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Volumn 29, Issue 22, 2010, Pages 5751-5753

Unexpected synthesis of tetrahedral Fe/S clusters via highly reactive butterfly intermediates (μ-HS)2Fe2(CO) 5[RP(CH2OH)2]

Author keywords

[No Author keywords available]

Indexed keywords

IN-SITU REACTIONS; ISOLATION AND CHARACTERIZATION; MODEL COMPLEXES; TETRAHEDRAL COMPLEXES;

EID: 78649301343     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100793d     Document Type: Article
Times cited : (24)

References (23)
  • 4
    • 67649283572 scopus 로고    scopus 로고
    • For reviews, see for example
    • For reviews, see for example: Tard, C.; Pickett, C. J. Chem. Rev. 2009, 109, 2245
    • (2009) Chem. Rev. , vol.109 , pp. 2245
    • Tard, C.1    Pickett, C.J.2
  • 12
    • 78649263452 scopus 로고    scopus 로고
    • note
    • 2] (0.438 g, 1.5 mmol) for preparation of 4b was added. The new mixture was allowed to warm to room temperature and stirred at this temperature for 12 h. Solvent was removed in vacuo, and the residue was subjected to open-air TLC separation using petroleum ether/AcOEt (for preparation of 4a, v/v = 3:2; for preparation of 4b, v/v = 2:1) as eluent. From the main orange-red band, 4a (0.230 g, 32%) or 4b (0.375 g, 41%) was obtained as a red solid.
  • 13
    • 78649277033 scopus 로고    scopus 로고
    • note
    • 4), 210.0, 214.9, 215.0 (C=O) ppm.
  • 17
    • 78649309530 scopus 로고    scopus 로고
    • note
    • 5), 209.6, 213.6, 213.7 (C=O) ppm.
  • 20
    • 78649293680 scopus 로고    scopus 로고
    • note
    • 5), 209.7, 212.8, 212.9 (C=O) ppm.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.