Estimate of mole sulfate ratios in magmatic rocks

Geochemical Journal

Volumn 43, Issue 5, 2009, Pages 371-377

  Yang, Xue Ming ^a,b   Lentz, David R ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

^b VALE S A   (Brazil)

Author keywords

Magmatic rocks; Mole sulfate ratio; Redox; Sulfur speciation; Sulfur isotopes

Indexed keywords

ESTIMATION METHOD; IGNEOUS GEOCHEMISTRY; IGNEOUS ROCK; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION; MAGMA; MINERAL DEPOSIT; NUMERICAL METHOD; REDOX CONDITIONS; SULFATE; SULFUR ISOTOPE;

EID: 78449303240     PISSN: 00167002     EISSN: None     Source Type: Journal    
DOI: 10.2343/geochemj.1.0033     Document Type: Article

References (42)

1. Alt, J. C, Shanks, W. C, III and Jackson, M. C. (1993) Cycling of sulfur in subduction zones: the geochemistry of sulfur in the Mariana Island Arc and back-arc trough. Earth Planet. Sci. Lett. 119, 477-494. (Pubitemid 24421104)
2. Bendall, C., Lahaye, Y., Fiebig, J., Weyer, S. and Brey, G. P. (2006) In situ sulfur isotope analysis by laser ablation MC-ICPMS. Appl. Geochem. 21, 782-787.
3. Borrok, D., Kesler, S. E. and Vogel, T. A. (1999) Sulfide minerals in intrusive and volcanic rocks of the Bingham-Park City belt, Utah. Econ. Geol. 94, 1213-1230. (Pubitemid 30203374)
4. Carroll, M. R. and Webster, J. D. (1994) Solubilities of sulfur, noble gases, nitrogen, chlorine, and fluorine in magmas. Rev. Mineral. 30, 231-279.
5. Chaussidon, M., Albarkde, F. and Sheppard, S. M. F. (1989) Sulphur isotope variations in the mantle from ion microprobe analyses of micro-sulphide inclusions. Earth Planet. Sci. Lett. 92, 144-156.
6. Clemente, B., Scaillet, B. and Pichavant, M. (2004) The solubility of sulphur in hydrous rhyolitic melts. J. Petrol. 45, 2171-2196. (Pubitemid 39500292)
7. de Hoog, J. C. M., Taylor, B. E. and van Bergen, M. J. (2001) Sulfur isotope systematics of basaltic lavas from Indonesia: implications for the sulfur cycle in subduction zones. Earth Planet. Sci. Lett. 189, 237-252. (Pubitemid 32710508)
8. Field, C. W. and Gustafson, L. B. (1976) Sulfur isotopes in the porphyry deposits at El Salvador, Chile. Econ. Geol. 71, 1533-1548.
9. Field, C. W., Zhang, L., Dilles, J. H., Rye, R. O. and Reed, M. H. (2005) Sulfur and oxygen isotopic record in sulfate and sulfide minerals of early, deep, pre-Main Stage porphyry Cu-Mo and late Main Stage base-metal mineral deposits, Butte district, Montana. Chem. Geol. 215, 61-93. (Pubitemid 40301075)
10. Halter, W. E., Pettke, T. and Heinrich, C. A. (2004) Laserablation ICP-MS analysis of silicate and sulfide melt inclusions in an andesitic complex I: analytical approach and data evaluation. Contrib. Mineral. Petrol. 147, 385-396. (Pubitemid 38884138)
11. Halter, W. E., Heinrich, C. A. and Pettke, T. (2005) Magma evolution and formation of porphyry Cu-Au ore fluids: evidence from silicate and sulfide melt inclusions. Mineral. Deposita 39, 845-863. (Pubitemid 40393658)
12. Hattori, K. H., Arai, S. and Clarke, D. R. (2002) Selenium, tellurium, arsenic and antimony contents of primary mantle sulfides. Can. Mineral. 40, 637-650. (Pubitemid 34788982)
13. Hoefs, J. (1987) Stable Isotope Geochemistry. 3rd ed., Springer-Verlag, Berlin, 241 pp.
14. Huebner, J. S. and Sato, M. (1970) The oxygen fugacity-temperature relationships of manganese oxide and nickel oxide buffers. Am. Mineral. 55, 934-952.
15. Ishihara, S. and Sasaki, A. (1989) Sulfur isotopic ratios of the magnetite-series and ilmenite-series granitoids of the Sierra Nevada batholith-a reconnaissance study. Geology 17, 788-791.
16. Keith, J. D., Whitney, J. A., Hattori, K., Ballantyne, G. H., Christiansen, E. H., Barr D. L., Cannan, T. M. and Hook, C. J. (1997) The role of magmatic sulfides and mafic alkaline magmas in the Bingham and Tintic mining districts, Utah. J. Petrol. 38, 1679-1690.
17. Kiba, T., Takagi, T., Yoshimura, T. and Kishi, T. (1955) Tin(II)-strong phosphoric acid: a new reagent for the determination of sulfate by reduction to hydrogen sulfide. Bull. Chem. Soc. Japan 28, 641-644.
18. Larocque, A. C. L., Stimac, J. A., Keith, J. D. and Huminicki, M. A. E. (2000) Evidence for open-system behavior in immiscible Fe-S-O liquids in silicate magmas: implications for contributions of metals and sulfur to ore-forming fluids. Can. Mineral. 38, 1233-1249. (Pubitemid 32161215)
