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Volumn 75, Issue 22, 2010, Pages 7636-7643

Reactivity and selectivity in hydrovinylation of strained alkenes

Author keywords

[No Author keywords available]

Indexed keywords

C-C BOND FORMING REACTION; HYDROVINYLATION; NORBORNENES; RING OPENING;

EID: 78449232660     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1015135     Document Type: Article
Times cited : (33)

References (74)
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    • Hata, G.1
  • 9
    • 61449195272 scopus 로고    scopus 로고
    • Use of Ni: Angew. Chem., Int. Ed. Engl. 1988, 27, 185
    • Moreau, B.; Wu, J. Y.; Ritter, T. Org. Lett. 2009, 11, 337 Use of Ni: Wilke, G. Angew. Chem., Int. Ed. Engl. 1988, 27, 185
    • (2009) Org. Lett. , vol.11 , pp. 337
    • Moreau, B.1    Wu, J.Y.2    Ritter, T.3    Wilke, G.4
  • 10
    • 0041378064 scopus 로고    scopus 로고
    • For more recent reports, see: Ru: Angew. Chem., Int. Ed. Engl. 2007, 46, 7544
    • RajanBabu, T. V. Chem. Rev. 2003, 103, 2845 For more recent reports, see: Ru: Goossen, L. J. Angew. Chem., Int. Ed. Engl. 2007, 46, 7544
    • (2003) Chem. Rev. , vol.103 , pp. 2845
    • Rajanbabu, T.V.1    Goossen, L.J.2
  • 24
    • 84981909682 scopus 로고
    • Nozaki's Cu-catalyzed cyclopropanation of styrene with ethyl diazoacetate is the only other example of an asymmetric C-C bond-forming reaction that preceeds this discovery.; Tetrahedron Lett. 1966, 5239
    • Bogdanović, B.; Henc, B.; Lösler, A.; Meister, B.; Pauling, H.; Wilke, G. Angew. Chem., Int. Ed. Engl. 1973, 12, 954 Nozaki's Cu-catalyzed cyclopropanation of styrene with ethyl diazoacetate is the only other example of an asymmetric C-C bond-forming reaction that preceeds this discovery. Nozaki, H.; Moriuti, S.; Takaya, H.; Noyori, R. Tetrahedron Lett. 1966, 5239
    • (1973) Angew. Chem., Int. Ed. Engl. , vol.12 , pp. 954
    • Bogdanović, B.1    Henc, B.2    Lösler, A.3    Meister, B.4    Pauling, H.5    Wilke, G.6    Nozaki, H.7    Moriuti, S.8    Takaya, H.9    Noyori, R.10
  • 29
    • 0001429223 scopus 로고
    • For other related metal-catalyzed C-C bond-forming reactions of norbornene, see: Hydrocyanation
    • For other related metal-catalyzed C-C bond-forming reactions of norbornene, see: Hydrocyanation: Hodgson, M.; Parker, D.; Taylor, R. J.; Ferguson, G. Organometallics 1988, 7, 1761
    • (1988) Organometallics , vol.7 , pp. 1761
    • Hodgson, M.1    Parker, D.2    Taylor, R.J.3    Ferguson, G.4
  • 33
  • 42
    • 84904447771 scopus 로고    scopus 로고
    • 2/ligand L2 /NaBARF (0.007 equiv catalyst) at room temperature in an atmosphere of ethylene gave >99% yield of 3-phenyl-1-butene with >99% selectivity for this isomer. Under these conditions most other ligands lead to extensive isomerization of the initial product into (Z)- and (E)-2-phenyl-2-butenes
    • 2/ligand L2 /NaBARF (0.007 equiv catalyst) at room temperature in an atmosphere of ethylene gave >99% yield of 3-phenyl-1-butene with >99% selectivity for this isomer. Under these conditions most other ligands lead to extensive isomerization of the initial product into (Z)- and (E)-2-phenyl-2-butenes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.