Cosmochim Acta 48: 2405-2432.
19. Holdren GR, Berner RA (1979) Mechanism of feldspar weathering-1. Experimental studies. Geochim Cosmochim Acta 43: 1161-1171.
20. Ichenhower JP, McGrail BP, Shaw WJ, Pierce EM, Nachimuthu P, Shuh DK, Rodriguez EA, Steele JL (2008) Experimentally determined dissolution kinetics of Na-rich borosilicate glass at far from equilibrium conditions: implications for transition state theory. Geochim Cosmochim Acta 72: 2767-2788.
21. Jeschke AA, Dreybrodt W (2002) Dissolution rates of minerals and their relation to surface morphology. Geochim Cosmochim Acta 66: 3055-3062.
22. Jeschke A, Vosbek K, Dreybrodt W (2001) Surface controlled dissolution rates of gypsum in aqueous solutions exhibit nonlinear dissolution kinetics. Geochim Cosmochim Acta 65: 27-34.
23. Kamatani A (1982) Dissolution rates of silica from diatoms decomposing at various temperatures. Mar Biol 68: 91-96.
24. Kamatani A, Riley JP, Skirrow GJ (1980) The dissolution of opaline silica of diatom tests in seawater. Oceanogr Soc Japan 36: 201-208.
25. Kuechler R, Noack K, Zorn T (2004) Investigation of gypsum dissolution under saturated and unsaturated water conditions. Biol Model 176: 1-14.
26. Lasaga AC (1981) Transition state theory. In: Lasaga AC, Kirkpatrick RJ (eds) Kinetics of geochemical processes. Reviews in mineralogy, vol 8. Minerological Society of America, Washington DC, pp 261-319.
27. Lebedev AL, Lekhov AV (1990) Dissolution kinetics of natural gypsum in water at 5-25°C. Geochem Int 27: 85-94.
28. Liu S-T, Nancollas GH (1971) The kinetics of dissolution of calcium sulfate dihydrate. J Inorg Nucl Chem 33: 2311-2316.
29. Lovelock JE, Rapley CG (2007) Ocean pipes could help the Earth to cure itself. Nature 449: 403.
30. Lüttge A, Winkler U, Lasaga AC (2003) Interferometric study of the dolomite dissolution: a new conceptual model for mineral dissolution. Geochim Cosmochim Acta 67: 1099-1116.
31. Nagy KL, Lasaga AC (1992) Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: the dependence on solution saturation state. Geochim Cosmochim Acta 56: 3093-3111.
32. O'Connor TL, Greenberg SA (1958) The kinetics for solution of silica in aqueous solutions. J Phys Chem 63: 1195-1198.
33. Petrovich R (1981) Kinetic of dissolution of mechanically comminuted rock-forming oxides and silicates-II. Deformation and dissolution of oxides and silicates in the laboratory and at the earth's surface. Geochim Cosmochim Acta 45: 1675-1686.
34. Raines MA, Dewers TA (1997) Mixed transport/reaction control of gypsum dissolution kinetics in aqueous solutions and initiation of gypsum karst. Chem Geol 140: 29-48.
35. Rickert D, Schulter M, Wallmann K (2002) Dissolution kinetics of biogenic silica in aqueous solutions. Geochim Cosmochim Acta 66: 439-455.
36. Schott J, Berner RA, Sjöberg EL (1981) Mechanism of pyroxene and amphibole weathering-I. Experimental studies of iron-free minerals. Geochim Cosmochim Acta 45: 2123-2135.
37. Sjöberg EL, Rickard D (1983) The influence of experimental design on the rate of calcite dissolution. Geochim Cosmochim Acta 47: 2281-2285.
38. Sohn HY, Wadsworth ME (1979) Rate processes in extractive metallurgy. Plenum, New York. ISBN 0 306 31102-X.
39. 2-water systems approaching calcite equilibrium. Chem Geol 100: 129-145.
40. 4). Geochim Cosmochim Acta 50: 379-392.
41. Trégur P, Kamatani A, Gueneley S, Quéguiner B (1989) Kinetics of dissolution of Antarctic diatom frustules and the biogeochemical cycle of silicon in the ocean. Polar Biol 9: 397-403.
42. Truesdale VW (2007) Batch dissolution kinetics: the shrinking sphere model with salts and its potential application to biogenic silica. Aquat Geochem 13: 267-287. doi: 10. 1007/s10498-007-9020-1.
43. Truesdale VW (2008) Shrinking sphere kinetics for batch dissolution of mixed particles of a single substance at high under-saturation-validation with sodium chloride, but with biogenic silica in mind. Aquat Geochem 14: 359-379. doi: 10. 1007/s10498-008-9041-4.
44. Truesdale VW (2009) Sucrose dissolution studies leading to a generic shrinking object model for batch dissolution of regular-shaped particles. Aquat Geochem 15: 421-442. doi: 10. 1007/s10498-008-9059-7.
45. Truesdale VW (2010) Silica gel as a surrogate for biogenic silica in batch dissolution experiments at pH 9. 2: further testing of the shrinking object model and a novel approach to the dissolution of a population of particles. Aquat Geochem 16: 101-126. doi: 10. 1007/s10498-009-9072-5.
46. Truesdale VW, Greenwood JE, Rendell AR (2005a) The rate-equation for biogenic silica dissolution in seawater-New hypotheses. Aquat Geochem 11: 319-343. doi: 10. 1007/s10498-004-7921-9.
47. Truesdale VW, Greenwood JE, Rendell AR (2005b) In vitro, batch-dissolution of biogenic silica in seawater-the application of recent modelling to real data. Progr Oceanogr 66: 1-24. doi: 10. 1016/j. pocean. 2005. 02. 019.
48. van Cappellen P, Qiu L (1997) Biogenic silica dissolution in sediments of the Southern Ocean. II. Kinetics. Deep-Sea Res II 44: 1129-1149.
49. Weast RC (1976) Handbook of chemistry and physics, 57th edn. CRC Press, Cleveland.
50. Wolff-Boenisch D, Gislason SR, Oelkers EH, Putnis CV (2004) The dissolution rates of natural glasses as a function of their composition at pH 4 and 10. 6, and temperatures from 25 to 74°C. Geochim Cosmochim Acta 68: 4843-4858.
51. Yool A, Tyrell T (2003) Role of diatoms in regulating the ocean's silicon cycle. Global Biogeochem Cycles 17(4): 1103-1124.
52. Zhang L, Lüttge A (2009) Theoretical approach to evaluating plagioclase dissolution mechanisms. Geochim Cosmochim Acta 73: 2832-2849.