Catalytic supercritical fluid extraction: Selective hydroformylation of olefin mixtures using scCO2 solubility for differentiation

Green Chemistry

Volumn 12, Issue 10, 2010, Pages 1719-1721

  Koch, Timo J ^a   Desset, Simon L ^a   Leitner, Walter ^a,b  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 78149419311     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/c0gc00299b     Document Type: Article

References (26)

1. Reactive Separation Processes, S. Kulprathipanja, ed., 2002, Taylor & Francis, New York.
2. for recent examples see: S. H. Shuit K. T. Lee A. H. Kamaruddin S. Yusup Fuel 2010 89 527.
3. G. J. Harmsen Chem. Eng. Process. 2007 46 774.
4. W. Leitner Nature 2000 405 129-130.
5. K. Zosel Angew. Chem., Int. Ed. Engl. 1978 17 702-709.
6. N. R. Foster, F. P. Lucien and R. Mammucari, Basic physical properties, phase behavior and solubility, in Handbook of Green Chemistry, Volume 4: Supercritical Solvents, W. Leitner and P. Jessop, ed., 2010, Wiley-VCH, Weinheim, p 77.
7. For recent application of this principle to separate catalyst and product in continuous flow mode see: T. Harwardt G. Franciò W. leitner Chem. Commun 2010, 46 6669.
8. Rhodium Catalyzed Hydroformylation, P. W. N. M. van Leeuwen and C. Claver, ed., 2000, Kluwer, Dordrecht.
9. C. D. Frohning, C. W. Kohlpaintner and H. W. Bohnen, Hydroformylation (Oxo Synthesis, Roelen reaction), in Applied Homogeneous Catalysis with Organometallic Compounds 2nd Ed, B. Cornils and W. A. Herrmann, ed., 2002, Wiley-VCH, Weinheim, p 31.
10. I. T. Horváth Catal. Lett. 1990 6 43.
11. In aqueous biphasic systems, olefins with chain lengths > C5 are typically hydroformylated at lower rates owing to the lower water solubility as compared to shorter-chain substrate: E. Wiebus and B. Cornils, Biphasic systems: water-organic, in Catalyst Separation, Recovery and Recycling, D. J. Cole-Hamilton, and R. P. Tooze, ed., 2006, Springer, Dordrecht, p 105.
12. H. Bahrmann, S. Bogdanovic and P. W. N. M. van Leeuwen, Higher alkenes in Aqueous-Phase Organometallic Catalysis 2nd Ed., B. Crornils, and W. A. Herrmann, ed., 2004, Wiley-VCH, Weinheim, p 391.
13. D. Koch W. Leitner J. Am. Chem. Soc. 1998 120 13398-13404.
14. W. Leitner Acc. Chem. Res. 2002 35 746.
15. C. M. Rayner, P. M. Rose and D. C. Barnes, Synthetic Organic Chemistry in Supercritical Fluids, in Handbook of Green Chemistry, Volume 4: Supercritical Solvents, W. Leitner and P. JessopEds, 2010, Wiley-VCH, Weinheim, p 189 and references therein.
16. P. B. Webb M. F. Sellin T. E. Kunene S. Williamson A. M. Z. Slawin D. J. Cole-Hamilton J. Am. Chem. Soc. 2003 125 15577.
17. D. J. Cole-Hamilton Science 2003 299 1702 and references therein.
18. U. Hintermair Z. Gong A. Serbanovic M. J. Muldoon C. C. Santini D. J. Cole-Hamilton Dalton Trans. 2010 38 8501.
19. U. Hintermair G. Zhao C. C. Santini M. J. Muldoon D. J. Cole-Hamilton Chem. Commun. 2007 1462.
20. R. P. J. Bronger J. P. Bermon J. N. H. Reek P. C. J. Kamer P. W. N. M. van Leeuwen P. Licence M. Poliakoff J. Mol. Catal. A: Chem. 2004 224 145.
21. F. Shibahara K. Nozaki T. Hiyama J. Am. Chem. Soc. 2003 125 8555.
22. J. P. Arhancet M. E. Davis J. S. Merola B. E. Hanson Nature 1989 339 454.
23. P. Barbaro F. Liguori Chem. Rev. 2009 109 515.
24. J. P. Arhancet M. E. Davis J. S. Merola B. E. Hanson J. Catal. 1990 121 327.
25. T. I. Horvath Cat. Lett. 1990 6 43.
26. I. Toth B. E. Hanson I. Guo M. E. Davis Catal. Lett. 1991 8 209.