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Volumn 11, Issue 14, 2010, Pages 3152-3160

Metal ion modulated torsion angle in a ditopic oligothiophene ligand: Toward supramolecular control of π conjugation

(8) Lukovskaya, Elena b Bobylyova, Alla b Fedorov, Yuri c Maksimov, Anton b Anisimov, Alexander b Fedorova, Olga b,c Jonusauskas, Gediminas d Fages, Frédéric a

a AIX MARSEILLE UNIVERSITÉ (France)

b MOSCOW STATE UNIVERSITY (Russian Federation)

c A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS (Russian Federation)

d CNRS (France)

Author keywords

Alkaline earth metals; Crown compounds; Oligothiophenes; Optical spectroscopy; Supramolecular chemistry

Indexed keywords

ABSORPTION SPECTROSCOPY; ALKALINE EARTH METAL COMPOUNDS; ALKALINE EARTH METALS; ALKALINITY; BARIUM; FLUORESCENCE SPECTROSCOPY; LIGANDS; MAGNESIUM; MASS SPECTROMETRY; METAL IONS;

BINUCLEAR COMPLEXES; COSMO SOLVATION MODELS; CROWN COMPOUNDS; ELECTRON DELOCALIZATION; MONONUCLEAR COMPLEXES; OLIGOTHIOPHENES; OPTICAL SPECTROSCOPY; SPECTROSCOPIC PROPERTY;

SUPRAMOLECULAR CHEMISTRY;

EID: 78349263766 PISSN: 14394235 EISSN: 14397641 Source Type: Journal
DOI: 10.1002/cphc.201000356 Document Type: Article

Times cited : (8)

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- Preliminary electrochemical experiments did show a strong but complex dependence of cyclic-voltammetric behavior of the two ligands in the presence of increasing amounts of metal cations. The complex electrochemical features were further complicated by the fact that, at the concentration used, 2 was observed to undergo electrodimerization and compound 3 was not soluble enough
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