Influence of polar solvents upon the complex formation of 18-crown-6 with cations in chloroform

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Volumn 68, Issue 3-4, 2010, Pages 411-416

  Mutihac, Radu Cristian ^a   Buschmann, Hans Jürgen ^a   Schollmeyer, Eckhard ^a  

^a DEUTSCHES TEXTILFORSCHUNGSZENTRUM NORD WEST E V   (Germany)

Author keywords

Cations; Chloroform; Complex formation; Crown ethers; Polar solvents

Indexed keywords

EID: 78649331452     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10847-010-9800-x     Document Type: Article

References (32)

1. Lehn, J. M.: Supramolecular Chemistry, Concepts and Perspectives. VCH, Weinheim (1995).
2. Schneider, H. J., Yatsimirsky, A.: Principles and Methods in Supramolecular Chemistry. Wiley, Chichester (2000).
3. Schneider, H. J.: Binding mechanisms in supramolecular complexes. Angew. Chem. Int. Ed. 48, 3924-3977 (2009). doi: 10. 1002/anie. 200802947.
4. Izatt, R. M., Pawlak, K., Bradshaw, J. S., Bruening, R. L.: Thermodynamic and kinetic data for macrocyclic interaction with cations, anions, and neutral molecules. Chem. Rev. 95, 2529-2586 (1995). doi: 10. 1021/cr00039a010.
5. Mossier-Boss, P. A., Popov, A. I.: NMR and infrared studies of the complexation reaction of 18-crown-6 with some organic solvents. J. Am. Chem. Soc. 107, 6168-6174 (1985). doi: 10. 1021/ja00308a004.
6. Kusaka, R., Inokuchi, Y., Ebata, T.: Structure of hydrated clusters of dibenzo-18-crown-6-ether in a supersonic jet-encapsulation of water molecules in the crown cavity. Phys. Chem. Chem. Phys. 10, 6238-6244 (2008). doi: 10. 1039/b807113f.
7. Reichardt, C.: Solvents and Solvent Effects in Organic Chemistry. Wiley-VCH, Weinheim (2002).
8. n, n = 1, 2. J. Phys. Chem. A 113, 8067-8079 (2009). doi: 10. 1021/jp904233y.
9. Buschmann, H. J., Schollmeyer, E., Wenz, G., Mutihac, L.: Solvent influence upon complex formation between crown ethers and unprotonated amines. Thermochim. Acta 261, 1-5 (1995). doi: 10. 1016/0040-6031(95)02384-E.
10. Buschmann, H. J., Mutihac, L.: Complexation, solvent extraction, and transport through liquid membrane of protonated peptides using crown ethers. Anal. Chim. Acta 466, 101-108 (2002). doi: 10. 1016/S0003-2670(02)00513-5.
11. Voth, G. A.: Computer simulation of proton solvation and transport in aqueous and biomolecular systems. Acc. Chem. Res. 39, 143-150 (2006). doi: 10. 1021/ar0402098.
12. Rose, D., Benjamin, I.: Free energy of transfer of hydrated ion clusters from water to an immiscible organic solvent. J. Phys. Chem. B. 113, 9296-9303 (2009). doi: 10. 1021/jp904470d.
13. Ball, P.: Water as an active constituent in cell biology. Chem. Rev. 108, 74-108 (2008). doi: 10. 1021/cr068037a.
14. Buschmann, H. J., Wenz, G., Schollmeyer, E., Mutihac, L.: The influence of water molecules on the complex formation between K+ and 18-crown-6 and the cryptand (222) in chloroform. Inorg. Chem. Commun. 4, 211-214 (2001). doi: 10. 1016/S1387-7003(01)00175-7.
15. Schneider, H.: Ion solvation in mixed solvents. Top. Curr. Chem. 68, 103-148 (1976). doi: 10. 1007/BFb0048533.
16. Wipff, G.: Computational Approaches in Supramolecular Chemistry. Kluwer, Dordrecht, The Netherlands (1994).
