Circular dichroism, optical rotation and absolute configuration of 2-cyclohexenone-cis-diol type phenol metabolites: Redefining the role of substituents and 2-cyclohexenone conformation in electronic circular dichroism spectra

Organic and Biomolecular Chemistry

Volumn 8, Issue 24, 2010, Pages 5635-5645

  Kwit, Marcin ^a   Gawronski, Jacek ^a   Boyd, Derek R ^b   Sharma, Narain D ^b   Kaik, Magdalena ^b  

^a ADAM MICKIEWICZ UNIVERSITY   (Poland)

^b QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

2-CYCLOHEXENONES; ABSOLUTE CONFIGURATION; ALKYL DERIVATIVES; ALKYL SUBSTITUENT; C-C BONDS; CD SPECTRA; CIRCULAR DICHROISM; CIRCULAR DICHROISM SPECTRA; CIS-DIOL; COMPLEX NATURE; DOMINANT CONTRIBUTIONS; ELECTRONIC CIRCULAR DICHROISM; ENERGY TRANSITIONS; GENERALIZED MODELS; PLANARITY; RING CONFORMATIONS; ROTATORY STRENGTH;

ALDEHYDES; ALKYLATION; CHROMOPHORES; KETONES; METABOLISM; METABOLITES; MODEL STRUCTURES; OPTICAL CORRELATION; OPTICAL ROTATION; PHENOLS; ROTATION;

DICHROISM;

2 CYCLOHEXENONE; 2-CYCLOHEXEN-1-ONE; CYCLOHEXANONE DERIVATIVE; PHENOL;

ARTICLE; CHEMISTRY; CIRCULAR DICHROISM; CONFORMATION; STEREOISOMERISM;

CIRCULAR DICHROISM; CYCLOHEXANONES; MOLECULAR CONFORMATION; PHENOL; STEREOISOMERISM;

EID: 78649527017     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/c0ob00422g     Document Type: Article

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