Magma evolution and the formation of porphyry Cu-Au ore fluids: Evidence from silicate and sulfide melt inclusions

Mineralium Deposita

Volumn 39, Issue 8, 2005, Pages 845-863

  Halter, Werner E ^a   Heinrich, Christoph A ^a   Pettke, Thomas ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

Alumbrera; Andesite; Argentina; Copper; Fluid; Gold; Melt inclusions; Porphyry; Sulfide

Indexed keywords

COPPER; MELT INCLUSION; ORE DEPOSIT; PORPHYRY;

ARGENTINA; SOUTH AMERICA; WESTERN HEMISPHERE; WORLD;

EID: 15344339339     PISSN: 00264598     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00126-004-0457-5     Document Type: Article

References (73)

1. Allmendinger RW (1986) Tectonic development, southeastern border of the Puna plateau, Northwestern Argentine Andes. Geol Soc Am Bull 97:1070-1082
2. Audetat A, Gunther D, Heinrich CA (1998) Formation of a magmatic-hydrothermal ore deposit: Insights with LA-ICP-MS analysis of fluid inclusions. Science 279:2091-2094 10.1126/science.279.5359.2091
3. Audetat A, Pettke T, Dolejs D (2004) Magmatic anhydrite and calcite in the ore-forming quartz- monzodiorite magma at Santa Rita, New Mexico (USA): Genetic constraints on porphyry-Cu mineralization. Lithos 72:147-161 10.1016/j.lithos.2003.10.003
4. Bain N (2001) Petrological and geochemical contribution to the Faralĺn Negro Volcanic Complex, NW-Argentina. Diploma Thesis. Swiss Federal Institute of Technology, Zurich, 92 pp
5. Bassi HGL, Rochefort G (1980) Estudio geologico del yacimiento cuproaurifero de la Alumbrera. Servicio Minero Nacional, Buenos Aires
6. Becker K (2001) Sm-Nd and Rb-Sr isotope geochemistry on the magmatic source of the igneous rocks in the Farallón Negro Volcanic Complex, NW Argentina. Diploma Thesis. Swiss Federal Institute of Technology, Zurich, 103 pp
7. Bodnar RJ, Rapien RH, Simmons S, Szabo CS, Wood CP, Sutton SR (2002) Neo-natal porphyry copper system at White Island, New Zealand. Geochim Cosmochim Acta 66:A86-A86
8. Candela PA, Holland HD (1984) The partitioning of copper and molybdenum between silicate melts and aqueous fluids. Geochim Cosmochim Acta 48:373-380. 10.1016/0016-7037(84)90257-6
9. Carroll MR, Rutherford MJ (1985) Sulfide and sulfate saturation in hydrous silicate melts. J Geophys Res 90:C601-C612
10. Charlier BLA, Peate DW, Wilson CJN, Lowenstern JB, Storey M, Brown SJA (2003) Crystallisation ages in coeval silicic magma bodies: U-238-Th- 230 disequilibrium evidence from the Rotoiti and Earthquake Flat eruption deposits, Taupo Volcanic Zone, New Zealand. Earth Planet Sci Lett 206:441-457 10.1016/S0012-821X(02)01109-3
11. Coughlin TJ, O'Sullivan PB, Kohn BP, Holcombe RJ (1998) Apatite fission-track thermochronology of the Sierras Pampeanas, central western Argentina; implications for the mechanism of plateau uplift in the Andes. Geology (Boulder) 26:999-1002 10.1130/ 0091-7613(1998)026<0999:AFTTOT>2.3.CO;2
12. Dilles JH (1987) Petrology of the Yerington Batholith, Nevada - evidence for evolution of porphyry copper ore fluids. Econ Geol 82:1750-1789
13. Dungan MA, Wulff A, Thompson R (2001) Eruptive stratigraphy of the Tatara-San Pedro complex, 36°S, southern volcanic zone, Chilean Andes: Reconstruction method and implications for magma evolution at long-lived arc volcanic centers. J Petrol 42:555-626 10.1093/petrology/ 42.3.555
