Synthesis and structure of technetium trichloride

Journal of the American Chemical Society

Volumn 132, Issue 45, 2010, Pages 15864-15865

  Poineau, Frederic ^a   Johnstone, Erik V ^a   Weck, Philippe F ^a   Kim, Eunja ^a   Forster, Paul M ^a   Scott, Brian L ^b   Sattelberger, Alfred P ^a,c   Czerwinski, Kenneth R ^a  

^a UNIVERSITY OF NEVADA   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

^c ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ISOSTRUCTURAL; MECHANISM OF FORMATION;

REACTION INTERMEDIATES; RHENIUM; SYNTHESIS (CHEMICAL);

TECHNETIUM;

RHENIUM; TECHNETIUM; TECHNETIUM TRICHLORIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; MEDICAL LITERATURE; MOLECULAR STABILITY; ROOM TEMPERATURE; SEPARATION TECHNIQUE; SYNTHESIS;

EID: 78449231609     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105730e     Document Type: Article

References (25)

1. Cotton, F. A., Wilkinson, G., Murillo, C. A., and Bochmann, M. Advanced Inorganic Chemistry, 6 th ed.; Wiley: New York, 1999.
2. Shaik, S. S. and Bar, R. Inorg. Chem. 1983, 22, 735-743
3. Corbett, J. D. Adv. Chem. Ser. 1984, 186, 329-347
4. von Schnering, H. G., Chang, J. H., Peters, K., Peters, E. M., Wagner, F. R., Grin, Y., and Thiele, G. Z. Anorg. Allg. Chem. 2003, 629, 516-522
5. Lin, J. and Miller, G. J. Inorg. Chem. 1993, 32, 1476-1487
6. Dilworth, J. R. and Parrott, S. J. Chem. Soc. Rev. 1998, 27, 43-55
7. Schwochau, K. Technetium: Chemistry and Radiopharmaceutical Applications; Wiley-VCH: Weinheim, Germany, 2000.
8. Poineau, F., Rodriguez, E. E., Forster, P. M., Sattelberger, A. P., Cheetham, A. K., and Czerwinski, K. R. J. Am. Chem. Soc. 2009, 131, 910-911
9. Rinke, K., Klein, M., and Schaefer, H. J. Less-Common Met. 1967, 12, 497-503
10. Walton, R. A. J. Cluster Sci. 2004, 15, 559-588
11. max = 292 keV). All manipulations were performed in a radiochemistry laboratory designed for chemical synthesis using efficient HEPA-filtered fume hoods and Schlenk and glovebox techniques, and locally approved radioisotope handling and monitoring procedures were followed.
12. Poineau, F., Sattelberger, A. P., and Czerwinski, K. J. Coord. Chem. 2008, 61, 2356-2370
13. 4. The structure consists of two bridging trans -acetate ligands and four terminal chlorides. The Tc-Tc separation is 2.150(1) Å. Additional synthetic and characterization details are included in the Supporting Information.
14. Cotton, F. A. and Mague, J. T. Inorg. Chem. 1964, 3, 1402-1407
15. 3: R 3̄ m; a = b = 10.1035(19) Å, c = 20.120(8) Å. Full refinement details are included in the Supporting Information.
16. Sattelberger, A. P. In Multiple Bonds between Metal Atoms, 3 rd ed.; Cotton, F. A., Murillo, C. A., and Walton, R. A., Eds.; Springer: New York, 2005; Chapter 7.
17. Plekhanov, Y. V. and Kryutchkov, S. V. Russ. J. Coord. Chem. 1998, 24, 617-624
18. Batsanov, S. S. Inorg. Mater. 2001, 37, 871-885
19. Schafer, H., von Schnering, H. G., Tillack, J., Kuhnen, F., Wahrle, H., and Bauman, H. Z. Anorg. Allg. Chem. 1967, 353, 281-310
20. Hillebrecht, H., Ludwig, Th., and Thiele, G. Z. Anorg. Allg. Chem. 2004, 630, 2199-2204
21. Poineau, F., Weck, P. F., Forster, P., Sattelberger, A. P., and Czerwinski, K. R. Dalton Trans. 2009, 10338-10342
22. Weck, P. F., Kim, E., Poineau, F., Rodriguez, E. E., Sattelberger, A. P., and Czerwinski, K. R. Inorg. Chem. 2009, 48, 6555-6558
23. Weck, P. F., Kim, E., and Czerwinski, K. R. Chem. Phys. Lett. 2010, 487, 190-193
24. Weck, P. F., Sergeeva, A. P., Kim, E., Boldyrev, A. I., and Czerwinski, K. R. Inorg. Chem., submitted.
25. Alberto, R. In Comprehensive Coordination Chemistry II; McCleverty, J. A. and Mayer, T. J., Eds.; Elsevier: Amsterdam, 2003; Vol. 5, Chapter 2.