Enantioselective and Z/E-selective conjugate addition of α-substituted cyanoacetates to acetylenic esters catalyzed by bifunctional ruthenium and iridium complexes

Angewandte Chemie - International Edition

Volumn 49, Issue 44, 2010, Pages 8157-8160

  Hasegawa, Yasuharu ^a   Gridnev, Ilya D ^a   Ikariya, Takao ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Acetylenic esters; Asymmetric conjugate addition; Bifunctional catalysts; Density functional calculations; Ruthenium

Indexed keywords

ACETYLENIC ESTERS; ASYMMETRIC CONJUGATE ADDITION; BI-FUNCTIONAL CATALYSTS; BIFUNCTIONAL; CONJUGATE ADDITION; DENSITY-FUNCTIONAL CALCULATIONS; ENANTIOMERIC EXCESS; ENANTIOSELECTIVE; HIGH YIELD; IRIDIUM COMPLEX; METAL-BASED CATALYSTS; REACTION MECHANISM; STEREOSELECTIVE REACTIONS; TRANSITION STATE STRUCTURE;

CATALYST SELECTIVITY; ESTERIFICATION; IRIDIUM; IRIDIUM COMPOUNDS; REACTION INTERMEDIATES; RUTHENIUM; RUTHENIUM COMPOUNDS;

ESTERS;

EID: 78249246640     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201003585     Document Type: Article

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