14. A Ewart 1982 The mineralogy and petrology of tertiary-recent orogenic volcanic rocks; with special reference to the andesitic-basaltic compositional range In: RS Thorpe (ed.) Andesites; orogenic andesites and related rocks Wiley Chichester 25-95
15. Guilbert JM (1995) Geology, alteration, mineralization, and genesis of the Bajo de la Alumbrera porphyry copper-gold deposit, Catamarca Province, Argentina. In: Pierce FW, Bolm JG (eds) Porphyry copper deposits of the American Cordillera: Arizona Geological Society Digest, vol 20. Arizona Geological Society, Tucson, pp 646-656
16. Gunther D, Audetat A, Frischknecht R, Heinrich CA (1998) Quantitative analysis of major, minor and trace elements in fluid inclusions using laser ablation inductively coupled plasma mass spectrometry. J Anal Atom Spectrom 13:263-270 10.1039/a707372k
17. Gustafson LB, Hunt JP (1975) The porphyry copper deposit at El Salvador, Chile. Econ Geol Bull Soc Econ Geol 70:857-912
18. Halter WE, Pettke T, Heinrich CA (2002a) The origin of Cu/Au ratios in porphyry-type ore deposits. Science 296:1844-1846 10.1126/science.1070139
19. Halter WE, Pettke T, Heinrich CA, Rothen-Rutishauser B (2002b) Major to trace element analysis of melt inclusions by laser-ablation ICP-MS: methods of quantification. Chem Geol 183:63-86 10.1016/ S0009-2541(01)00372-2
20. Halter WE, Bain N, Becker K, Heinrich CA, Landtwing M, VonQuadt A, Bissig T, Clark AH, Sasso AM, Tosdal RM (2004a) From andesitic volcanism to the formation of a porphyry-Cu-Au mineralizing magma chamber: The Farallón Negro Volcanic Complex, northwestern Argentina. J Volcanol Geotherm Res (in press)
21. Halter WE, Heinrich CA, Pettke T (2004b) Laser-ablation ICP-MS analysis of silicate and sulfide melt inclusions in an andesitic complex II: magmas genesis and implications for ore-formation. Contrib Mineral Petrol 147:397-412 10.1007/s00410-004-0563-5
22. Halter WE, Pettke T, Heinrich CA (2004c) Laser-ablation ICP-MS analysis of silicate and sulfide melt inclusions in an andesitic complex I: analytical approach and data evaluation. Contrib Mineral Petrol 147:385-396 10.1007/s00410-004-0562-6
23. Harris AC, Kamenetsky VS, White NC, van Achterbergh E, Ryan CG (2003) Melt inclusions in veins: Linking magmas and porphyry Cu deposits. Science 302:2109-2111 10.1126/science.1089927
24. Harris AC, Allen CM, Bryan SE, Campbell IH, Holcombe RJ, Palin JM (2004) ELA-ICP-MS U-Pb zircon geochronology of regional volcanism hosting the Bajo de la Alumbrera Cu-Au deposit: Implications for porphyry-related mineralization. Miner Deposita 39:46-67 10.1007/s00126-003-0381-0
25. Hattori K (1993) High-sulfur magma, a product of fluid discharge from underlying mafic magma - evidence from Mount-Pinatubo, Philippines. Geology 21:1083-1086 10.1130/ 0091-7613(1993)021<1083:HSMAPO>2.3.CO;2
26. Hattori K (1996) Occurrence and origin of sulfide and sulfate in the 1991 Mount Pinatubo eruption products. In: Newhall Christopher G, Punongbayan Raymundo S (eds) Fire and mud; eruptions and lahars of Mount Pinatubo, Philippines, Philippine Institute of Volcanology and Seismology. University of Washington Press, United States, Quezon City, Philippines, pp 807-824
