Isothermal solid-state transformation kinetics applied to Pd/Cu alloy membrane fabrication

AIChE Journal

Volumn 56, Issue 12, 2010, Pages 3062-3073

  Pomerantz, Natalie ^a   Ma, Yi Hua ^a   Payzant, E Andrew ^b  

^a Worcester Polytechnic Institute   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Avrami model; In situ high temperature X ray diffraction; Pd membranes; Pd Cu alloys; Pd Cu diffusion; Time resolved

Indexed keywords

AVRAMI MODELS; IN-SITU; PD MEMBRANE; PD/CU ALLOYS; PD/CU DIFFUSION; TIME-RESOLVED;

ALLOYS; ANNEALING; CERIUM ALLOYS; COPPER ALLOYS; DEPOSITION; DIFFRACTION; DIFFUSION; GROWTH KINETICS; MEMBRANES; PALLADIUM; STAINLESS STEEL; SULFUR; SUPERCONDUCTING FILMS; X RAY DIFFRACTION; X RAYS;

ACTIVATION ENERGY;

EID: 78349236563     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.12217     Document Type: Article

References (39)

1. 2 capture. Chem Eng Process. 2004; 43: 1129-1158.
2. McKinley DL. Metal alloy for hydrogen separation and purification. US Pat. 3, 350, 845, 1967.
3. Mundschau MV, Xie X, Evenson CR, Sammells AF. Dense inorganic membranes for production of hydrogen from methane and coal with carbon dioxide sequestration. Catal Today. 2006; 118: 12-23.
4. Kajiwara M, Uemiya S, Kojima T. Stability and hydrogen permeation behavior of supported platinum membranes in presence of hydrogen sulfide. Int J Hydrogen Energy. 1999; 24: 839-844.
5. 2S. J Membr Sci. 2005; 254: 49-62.
6. Subramanian PR, Laughlin DE. Cu-Pd (copper-palladium). J Phase Equilib. 1991; 12: 231-243.
7. Morreale BD, Ciocco MV, Howard BH, Killmeyer RP, Cugini AV, Enick RM. Effect of hydrogen-sulfide on the hydrogen permeance of palladium-copper alloys at elevated temperatures. J Membr Sci. 2004; 241: 219-224.
8. McKinley DL. Method for hydrogen separation and purification. US Pat. 3, 247, 648, 1966.
9. Knapton AG. Palladium alloys for hydrogen diffusion membranes. Platinum Met Rev. 1977; 21: 44-50.
10. Gryaznov V. Metal-containing membranes for the production of ultrapure hydrogen and the recovery of hydrogen isotopes. Sep Purif Methods. 2000; 29: 171-187.
11. 2S on the performance and long-term stability of Pd/Cu membranes. Ind Eng Chem Res. 2009; 48: 4030-4039.
12. Ma YH, Akis BC, Ayturk ME, Guazzone F, Engwall EE, Mardilovich IP. Characterization of intermetallic diffusion barrier and alloy formation for Pd/Cu and Pd/Ag porous stainless steel composite membranes. Ind Eng Chem Res. 2004; 43: 2936-2945.
13. Guazzone F. Engineering of substrate surface for the synthesis of ultra-thin composite palladium and palladium-copper membranes for hydrogen separation. PhD Dissertation. Worcester, MA: Worcester Polytechnic Institute, 2006.
14. 2 formation from a GaSe/CuSe bilayer precursor film. J Cryst Growth. 2008; 310: 2987-2994.
15. 2 thin films grown from bilayer InSe/CuSe precursors. J Vac Sci Technol A. 2005; 23: 310-315.
16. Ayturk ME, Payzant EA, Speakman SA, Ma YH. Isothermal nucleation and growth kinetics of Pd/Ag alloy phase via in situ time-resolved high-temperature X-ray diffraction (HTXRD) analysis. J Membr Sci. 2008; 316: 97-111.
17. Ma YH, Mardilovich PP, She Y. Hydrogen gas-extraction module and method of fabrication. US Pat. 6, 152, 987, 2000.
18. Mardilovich PP, She Y, Ma YH, Rei M. Defect-free palladium membranes on porous stainless-steel support. AIChE J. 1998; 44: 310-322.
19. Ma YH, Mardilovich IP, Engwall EE. Thin composite palladium and palladium/alloy membranes for hydrogen separation. Ann N Y Acad Sci. 2003; 984: 346-360.
20. Cullity BD, Stock SR. Elements of X-Ray Diffraction. New Jersey: Prentice Hall, 2001.
21. Samsonov GV. The Oxide Handbook. New York: IFI/Plenum, 1973.
22. Porter DA, Easterling KE. Phase Transformation in Metals and Alloys. London: Chapman and Hall, 1981.
23. Bitler WR, Pickering HW, Kaja S. Interdiffusion kinetics of copper with palladium. Plat Surf Finish. 1985; 72: 60-63.
24. Yuan L, Goldbach A, Xu H. Permeation hysteresis in PdCu membranes. J Phys Chem B. 2008; 112: 12692-12695.
25. Butrymowicz DB, Manning JR, Read ME. Diffusion in copper and copper alloys. IV. Diffusion in systems involving elements of Group VIII. J Phys Chem Ref Data. 1976; 5: 103-200.
26. Avrami M. Kinetics of phase change. I. General theory. J Chem Phys. 1939; 7: 1103-1112.
27. Avrami M. Kinetics of phase change. II. Transformation-time relations for random distribution of nuclei. J Chem Phys. 1940; 8: 212-224.
28. Avrami M. Granulation, phase change and microstructure. Kinetics of phase change. III. J Chem Phys. 1941; 9: 177-184.
29. Hulbert SF. Models for solid-state reactions in powdered compacts. J Br Ceram Soc. 1969; 6: 11-20.
30. Christian JW. Theory of Transformations in Metals and Alloys. I. Thermodynamics and General Kinetic Theory. New York: Pergamon, 1978.
31. Borovskii IB, Marchukova ID, Ugaste YE. Interdiffusion in binary systems forming a continuous series of solid solution by using a local x-ray spectral analysis. The iron-palladium, cobalt-palladium, nickel-palladium, and copper-palladium systems. Fiz Met Metalloved. 1966; 22: 849-858.
32. Badia M. Interdiffusion of Fe and the transition metals. PhD Dissertation. Nancy, France: University of Nancy, 1969.
33. Chow KM, Ng WY, Yeung LK. Barrier properties of Ni, Pd and Pd-Fe for Cu diffusion. Surf Coat Technol. 1998; 105: 56-64.
34. Al-Kassab T, Macht M, Wollenberger H. FIM/AP analysis of Cu-Pd multilayers. Appl Surf Sci. 1995; 87/88: 329-336.
35. Philofsky EM, Hilliard JE. Effect of coherency strains on diffusion in copper-palladium alloys. J Appl Phys. 1969; 40: 2198-2205.
36. Saini A. An investigation of the cause of leak formation in palladium composite membranes. MS Thesis. Worcester, MA: Worcester Polytechnic Institute, 2006.
37. Lewis FA. The Palladium-Hydrogen System. London: Academic Press, 1967.
38. Guazzone F, Ma YH. Leak growth mechanism in composite Pd membranes prepared by the electroless deposition method. AIChE J. 2008; 54: 487-494.
39. Piper J. Diffusion of hydrogen in copper-palladium alloys. J Appl Phys. 1966; 37: 715-721.