17. Sieffert, N., Chaumont, A., Wipff, G.: Importance of the liquid-liquid interface in assisted ion extraction: new molecular dynamics studies of cesium picrate extraction by a calix[4]arene. J. Phys. Chem. C 113, 10610-10622 (2009). doi: 10. 1021/jp900789v.
18. Cramer, C. J.: Essentials of Computational Chemistry: Theories and Models. Wiley, New York (2004).
19. Benjamin, I.: Mechanism and dynamics of ion transfer across a liquid-liquid interface. Science 261, 1558-1560 (1993). doi: 10. 1126/science. 261. 5128. 1558.
20. + in water-methanol mixtures at 298. 15 K. J. Solution Chem. On-line, doi: 10. 1007/s10953-009-9473-5.
21. Buschmann, H. J., Mutihac, R. C., Schollmeyer, E.: Complex formation of 18-crown-6 with metal cations and ammonium ions in dioxane-water mixtures. Thermochim. Acta. 472, 17-19 (2008). doi: 10. 1016/j. tca. 2008. 03. 010.
22. Buschmann, H.-J., Mutihac, R.-C., Schollmeyer, E.: Interactions between crown ethers and water, methanol, acetone, and acetonitrile in halogenated solvents. J. Solution Chem. 39, 291-299 (2010). doi: 10. 1007/s10953-010-9499-8.
23. Buschmann, H. J., Mutihac, R. C., Schollmeyer, E.: Complex formation of crown ethers and cryptands with alkali metal and ammonium ion in chloroform. J. Solution Chem. 38, 209-217 (2009). doi: 10. 1007/s10953-008-9358-z.
24. Moore, R. V.: Dibenzylammonium and sodium dibenzyldithiocarbamates as precipitants for preconcentration of trace elements in water for analysis by energy dispersive X-ray fluorescence. Anal. Chem. 54, 895-897 (1982). doi: 10. 1021/ac00243a013.
25. Christensen, J. J., Ruckman, J., Eatough, D. J., Izatt, R. M.: Determination of equilibrium constants by titration calorimetry. Part 1. Introduction to titration calorimetry. Thermochim. Acta 3, 203-218 (1972). doi: 10. 1016/0040-6031(72)85030-5.
26. Eatough, D. J., Christensen, J. J., Izatt, R. M.: Determination of equilibrium constants by titration calorimetry. Part II. Data reduction and calculation techniques. Thermochim. Acta 3, 219-232 (1972). doi: 10. 1016/0040-6031(72)85031-7.
27. Eatough, D. J., Izatt, R. M., Christensen, J. J.: Determination of equilibrium constants by titration calorimetry. Part III. Application of method to several chemical systems. Thermochim. Acta 3, 233-246 (1972). doi: 10. 1016/0040-6031(72)85032-9.
28. Buschmann, H. J., Schollmeyer, E.: A test reaction from macrocyclic chemistry for calorimetric titrations. Thermochim. Acta 333, 49-53 (1999). doi: 10. 1016/S0040-6031(99)00096-9.
29. Buschmann, H. J., Schollmeyer, E., Mutihac, L.: The complexation of the ammonium ion by 18-crown-6 in different solvents and by noncyclic ligands, crown ethers and cryptands in methanol. Supramol. Sci. 5, 139-142 (1998). doi: 10. 1016/S0968-5677(98)80005-9.
30. Kebarle, P.: Ion thermochemistry and solvation from gas phase ion equilibria. Ann. Rev. Phys. Chem. 28, 445-479 (1977). doi: 10. 1146/annurev. pc. 28. 100177. 002305.
31. Marcus, Y.: Ion Solvation. J. Wiley, Chichester (1985).
32. Shannon, R. D.: Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A 32, 751-767 (1976). doi: 10. 1107/S0567739476001551.