27. Hedenquist JW, Simmons SF, Giggenbach WF, Eldridge CS (1993) White-Island, New-Zealand, volcanic-hydrothermal system represents the geochemical environment of high-sulfidation Cu and Au ore deposition. Geology 21:731-734 10.1130/0091-7613(1993)021<0731:WINZVH>2.3.CO;2
28. Heinrich CA, Ryan CG, Mernagh TP, Eadington PJ (1992) Segregation of ore metals between magmatic brine and vapor - a fluid inclusion study using pixe microanalysis. Econ Geol Bull Soc Econ Geol 87:1566-1583
29. Heinrich CA, Pettke T, Halter WE, Aigner-Torres M, Audetat A, Gunther D, Hattendorf B, Bleiner D, Guillong M, Horn I (2003) Quantitative multi-element analysis of minerals, fluid and melt inclusions by laser-ablation inductively-coupled-plasma mass-spectrometry. Geochim Cosmochim Acta 67:3473-3497 10.1016/S0016-7037(03)00084-X
30. Heinrich CA, Driesner T, Stefansson A, Seward TM (2004) Magmatic vapor contraction and the transport of gold from the porphyry environment to epithermal ore deposits. Geology 32:761-764
31. Hezarkhani A, Williams-Jones AE (1998) Controls of alteration and mineralization in the Sungun porphyry copper deposit, Iran: Evidence from fluid inclusions and stable isotopes. Econ Geol Bull Soc Econ Geol 93:651-670
32. Hezarkhani A, Williams-Jones AE, Gammons CH (1999) Factors controlling copper solubility and chalcopyrite deposition in the Sungun porphyry copper deposit, Iran. Miner Deposita 34:770-783
33. Housh TB, Luhr JF (1991) Plagioclase-melt equilibria in hydrous systems. Am Miner 76:477-492
34. Hunt JP (1991) Porphyry copper deposits: Historical perspectives of genetic concepts and case histories of famous discoveries: Economic Geology Monographs, vol 8. Economic Geology Publishing Co., Lancaster, pp 192-206
35. Johannes W (1989) Melting of plagioclase-quartz assemblages at 2-Kbar Water-pressure. Contrib Mineral Petrol 103:270-276 1:CAS:528:DyaK3cXjvF2mug%3D%3D
36. Jordan TE, Allmendinger RW (1986) The sierra pampeanas of Argentina: A moderne analogue of Rocky Mountain foreland deformation. Am J Sci 260:737-764
37. Jugo PJ, Candela PA, Piccoli PM (1999) Magmatic sulfides and Au:CU ratios in porphyry deposits: An experimental study of copper and gold partitioning at 850°C, 100 MPa in a haplogranitic melt pyrrhotite intermediate solid solution gold metal assemblage, at gas saturation. Lithos 46 573-589 10.1016/S0024-4937(98)00083-8
38. Keith JD, Whitney JA, Hattori K, Ballantyne GH, Christiansen EH, Barr DL, Cannan TM, Hook CJ (1997) The role of magmatic sulfides and mafic alkaline magmas in the Bingham and Tintic mining districts, Utah. J Petrol 38:1679-1690 10.1093/petrology/38.12.1679
39. Keppler H (1999) Experimental evidence for the source of excess sulfur in explosive volcanic eruptions. Science 284:1652-1654 10.1126/ science.284.5420.1652
40. Kesler SE, Chryssoulis SL, Simon G (2002) Gold in porphyry copper deposits: Its abundance and fate. Ore Geol Rev 21:103-124 10.1016/ S0169-1368(02)00084-7
41. Kress V (1997) Magma mixing as a source for Pinatubo sulphur. Nature 389:591-593