19. Li, Y. and Liu, J. (2006) Calculation of sulfur isotope fractionation in sulfides. Geochim. Cosmochim. Acta 70, 1789-1795.
20. Luhr, J. F. and Logan, M. A. (2002) Sulfur isotope systematics of the 1982 El Chichón trachyandesite: An ion microprobe study. Geochim. Cosmochim. Acta 66, 3303-3316. (Pubitemid 35197708)
21. Mandeville, C. W., Sasaki, A., Saito, A., Faure, K., King, R. and Hauri, E. (1998) Open-system degassing of sulfur from Krakatau 1883 magma. Earth Planet. Sci. Lett. 160, 709-722. (Pubitemid 29105731)
22. Marini, L., Paiotti, A., Principe, C., Ferrara, G. and Cioni, R. (1994) Isotopic ratio and concentration of sulfur in the undersaturated alkaline magmas of Vulture Volcano (Italy). Bull. Volcanol. 56, 487-492.
23. Marini, L., Chiappini, V., Cioni, R., Cortecci, G., Dinelli, E., Principe, C. and Ferrara, G. (1998) Effect of degassing on sulfur contents and δ34S values in Somma-Vesuvius magmas. Bull. Volcanol. 60, 187-194. (Pubitemid 29107768)
24. Mavrogenes, J. A. and O'Neil, H. St. C. (1999) The relative effects of pressure, temperature and oxygen fugacity on the solubility of sulfide in mafic magmas. Geochim. Cosmochim. Acta 63, 1173-1180. (Pubitemid 29485374)
25. Miyoshi, T., Sakai, H. and Chiba, H. (1984) Experimental study of sulfur isotope fractionation factors between sulfate and sulfide in high temperature melts. Geochem. J. 18, 75-84.
26. Ohmoto, H. and Goldhaber, M. B. (1997) Sulfur and carbon isotopes. Geochemistry of Hydrothermal Ore Deposits (Barnes, H. L., ed.), 3rd ed., 517-611, John Wiley & Sons Inc., New York.
27. Ohmoto, H. and Rye, R. O. (1979) Isotopes of sulfur and carbon. Geochemistry of Hydrothermal Ore Deposits (Barnes, H. L., ed.), 2nd ed., 509-567, John Wiley & Sons Inc., New York.
28. Poulson, S. R. and Ohmoto, H. (1990) An evaluation of the solubility of sulfide sulfur in silicate melts from experimental data and natural samples. Chem. Geol. 85, 57-75.
29. Poulson, S. R., Kubilius, W. P. and Ohmoto, H. (1991) Geochemical behavior of sulfur in granitoids during intrusion of the South Mountain Batholith, Nova Scotia, Canada: Geochim. Cosmochim. Acta 55, 3809-3830.
30. Ripley, E. M. and Li, C. (2003) Sulfur isotope exchange and metal enrichment in the formation magmatic Cu-Ni-(PGE) deposits. Econ. Geol. 98, 635-641. (Pubitemid 37172263)
31. Rollinson, H. R. (1993) Using Geochemical Data: Evaluation, Presentation, Interpretation. Longman Scientific & Technical, London, 352 pp.
32. Rye, R. O., Luhr, J. F. and Wasserman, M. D. (1984) Sulfur and oxygen isotope systematics of the 1982 eruptions of El Chichón Volcano, Chiapas, México. J. Volcanol. Geoth. Res. 23, 109-123.
33. Sakai, H., Casadevall, T. J. and Moore, J. G. (1982) Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea Volcano, Hawaii. Geochim. Cosmochim. Acta 46, 729-738.
34. Sakai, H., Des Marais D. J., Ueda, A. and Moore, J. G. (1984) Concentrations and isotope ratios of carbon, nitrogen, and sulfur in ocean-floor basalts. Geochim. Cosmochim. Acta 48, 2433-2441.
35. Sasaki, A., Arikawa, Y. and Folinsbee, R. E. (1979) Kiba reagent method of sulfur extraction applied to isotopic work. Bull. Geol. Surv. Japan 30, 241-245.
36. Tachibana, S. and Huss, G. R. (2005) Sulfur isotope composition of putative primary troilite in chondrules from Bishunpur and Semarkona. Geochim. Cosmochim. Acta 69, 3074-3097.
37. Taylor, B. E. (1986) Magmatic volatiles: isotopic variation of C, H, and S. Stable Isotopes in High Temperature Geological Processes (Valley, J. W., Taylor, H. P., Jr. and O'Neil, J. R., eds.), Rev. Mineral. 16, 185-225.
38. Ueda, A. and Sakai, H. (1984) Sulfur isotope study of Quaternary volcanic rocks from the Japanese Island Arc. Geochim. Cosmochim. Acta 48, 1837-1848.
39. Wallace, P. and Carmichael, I. S. E. (1992) Sulfur in basaltic magmas: Geochim. Cosmochim. Acta 56, 1863-1874.
40. Whitney, J. A. and Stormer, J. C., Jr. (1983) Igneous sulfides in the Fish Canyon tuff and the role of sulfur in calc-alkaline magmas. Geology 11, 99-102.
41. Yang, X. M., Lentz, D. R. and Sylvester, P. J. (2006) Gold contents of sulfide minerals in granitoids from southwestern New Brunswick, Canada. Mineral. Deposita 41, 369-386. (Pubitemid 43905709)
42. Zheng, Y.-F. (1990) The effect of Rayleigh degassing of magma on sulphur isotope composition: A quantitative evaluation. Terra Nova 2, 74-78.