42. Landtwing M (2004) Fluid evolution and ore metal precipitation at the Bingham porphyry Cu-Au-Mo deposit, Utah, deduced from cathodoluminescence imaging and LA-ICPMS microanalysis of fluid inclusions. PhD Thesis, ETH Zurich, Zurich, 126 pp
43. Larocque ACL, Stimac JA, Keith JD, Huminicki MAE (2000) Evidence for open-system behavior in immiscible Fe-S-O liquids in silicate magmas: Implications for contributions of metals and sulfur to ore-forming fluids. Can Mineral 38:1233-1249
44. Llambías EJ (1970) Geologia de los yacimientos mineros Agua de Dionisio, Prov. de Catamarca, Rep. Argentina. Revista de la Asociacion Argentina de Mineralogia Petrologia y Sedimentologia 1:2-32
45. Llambías EJ (1972) Estructura del grupo volcanico Farallon Negro, Catamarca, Republica Argentina. Revista de la Asociacion Geologica Argentina 27:161-169
46. Lowell JD, Guilbert JM (1970) Lateral and vertical alteration-mineralization zoning in porphyry ore deposits. Econ Geol Bull Soc Econ Geol 65:373-408
47. Lowenstern JB (1993) Evidence for a copper-bearing fluid in magma erupted at the Valley of Ten-Thousand-Smokes, Alaska. Contrib Mineral Petrol 114:409-421 10.1007/BF00307869
48. Moore G, Carmichael ISE (1998) The hydrous phase equilibria (to 3 kbar) of an andesite and basaltic andesite from western Mexico: Constraints on water content and conditions of phenocryst growth. Contrib Mineral Petrol 130:304-319 10.1007/s004100050367
49. Oberli F, Meier M, Berger A, Rosenberg CL, Giere R (2004) U-Th-Pb and Th-230/U-238 disequilibrium isotope systematics: Precise accessory mineral chronology and melt evolution tracing in the Alpine Bergell intrusion. Geochim Cosmochim Acta 68:2543-2560 10.1016/j.gca.2003.10.017
50. O'Neill HSC, Mavrogenes JA (2002) The sulfide capacity and the sulfur content at sulfide saturation of silicate melts at 1400°C and 1 bar. J Petrol 43:1049-1087 10.1093/petrology/43.6.1049
51. Pallister JS, Hoblitt RP, Reyes AG (1992) A basalt trigger for the 1991 eruptions of Pinatubo Volcano. Nature 356:426-428 10.1038/356426a0
52. Parat F, Dungan MA, Streck MJ (2002) Anhydrite, pyrrhotite, and sulfur-rich apatite: Tracing the sulfur evolution of an Oligocene andesite (Eagle Mountain, CO, USA). Lithos 64:63-75 10.1016/ S0024-4937(02)00155-X
53. Pettke T, Halter WE, Webster JD, Aigner-Torres M, Heinrich CA (2004) Accurate quantification of melt inclusion chemistry by LA-ICPMS: A comparison with EMP and SIMS and advantages and possible limitations of these methods. Lithos 78:333-361
54. Proffett JM (2003) Geology of the Bajo de la Alumbrera porphyry copper-gold deposit, Argentina. Econ Geol Bull Soc Econ Geol 98: 1535-1574; 1534 sheets
55. PB Redmond MR Landtwing MT Einaudi 2001 Cycles of porphyry dike emplacement, veining, alteration and mineralisation in the Bingham porphyry Cu-Au-Mo deposit, Utah A Piestrzynski Mineral deposits at the beginning of the 21st century. Society for Geology Applied to Mineral Deposits (SGA) International Krakow
56. Sasso AM (1997) Geological evolution and metallogenetic relationships of the Farallon Negro volcanic complex, NW Argentina. PhD Thesis. Queen's University, 843 pp
57. Sasso AM, Clark AH (1998) The farallón negro group, northwest Argentina: Magmatic, hydrothermal and tectonic evolution and implications for Cu-Au metallogeny in the Andean back-arc. Soc Econ Geol Newslett 34:8-17
58. Sillitoe RH (1973) The tops and bottoms of porphyry copper deposits. Econ Geol Bull Soc Econ Geol 68:799-815
59. Sparks RSJ, Marshall LA (1986) Thermal and mechanical constraints on mixing between mafic and silicic magmas. J Volcanol Geotherm Res 29:99-124 10.1016/0377-0273(86)90041-7
60. Spooner ETC (1993) Magmatic sulfide volatile interaction as a mechanism for producing chalcophile element enriched, Archean Au-quartz, epithermal Au-Ag and Au skarn hydrothermal ore F fluids. Ore Geol Rev 7:359-379 10.1016/0169-1368(93)90001-F
61. Stefanini B, Williams-Jones AE (1996) Hydrothermal evolution in the Calabona porphyry copper system (Sardinia, Italy): The path to an uneconomic deposit. Econ Geol Bull Soc Econ Geol 91:774-791
62. Stults A (1985) Geology of the Bajo de la Alumbrera porphyry copper and gold prospect, Catamarca province, Argentina. Masters Thesis, University of Arizona, Tuscon, 75 pp
63. Sun WD, Arculus RJ, Kamenetsky VS, Binns RA (2004) Release of gold-bearing fluids in convergent margin magmas prompted by magnetite crystallization. Nature 431:975-978 10.1038/nature02972
64. Tomkins AG, Mavrogenes JA (2003) Generation of metal-rich felsic magmas during crustal anatexis. Geology 31:765-768 10.1130/G19499.1
65. Ulrich T (1999) Genesis of the Bajo de la Alumbrera porphyry Cu-Au deposit, Argentina: Geological, fluid geochemical, and isotopic implications. Doctoral Thesis, Swiss Federal Institute of Technology, Zurich, 207 pp
66. Ulrich T, Heinrich CA (2001) Geology and alteration geochemistry of the porphyry Cu-Au deposit at Bajo de la Alumbrera, Argentina, vol 96, p 1719, 2001, correctly printed in 2002. Econ Geol Bull Soc Econ Geol 97:1863-1888
67. Ulrich T, Gunther D, Heinrich CA (1999) Gold concentrations of magmatic brines and the metal budget of porphyry copper deposits. Nature 399:676-679 10.1038/21406
68. Ulrich T, Gunther D, Heinrich CA (2001) Evolution of a porphyry Cu-Au deposit, based on LA-ICP-MS analysis of fluid inclusions: Bajo de la Alumbrera, Argentina, vol 96, p 1743, 2001, correctly printed in 2002. Econ Geol Bull Soc Econ Geol 97:1888-1920
69. Urreiztieta M, Rosello EA, Gapais D, LeGorve C, Cobbold PR 1993. Neogene dextural transpression at the southern edge of the Altiplano-Puna (NW Argentina). In: IInd international symposium on andean tectonics, Oxford, pp 267-269
70. Wallace PJ, Gerlach TM (1994) Magmatic vapor source for sulfur-dioxide released during volcanic-eruptions - evidence from Mount-Pinatubo. Science 265:497-499
71. JL Walshe DR Cooke J Cannell P Frikken P Hollings G Masterman J Skarmeta F Camus PA Gow G Midgley 2003 Physicochemical gradients and architectural constraints on fluid-mixing models of porphyry Cu formation In: Eliopoulos DG (ed.) Mineral exploration and sustainable development Mill press Athens 419-422
72. Watson EB (1979) Zircon saturation in felsic liquids - experimental results and applications to trace-element geochemistry. Contrib Mineral Petrol 70:407-419 10.1007/BF00371047
73. Wolf KJ, Eichelberger JC (1997) Syneruptive mixing, degassing, and crystallization at Redoubt Volcano, eruption of December, 1989 to May 1990. J Volcanol Geotherm Res 75:19-37 10.1016/S0377-0273(96)00055-8